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Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters

Year 2021, , 42 - 52, 31.03.2021
https://doi.org/10.35208/ert.820613

Abstract

In this study, zinc ferrite nanoparticles, which has an important place among the spinel ferrite structured nanomaterials due to its unique properties, were synthesized by microwave-assisted combustion method and later were used as photocatalysts in the removal of dyestuffs by photocatalytic degradation method from wastewaters of textile industry. In the synthesis studies, it was determined that the microwave effect alone was not sufficient to complete the transformation. Heat treatment application is envisaged to solve this problem and in order to determine the optimum heat treatment temperature, the sample produced by microwave effect were subjected to heat treatment at 300℃, 400℃, 500℃, 600℃, 700℃, 800℃ and 900℃, respectively. It has been observed that the heat treatment has a significant effect on the crystal structure of the particles and 700℃ has been determined as the optimum heat treatment temperature. The data obtained showed that, under these conditions, the zinc ferrite nanoparticles were successfully synthesized and the powder produced completely consisted of nano-sized particles. Moreover, results showed that the synhesized zinc ferrite nanoparticles has a saturation magnetization value sufficient to separate them from the aqueous medium. Finally, zinc ferrite nanoparticles produced under optimum conditions were used as photocatalysts in the removal of textile dye known as Procion Yellow HE-3G from wastewater by photocatalytic oxidation. In photocatalysis experiments, it was observed that synthesized zinc ferrite nanoparticles provided very high removal efficiencies as photocatalysts and almost all of the dye content in the solution could be removed.

References

  • R. Saranya, R.A. Raj, M.S. Al Salhi, S. Devanesan, “Dependence of Catalytic Activity of Nanocrystalline Nickel Ferrite on Its Structural, Morphological, Optical, and Magnetic Properties in Aerobic Oxidation of Benzyl Alcohol”,Journal of Superconductivity and Novel Magnetism, 31(4), pp.1219-1225, 2017.
  • M. Hakamada, M. Mabuchi, “Nanoporous Gold Prism Microassembly through a Self-Organizing Route”, Nano Letters, 6(4), pp.882-885. 2006
  • Rachna, N.B.Singh, A. Agarwal,”Preparation, Characterization, Properties and Applications of nano Zinc Ferrite”, Materials Today: Proceedings, 5(3), pp.9148-9155. 2018.
  • R.C. Sripriya, V.A.F. Samson, S. Anand, J. Madhavan, M.V.A. Raj, ”Comparative studies of structural, magnetic and photocatalytic degradation on 4-chlorophenol by ZnFe2O4 nanostructures prepared via cost effective combustion methods”, Journal of Materials Science: Materials in Electronics, 29(16), pp.14084-14092, 2018
  • T. Prakash, G.V.M. Williams, J. Kennedy, S. Rubanov, “High spin-dependent tunneling magnetoresistance in magnetite powders made by arc-discharge”, Journal of Applied Physics, 120(12), 2016
  • Murmu PP, Kennedy J, Williams GVM, Ruck BJ, Granville S, Chong SV: Observation of magnetism, low resistivity, and magnetoresistance in the near-surface region of Gd implanted ZnO”, Applied Physics Letters, 101 (8). 2012
  • S. Banik, I. Das, “Large magnetoresistance and relative cooling power in polycrystalline Pr0.775Sr0.225MnO3 compound”, Journal of Magnetism and Magnetic Materials, 460, pp. 234-238, 2018.
  • K. Kaviyarasu, P.P. Murmu, J. Kennedy, F.T.Thema, D. Letsholathebe, L. Kotsedi, M. Maaza, ”Structural, optical and magnetic investigation of Gd implanted CeO2 nanocrystals”, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 409, pp.147-152, 2017.
  • T. Prakash, G.V.M. Williams, J. Kennedy, S. Rubanov, “Formation of magnetic nanoparticles by low energy dual implantation of Ni and Fe into SiO2”, Journal of Alloys and Compounds, 667, pp.255-261, 2016.
  • A.H. Morr, K. Haneda, “Magnetic structure of small NiFe2O4 particles”, Journal of Applied Physics, 52 (3), pp. 2496-2498, 1981.
  • N.M. Deraz, A. Alarifi, ”Microstructure and Magnetic Studies of Zinc Ferrite Nano-Particles”, Int J Electrochem Sci, 7, pp. 650-6511, 2012.
  • M. Sertkol, Y. Köseoğlu, A. Baykal, H. Kavas, A. Bozkurt, M.S. Toprak, “Microwave synthesis and characterization of Zn-doped nickel ferrite nanoparticles”, Journal of Alloys and Compounds, 486(1-2), pp. 325-329, 2009
  • P. Guo, L. Cui, Y. Wang, M. Lv, B. Wang, X.S. Zhao, “Facile Synthesis of ZnFe2O4 Nanoparticles with Tunable Magnetic and Sensing Properties”, Langmuir, 29 (28), pp. 8997-9003, 2013.
  • F. Iqbal, M.I.A. Mutalib, M.S. Shaharun, M. Khan, B. Abdullah, “Synthesis of ZnFe2O4 Using sol-gel Method: Effect of Different Calcination Parameters”, Procedia Engineering, 148, pp.787-794, 2016.
  • M.G. Naseri, E.B. Saion, M. Hashim, A.H. Shaari, H.A. Ahangar, “Synthesis and characterization of zinc ferrite nanoparticles by a thermal treatment method”, Solid State Communications, 151(14-15), pp. 1031-1035, 2011.
  • M. Ebrahimi, R. Raeisi Shahraki, S.A. Seyyed Ebrahimi, S.M. Masoudpanah, “Magnetic Properties of Zinc Ferrite Nanoparticles Synthesized by Coprecipitation Method”, Journal of Superconductivity and Novel Magnetism, 27(6), pp. 1587-1592, 2014.
  • S. Sun, X. Yang, Y. Zhang, F. Zhang, J. Ding, J. Bao, C. Gao, “Enhanced photocatalytic activity of sponge-like ZnFe2O4 synthesized by solution combustion method”, Progress in Natural Science: Materials International, 22(6), pp. 639-643, 2012.
  • J. Zhang, J.M. Song, H.L. Niu, C.J. Mao, S.Y. Zhang, Y.H. Shen, “ZnFe2O4 nanoparticles: Synthesis, characterization, and enhanced gas sensing property for acetone”, Sensors and Actuators B: Chemical, 221:55-62, 2015.
  • Z. Karcıoğlu Karakaş, R. Boncukcuoğlu, İ.H. Karakaş, M. Ertuğrul, “The effects of heat treatment on the synthesis of nickel ferrite (NiFe2O4) nanoparticles using the microwave assisted combustion method”, Journal of Magnetism and Magnetic Materials, 374, pp. 298-306, 2015.
  • S.D. Jadhav, P.P. Hankare, R.P. Patil, R. Sasikala, ” Effect of sintering on photocatalytic degradation of methyl orange using zinc ferrite”, Materials Letters, 65 (2), pp. 371-373, 2011.
  • G.Y. Zhang, Y.Q. Sun, D.Z. Gao, Y.Y. Xu, ”Quasi-cube ZnFe2O4 nanocrystals: Hydrothermal synthesis and photocatalytic activity with TiO2 (Degussa P25) as nanocomposite”, Mater Res Bull, 45 (7), pp. 755-760, 2010.
  • M. Rostami, M. Rahimi-Nasrabadi, M.R. Ganjali, F. Ahmadi, Shojaei AF, Rafiee MD, “Facile synthesis and characterization of TiO2-graphene-ZnFe2-x Tb (x) O-4 ternary nano-hybrids”, J Mater Sci, 52 (12), pp. 7008-7016, 2017.
  • P. Kharazi, R. Rahimi, M. Rabbani, “Study on porphyrin/ZnFe2O4@polythiophene nanocomposite as a novel adsorbent and visible light driven photocatalyst for the removal of methylene blue and methyl orange”, Mater Res Bull, 103, pp. 133-141, 2018.
  • H. Zhang, R. Hou, Z.L. Lu, X. Duan, “A novel magnetic nanocomposite involving anatase titania coating on silica-modified cobalt ferrite via lower temperature hydrolysis of a water-soluble titania precursor”, Mater Res Bull, 44(10), pp. 2000-2008, 2009.
  • S. Xu, D. Feng, W. Shangguan, “Preparations and Photocatalytic Properties of Visible-Light-Active Zinc Ferrite-Doped TiO2 Photocatalyst”, The Journal of Physical Chemistry C, 113(6), pp. 2463-2467, 2009.
  • P.P. Hankare, R.P. Patil, A.V. Jadhav, K.M. Garadkar, R. Sasikala, “Enhanced photocatalytic degradation of methyl red and thymol blue using titania-alumina-zinc ferrite nanocomposite”, Appl Catal B: Environ, 107 (3-4), pp. 333-339, 2011.
  • [27] R. Jiang, H. Zhu, Y. Fu, S. Jiang, E. Zong, J. Yao, “Photocatalytic Decolorization of Congo Red Wastewater by Magnetic ZnFe2O4/Graphene Nanosheets Composite under Simulated Solar Light Irradiation”, Ozone: Science & Engineering, 42 (2), pp.174-182, 2020.
  • Y. Fu, X. Wang, “Magnetically Separable ZnFe2O4–Graphene Catalyst and its High Photocatalytic Performance under Visible Light Irradiation”, Industrial & Engineering Chemistry Research, 50 (12), pp. 7210-7218, 2011.
  • Z. Shahnavaz, F. Lorestani, Y. Alias, P.M. Woi, “Polypyrrole–ZnFe2O4 magnetic nano-composite with core–shell structure for glucose sensing”, Applied Surface Science 317, pp. 622-629, 2014.
  • M. Venkatesh, G.S. Kumar, S. Viji, S. Karthi, E.K. Girija,”Microwave assisted combustion synthesis and characterization of nickel ferrite nanoplatelets”, Modern Electronic Materials 2 (3), pp. 74-78, 2016.
  • Y. Zhang, M. Yang, X. Huang, “Arsenic (V) removal with a Ce(IV)-doped iron oxide adsorbent”, Chemosphere, 51 (9), pp. 945-952, 2003.
  • Z. Karcıoğlu Karakaş, R. Boncukcuoğlu, İ.H. Karakaş, “Antimony removal from aqueous solutions using magnetic nickel ferrite (NiFe2O4) nanoparticles”, Separation Science and Technology, 54 (7):1141-1158, 2018.
  • Z. Alothman, “A Review: Fundamental Aspects of Silicate Mesoporous Materials”, Materials, 5, pp. 2874-2902, 2012.
  • K.S.W. Sing, “Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)”, Pure and Applied Chemistry, 57(4), pp. 603, 1985
  • K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemieniewska, “Reporting Physisorption Data for Gas/Solid Systems” Handbook of Heterogeneous Catalysis, pp. 1217-1230, 2008.
Year 2021, , 42 - 52, 31.03.2021
https://doi.org/10.35208/ert.820613

Abstract

References

  • R. Saranya, R.A. Raj, M.S. Al Salhi, S. Devanesan, “Dependence of Catalytic Activity of Nanocrystalline Nickel Ferrite on Its Structural, Morphological, Optical, and Magnetic Properties in Aerobic Oxidation of Benzyl Alcohol”,Journal of Superconductivity and Novel Magnetism, 31(4), pp.1219-1225, 2017.
  • M. Hakamada, M. Mabuchi, “Nanoporous Gold Prism Microassembly through a Self-Organizing Route”, Nano Letters, 6(4), pp.882-885. 2006
  • Rachna, N.B.Singh, A. Agarwal,”Preparation, Characterization, Properties and Applications of nano Zinc Ferrite”, Materials Today: Proceedings, 5(3), pp.9148-9155. 2018.
  • R.C. Sripriya, V.A.F. Samson, S. Anand, J. Madhavan, M.V.A. Raj, ”Comparative studies of structural, magnetic and photocatalytic degradation on 4-chlorophenol by ZnFe2O4 nanostructures prepared via cost effective combustion methods”, Journal of Materials Science: Materials in Electronics, 29(16), pp.14084-14092, 2018
  • T. Prakash, G.V.M. Williams, J. Kennedy, S. Rubanov, “High spin-dependent tunneling magnetoresistance in magnetite powders made by arc-discharge”, Journal of Applied Physics, 120(12), 2016
  • Murmu PP, Kennedy J, Williams GVM, Ruck BJ, Granville S, Chong SV: Observation of magnetism, low resistivity, and magnetoresistance in the near-surface region of Gd implanted ZnO”, Applied Physics Letters, 101 (8). 2012
  • S. Banik, I. Das, “Large magnetoresistance and relative cooling power in polycrystalline Pr0.775Sr0.225MnO3 compound”, Journal of Magnetism and Magnetic Materials, 460, pp. 234-238, 2018.
  • K. Kaviyarasu, P.P. Murmu, J. Kennedy, F.T.Thema, D. Letsholathebe, L. Kotsedi, M. Maaza, ”Structural, optical and magnetic investigation of Gd implanted CeO2 nanocrystals”, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 409, pp.147-152, 2017.
  • T. Prakash, G.V.M. Williams, J. Kennedy, S. Rubanov, “Formation of magnetic nanoparticles by low energy dual implantation of Ni and Fe into SiO2”, Journal of Alloys and Compounds, 667, pp.255-261, 2016.
  • A.H. Morr, K. Haneda, “Magnetic structure of small NiFe2O4 particles”, Journal of Applied Physics, 52 (3), pp. 2496-2498, 1981.
  • N.M. Deraz, A. Alarifi, ”Microstructure and Magnetic Studies of Zinc Ferrite Nano-Particles”, Int J Electrochem Sci, 7, pp. 650-6511, 2012.
  • M. Sertkol, Y. Köseoğlu, A. Baykal, H. Kavas, A. Bozkurt, M.S. Toprak, “Microwave synthesis and characterization of Zn-doped nickel ferrite nanoparticles”, Journal of Alloys and Compounds, 486(1-2), pp. 325-329, 2009
  • P. Guo, L. Cui, Y. Wang, M. Lv, B. Wang, X.S. Zhao, “Facile Synthesis of ZnFe2O4 Nanoparticles with Tunable Magnetic and Sensing Properties”, Langmuir, 29 (28), pp. 8997-9003, 2013.
  • F. Iqbal, M.I.A. Mutalib, M.S. Shaharun, M. Khan, B. Abdullah, “Synthesis of ZnFe2O4 Using sol-gel Method: Effect of Different Calcination Parameters”, Procedia Engineering, 148, pp.787-794, 2016.
  • M.G. Naseri, E.B. Saion, M. Hashim, A.H. Shaari, H.A. Ahangar, “Synthesis and characterization of zinc ferrite nanoparticles by a thermal treatment method”, Solid State Communications, 151(14-15), pp. 1031-1035, 2011.
  • M. Ebrahimi, R. Raeisi Shahraki, S.A. Seyyed Ebrahimi, S.M. Masoudpanah, “Magnetic Properties of Zinc Ferrite Nanoparticles Synthesized by Coprecipitation Method”, Journal of Superconductivity and Novel Magnetism, 27(6), pp. 1587-1592, 2014.
  • S. Sun, X. Yang, Y. Zhang, F. Zhang, J. Ding, J. Bao, C. Gao, “Enhanced photocatalytic activity of sponge-like ZnFe2O4 synthesized by solution combustion method”, Progress in Natural Science: Materials International, 22(6), pp. 639-643, 2012.
  • J. Zhang, J.M. Song, H.L. Niu, C.J. Mao, S.Y. Zhang, Y.H. Shen, “ZnFe2O4 nanoparticles: Synthesis, characterization, and enhanced gas sensing property for acetone”, Sensors and Actuators B: Chemical, 221:55-62, 2015.
  • Z. Karcıoğlu Karakaş, R. Boncukcuoğlu, İ.H. Karakaş, M. Ertuğrul, “The effects of heat treatment on the synthesis of nickel ferrite (NiFe2O4) nanoparticles using the microwave assisted combustion method”, Journal of Magnetism and Magnetic Materials, 374, pp. 298-306, 2015.
  • S.D. Jadhav, P.P. Hankare, R.P. Patil, R. Sasikala, ” Effect of sintering on photocatalytic degradation of methyl orange using zinc ferrite”, Materials Letters, 65 (2), pp. 371-373, 2011.
  • G.Y. Zhang, Y.Q. Sun, D.Z. Gao, Y.Y. Xu, ”Quasi-cube ZnFe2O4 nanocrystals: Hydrothermal synthesis and photocatalytic activity with TiO2 (Degussa P25) as nanocomposite”, Mater Res Bull, 45 (7), pp. 755-760, 2010.
  • M. Rostami, M. Rahimi-Nasrabadi, M.R. Ganjali, F. Ahmadi, Shojaei AF, Rafiee MD, “Facile synthesis and characterization of TiO2-graphene-ZnFe2-x Tb (x) O-4 ternary nano-hybrids”, J Mater Sci, 52 (12), pp. 7008-7016, 2017.
  • P. Kharazi, R. Rahimi, M. Rabbani, “Study on porphyrin/ZnFe2O4@polythiophene nanocomposite as a novel adsorbent and visible light driven photocatalyst for the removal of methylene blue and methyl orange”, Mater Res Bull, 103, pp. 133-141, 2018.
  • H. Zhang, R. Hou, Z.L. Lu, X. Duan, “A novel magnetic nanocomposite involving anatase titania coating on silica-modified cobalt ferrite via lower temperature hydrolysis of a water-soluble titania precursor”, Mater Res Bull, 44(10), pp. 2000-2008, 2009.
  • S. Xu, D. Feng, W. Shangguan, “Preparations and Photocatalytic Properties of Visible-Light-Active Zinc Ferrite-Doped TiO2 Photocatalyst”, The Journal of Physical Chemistry C, 113(6), pp. 2463-2467, 2009.
  • P.P. Hankare, R.P. Patil, A.V. Jadhav, K.M. Garadkar, R. Sasikala, “Enhanced photocatalytic degradation of methyl red and thymol blue using titania-alumina-zinc ferrite nanocomposite”, Appl Catal B: Environ, 107 (3-4), pp. 333-339, 2011.
  • [27] R. Jiang, H. Zhu, Y. Fu, S. Jiang, E. Zong, J. Yao, “Photocatalytic Decolorization of Congo Red Wastewater by Magnetic ZnFe2O4/Graphene Nanosheets Composite under Simulated Solar Light Irradiation”, Ozone: Science & Engineering, 42 (2), pp.174-182, 2020.
  • Y. Fu, X. Wang, “Magnetically Separable ZnFe2O4–Graphene Catalyst and its High Photocatalytic Performance under Visible Light Irradiation”, Industrial & Engineering Chemistry Research, 50 (12), pp. 7210-7218, 2011.
  • Z. Shahnavaz, F. Lorestani, Y. Alias, P.M. Woi, “Polypyrrole–ZnFe2O4 magnetic nano-composite with core–shell structure for glucose sensing”, Applied Surface Science 317, pp. 622-629, 2014.
  • M. Venkatesh, G.S. Kumar, S. Viji, S. Karthi, E.K. Girija,”Microwave assisted combustion synthesis and characterization of nickel ferrite nanoplatelets”, Modern Electronic Materials 2 (3), pp. 74-78, 2016.
  • Y. Zhang, M. Yang, X. Huang, “Arsenic (V) removal with a Ce(IV)-doped iron oxide adsorbent”, Chemosphere, 51 (9), pp. 945-952, 2003.
  • Z. Karcıoğlu Karakaş, R. Boncukcuoğlu, İ.H. Karakaş, “Antimony removal from aqueous solutions using magnetic nickel ferrite (NiFe2O4) nanoparticles”, Separation Science and Technology, 54 (7):1141-1158, 2018.
  • Z. Alothman, “A Review: Fundamental Aspects of Silicate Mesoporous Materials”, Materials, 5, pp. 2874-2902, 2012.
  • K.S.W. Sing, “Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)”, Pure and Applied Chemistry, 57(4), pp. 603, 1985
  • K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemieniewska, “Reporting Physisorption Data for Gas/Solid Systems” Handbook of Heterogeneous Catalysis, pp. 1217-1230, 2008.
There are 35 citations in total.

Details

Primary Language English
Subjects Environmental Engineering
Journal Section Research Articles
Authors

Zeynep Karcıoğlu Karakaş 0000-0001-9778-5956

Publication Date March 31, 2021
Submission Date November 3, 2020
Acceptance Date January 22, 2021
Published in Issue Year 2021

Cite

APA Karcıoğlu Karakaş, Z. (2021). Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters. Environmental Research and Technology, 4(1), 42-52. https://doi.org/10.35208/ert.820613
AMA Karcıoğlu Karakaş Z. Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters. ERT. March 2021;4(1):42-52. doi:10.35208/ert.820613
Chicago Karcıoğlu Karakaş, Zeynep. “Investigation of the Usability of Zinc Ferrite Nanoparticles Synthesized by Microwave Assisted Combustion Method As Photocatalyst for Removal of Organic Dyes from Wastewaters”. Environmental Research and Technology 4, no. 1 (March 2021): 42-52. https://doi.org/10.35208/ert.820613.
EndNote Karcıoğlu Karakaş Z (March 1, 2021) Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters. Environmental Research and Technology 4 1 42–52.
IEEE Z. Karcıoğlu Karakaş, “Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters”, ERT, vol. 4, no. 1, pp. 42–52, 2021, doi: 10.35208/ert.820613.
ISNAD Karcıoğlu Karakaş, Zeynep. “Investigation of the Usability of Zinc Ferrite Nanoparticles Synthesized by Microwave Assisted Combustion Method As Photocatalyst for Removal of Organic Dyes from Wastewaters”. Environmental Research and Technology 4/1 (March 2021), 42-52. https://doi.org/10.35208/ert.820613.
JAMA Karcıoğlu Karakaş Z. Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters. ERT. 2021;4:42–52.
MLA Karcıoğlu Karakaş, Zeynep. “Investigation of the Usability of Zinc Ferrite Nanoparticles Synthesized by Microwave Assisted Combustion Method As Photocatalyst for Removal of Organic Dyes from Wastewaters”. Environmental Research and Technology, vol. 4, no. 1, 2021, pp. 42-52, doi:10.35208/ert.820613.
Vancouver Karcıoğlu Karakaş Z. Investigation of the usability of zinc ferrite nanoparticles synthesized by microwave assisted combustion method as photocatalyst for removal of organic dyes from wastewaters. ERT. 2021;4(1):42-5.