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Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid

Year 2021, , 102 - 107, 31.03.2021
https://doi.org/10.35208/ert.842192

Abstract

The heat accumulated in the inner parts of the earth's crust is transmitted to the fluid in the geothermal aquifer by means of transportation. The geothermal fluid is transported to the surface either by wells or naturally. In this study, the geothermal fluid in Tuzla geothermal field in Çanakkale city was examined due to its high boron content (10.3 mg L-1). It was aimed to remove boron from geothermal fluid by adsorption in order to prevent possible negative effects on the environment. Fly ash was obtained from Çan thermal power plant. The specific surface area of the fly ash was 14.6 m2 g-1 and the particle size was between 1.45 and 186 µm. According to ASTM C618 standard, fly ash was classified as Class C. Fly ash was composed of anhydrite, lime, hematite, cristobalite, quartz, calcite and feldspar. Various parameters such as initial pH, adsorbent dosage, contact time, and temperature were studied experimentally for the removal of boron from the geothermal fluid. The suitability of pseudo-first-order, pseudo-second-order, and intraparticle kinetic models to experimental data was examined. The data obtained from the isotherm studies were applied to the Langmuir, Freundlich and Dubinin-Radushkevich models.

Supporting Institution

Scientific Research Projects Coordination Unit of Çanakkale Onsekiz Mart University

Project Number

FYL-2019-3086

References

  • [1]. Yilmaz, N. Kabay, M. Brjyak, M. Yuksel, J. Wolska and A. Koltuniewicz, "A submerged membrane–ion-exchange hybrid process for boron removal," Desalination, Vol. 198, pp. 310-315, 2006.
  • [2]. R.O. Nable, G.S. Banuelos, J.G. Paull, Plant and Soil, Kluwer Academic Publishers, Netherlands, pp. 181–198, 1997.
  • [3]. H. Polat, A. Vengosh, I. Pankratov, M. Polat, "A new methodology for removal of boron from water by coal and fly ash," Desalination, Vol. 164, pp. 173-188, 2004.
  • [4]. M. Yurdakoç M. Y. Seki, S. Karahan and K. Yurdakoç, "Kinetic and thermodynamic studies of boron removal by Siral 5, Siral 40, and Siral 80," Journal of Colloid and Interface Science, Vol. 286, pp. 440–446, 2005.
  • [5]. N. Kabay, I. Yilmaz Ipek., I. Soroko, M. Makowski, O., Kirmizisakal, S. Yag, M. Bryjak and M. Yuksel, "Removal of boron from Balcova geothermal water by ion exchange–microfiltration hybrid process," Desalination, Vol. 241(1-3), pp. 167-173, 2009.
  • [6]. N. Oztürk and D. Kavak, "Boron removal from aqueous solutions by adsorption on waste sepiolite and activated waste sepiolite using full factorial design," Adsorption, Vol. 10, pp. 245-257, 2005.
  • [7]. C. H. Weng and C. P. Huang, "Adsorption characteristics of Zn(II) from dilute aqueous solution by fly ash," Colloid Surface A., Vol. 247, pp. 137-143, 2004.
  • [8]. D. Sanliyuksel Yucel, "Removal of heavy metals from aqueous solution using fly ash: Can Thermal Power Plant, NW Turkey as a case study," Karaelmas Science and Engineering Journal, Vol. 7(1), pp. 291–298, 2017.
  • [9]. M. Ondova, N. Stevulova and A. Estokova, "The study of the properties of fly ash based concrete composites with various chemical admixtures," Procedia Engineering, Vol. 42, pp. 1863-1872, 2012.
  • [10]. E. Sayilgan, K. Kurklu, "Uçucu kül örneğinden demir ve alüminyum gideriminde Taguchi yaklaşımı," Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Vol. 23(3), pp. 133–142, 2018.
  • [11]. D. Sanliyuksel Yucel and B. Ileri, "Mitigation of Environmental Effects of Anthropogenic Metal Contamination Using Fly Ash,” Geological Bulletin of Turkey, Vol. 63, pp. 43-56, 2020.
  • [12]. T. Yalçın, "Geochemical characterization of the Biga Peninsula thermal waters (NW Turkey)," Aquatic Geochemistry, Vol. 13(1), pp. 75–93, 2007.
  • [13]. American Society for Testing and Materials (ASTM). Standard C618–15 standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. West Conshohocken, PA: ASTM International, 2015.
  • [14]. K. B. Krauskopf and D. K. Bird, Introduction to Geochemistry, 3rd ed., McGraw-Hill, New York, 1995.
  • [15]. W.J. Weber, Physicochemical Processes for Water Quality Control, John Wiley and Sons Inc., New York, 1972.
  • [16]. M.M. Dubinnin, “The potential theory of adsorption of gases and vapors for adsorbents with energetically non-uniform surface,” Chemical Reviews, Vol. 60, pp. 235, 1960.
  • [17]. S. Lagergren, “About the theory of so called adsorption of soluble substances,” K. Sven. Vetenskapsakad. Handl., Vol. 24 (4), pp. 1–39, 1898.
  • [18]. Y.S. Ho, “Citation review of Lagergren kinetic rate equation on adsorption reaction,” Scientometrics, Vol. 59 (1), pp. 171–177, 2004.
  • [19]. Y.S. Ho, “Removal of metal ions from sodium arsenate solution using tree fern,” Trans. IChemE. Part B, Vol. 81, pp. 352–356, 2003.
  • [20]. Y.S. Ho, “Review of second-order models for adsorption systems,” J. Hazard. Mater., B, Vol. 136, pp. 681–689, 2006.
  • [21]. A.A. Halım, N.A. Roslan, N.S. Yaacub and M.T. Latif, “Boron removal from aqueous solution using Curcumin-impregnated activated carbon,” Sains Malaysiana, Vol. 42(9), pp. 1293-1300, 2013.
Year 2021, , 102 - 107, 31.03.2021
https://doi.org/10.35208/ert.842192

Abstract

Project Number

FYL-2019-3086

References

  • [1]. Yilmaz, N. Kabay, M. Brjyak, M. Yuksel, J. Wolska and A. Koltuniewicz, "A submerged membrane–ion-exchange hybrid process for boron removal," Desalination, Vol. 198, pp. 310-315, 2006.
  • [2]. R.O. Nable, G.S. Banuelos, J.G. Paull, Plant and Soil, Kluwer Academic Publishers, Netherlands, pp. 181–198, 1997.
  • [3]. H. Polat, A. Vengosh, I. Pankratov, M. Polat, "A new methodology for removal of boron from water by coal and fly ash," Desalination, Vol. 164, pp. 173-188, 2004.
  • [4]. M. Yurdakoç M. Y. Seki, S. Karahan and K. Yurdakoç, "Kinetic and thermodynamic studies of boron removal by Siral 5, Siral 40, and Siral 80," Journal of Colloid and Interface Science, Vol. 286, pp. 440–446, 2005.
  • [5]. N. Kabay, I. Yilmaz Ipek., I. Soroko, M. Makowski, O., Kirmizisakal, S. Yag, M. Bryjak and M. Yuksel, "Removal of boron from Balcova geothermal water by ion exchange–microfiltration hybrid process," Desalination, Vol. 241(1-3), pp. 167-173, 2009.
  • [6]. N. Oztürk and D. Kavak, "Boron removal from aqueous solutions by adsorption on waste sepiolite and activated waste sepiolite using full factorial design," Adsorption, Vol. 10, pp. 245-257, 2005.
  • [7]. C. H. Weng and C. P. Huang, "Adsorption characteristics of Zn(II) from dilute aqueous solution by fly ash," Colloid Surface A., Vol. 247, pp. 137-143, 2004.
  • [8]. D. Sanliyuksel Yucel, "Removal of heavy metals from aqueous solution using fly ash: Can Thermal Power Plant, NW Turkey as a case study," Karaelmas Science and Engineering Journal, Vol. 7(1), pp. 291–298, 2017.
  • [9]. M. Ondova, N. Stevulova and A. Estokova, "The study of the properties of fly ash based concrete composites with various chemical admixtures," Procedia Engineering, Vol. 42, pp. 1863-1872, 2012.
  • [10]. E. Sayilgan, K. Kurklu, "Uçucu kül örneğinden demir ve alüminyum gideriminde Taguchi yaklaşımı," Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, Vol. 23(3), pp. 133–142, 2018.
  • [11]. D. Sanliyuksel Yucel and B. Ileri, "Mitigation of Environmental Effects of Anthropogenic Metal Contamination Using Fly Ash,” Geological Bulletin of Turkey, Vol. 63, pp. 43-56, 2020.
  • [12]. T. Yalçın, "Geochemical characterization of the Biga Peninsula thermal waters (NW Turkey)," Aquatic Geochemistry, Vol. 13(1), pp. 75–93, 2007.
  • [13]. American Society for Testing and Materials (ASTM). Standard C618–15 standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. West Conshohocken, PA: ASTM International, 2015.
  • [14]. K. B. Krauskopf and D. K. Bird, Introduction to Geochemistry, 3rd ed., McGraw-Hill, New York, 1995.
  • [15]. W.J. Weber, Physicochemical Processes for Water Quality Control, John Wiley and Sons Inc., New York, 1972.
  • [16]. M.M. Dubinnin, “The potential theory of adsorption of gases and vapors for adsorbents with energetically non-uniform surface,” Chemical Reviews, Vol. 60, pp. 235, 1960.
  • [17]. S. Lagergren, “About the theory of so called adsorption of soluble substances,” K. Sven. Vetenskapsakad. Handl., Vol. 24 (4), pp. 1–39, 1898.
  • [18]. Y.S. Ho, “Citation review of Lagergren kinetic rate equation on adsorption reaction,” Scientometrics, Vol. 59 (1), pp. 171–177, 2004.
  • [19]. Y.S. Ho, “Removal of metal ions from sodium arsenate solution using tree fern,” Trans. IChemE. Part B, Vol. 81, pp. 352–356, 2003.
  • [20]. Y.S. Ho, “Review of second-order models for adsorption systems,” J. Hazard. Mater., B, Vol. 136, pp. 681–689, 2006.
  • [21]. A.A. Halım, N.A. Roslan, N.S. Yaacub and M.T. Latif, “Boron removal from aqueous solution using Curcumin-impregnated activated carbon,” Sains Malaysiana, Vol. 42(9), pp. 1293-1300, 2013.
There are 21 citations in total.

Details

Primary Language English
Subjects Environmental Sciences, Environmental Engineering, Water Resources and Water Structures
Journal Section Research Articles
Authors

Mehmet Oğuzhan Şahin 0000-0002-4453-6187

Tijen Ennil Bektas 0000-0001-9180-3623

Deniz Şanlıyüksel Yücel 0000-0001-6546-5624

Project Number FYL-2019-3086
Publication Date March 31, 2021
Submission Date December 17, 2020
Acceptance Date February 4, 2021
Published in Issue Year 2021

Cite

APA Şahin, M. O., Bektas, T. E., & Şanlıyüksel Yücel, D. (2021). Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid. Environmental Research and Technology, 4(1), 102-107. https://doi.org/10.35208/ert.842192
AMA Şahin MO, Bektas TE, Şanlıyüksel Yücel D. Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid. ERT. March 2021;4(1):102-107. doi:10.35208/ert.842192
Chicago Şahin, Mehmet Oğuzhan, Tijen Ennil Bektas, and Deniz Şanlıyüksel Yücel. “Effectiveness of Fly Ash in Boron Removal from Tuzla (Çanakkale) Geothermal Fluid”. Environmental Research and Technology 4, no. 1 (March 2021): 102-7. https://doi.org/10.35208/ert.842192.
EndNote Şahin MO, Bektas TE, Şanlıyüksel Yücel D (March 1, 2021) Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid. Environmental Research and Technology 4 1 102–107.
IEEE M. O. Şahin, T. E. Bektas, and D. Şanlıyüksel Yücel, “Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid”, ERT, vol. 4, no. 1, pp. 102–107, 2021, doi: 10.35208/ert.842192.
ISNAD Şahin, Mehmet Oğuzhan et al. “Effectiveness of Fly Ash in Boron Removal from Tuzla (Çanakkale) Geothermal Fluid”. Environmental Research and Technology 4/1 (March 2021), 102-107. https://doi.org/10.35208/ert.842192.
JAMA Şahin MO, Bektas TE, Şanlıyüksel Yücel D. Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid. ERT. 2021;4:102–107.
MLA Şahin, Mehmet Oğuzhan et al. “Effectiveness of Fly Ash in Boron Removal from Tuzla (Çanakkale) Geothermal Fluid”. Environmental Research and Technology, vol. 4, no. 1, 2021, pp. 102-7, doi:10.35208/ert.842192.
Vancouver Şahin MO, Bektas TE, Şanlıyüksel Yücel D. Effectiveness of fly ash in boron removal from Tuzla (Çanakkale) geothermal fluid. ERT. 2021;4(1):102-7.