Adsorption properties of activated almond shells for methylene blue (MB)

Year 2018, Volume: 1 Issue: 2, 31 - 38, 01.04.2018

Ramazan Coskun Serpil Savci Ali Delibas

Abstract

In this study, the
adsorption properties of activated almond shells for methylene blue (MB) were
investigated. For this aim raw almond shells (RAS) were activated with
concentrated sulfuric acid. Activated almond shell (SAS) and raw almond shells
(RAS) were characterized with FTIR, SEM and BET analysis. After activation,
larger and deeper pores similar to chamber were formed and increase in BET
surface area and adsorption rate and also new functional groups were observed.
Effects of pH, initial concentration of dye and adsorbent dose on adsorption of
MB were studied. Adsorption studies were fitted Langmuir isotherm and pseudo
second order kinetic models. Experimental results showed that activated almond
shells were not affected pH of solution and adsorption capacity were highly
increased and it was calculated as 131.58 mg g^-1 from Langmuir
isotherm. It was observed that the activated almond shells could be used with
high efficiency in a wide pH and concentration ranges and SASs could be
desorbed and reusable without losing their activity. As a results, SAS could be
used an effective adsorbent for the removal of basic dyes like MB at a wide pH
and dye concentration range.

Keywords

adsorption, methylene blue, activated almond shell, efficiently removal

References

• [1] T. Madrakian, A. Afkhami, H. Mahmood-Kashani and M. Ahmadi, “Adsorption of some cationic and anionic dyes on magnetite nanoparticles-modified activated carbon from aqueous solutions: equilibrium and kinetics study," Journal of the Iranian Chemical Society, Vol. 10 pp. 481– 489, 2013.
• [2] X.G. Li, X.L. Ma, J. Sun and M.R. Huang, “Powerful reactive sorption of silver(i) and mercury(II) onto poly(o-phenylenediamine) microparticles,” Langmuir, Vol. 25, pp. 1675–1684, 2009.
• [3] X. Gu, J. Zhou, A. Zhang, P.Wang,M. Xiao and G. Liu, “Feasibility study of the treatment of aniline hypersaline wastewater with a combined adsorption/bio-regeneration system,” Desalination, Vol. 227, pp. 139–149, 2008.
• [4] J.G. Cai, A. Li, H.Y. Shi, Z.H. Fei, C. Long and Q.X. Zhang, “Adsorption characteristics of aniline and 4-methylaniline onto bifunctional polymeric adsorbent modified by sulfonic groups,” Journal of Hazardous Materials, Vol. 124, pp. 173–180, 2005.
• [5] E. Forgacs, T.C. Serhati and G.Oros, “Removal of synthetic dyes from wastewaters: a review”, Environment International, Vol. 30, pp. 953-971, 2004.
• [6] T. Robinson, G. McMullan, R. Marchant and P. Nigam, “Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative”, Bioresource Technology, Vol. 77, pp. 247-255, 2001.
• [7] S. Papic, N. Koprivanac, A.L. Bozic and A. Metes, “Removal of some reactive dyes from synthetic wastewater by combined Al(III) coagulation/carbon adsorption process”, Dyes and Pigments, Vol. 62, pp. 293-300, 2004.
• [8] T.H. Kim, C.H. Park, E.B. Shin and S.Y. Kim, “Decolorization of disperse and reactive dye solutions using ferric chloride,” Desalination, Vol. 161, pp. 49-58, 2004.
• [9] K. Nakagawa, A. Namba, S.R. Mukai, H. Tamon, P Ariyadejwanich and W.Tanthapanichakoon, “Adsorption of phenol and reactive dye from aqueous solution on activated carbons derived from solid wastes”, Water Research, Vol. 38, pp.1791-1798, 2004.
• [10] K.G. Bhattacharyya and A. Sharma, Kinetics and thermodynamics of methylene blue adsorption on neem (Azadirachta indica) leaf powder, Dyes and Pigments, Vol. 65, pp. 51– 59, 2005.
• [11] A. Bhatnagar, M. Sillanpää and A. Witek-Krowiak, “Agricultural waste peels as versatile biomass for water purification — a review”, Chemical Engineering Journal, Vol. 270, pp. 244–271, 2015.
• [12] R.K. Gautam, A. Mudhoo, G. Lofrano and M.C. Chattopadhyaya, “Biomass-derived biosorbents for metal ions sequestration: Adsorbent modification and activation methods and adsorbent regeneration”, Journal of Environmental Chemical Engineering, Vol. 2, pp. 239–259, 2014.
• [13] I. Ali, M. Asim and T.A. Khan, “Low cost adsorbents for the removal of organic pollutants from wastewater”, Journal of Environmental Management, Vol. 113, pp.170–183, 2012.
• [14] M.V. Dinu and E.S. Dragan, “Heavy metals adsorption on some iminodiacetate chelating resins as a function of the adsorption parameters”, Reactive and Functional Polymers, Vol. 68, pp. 1346–1354, 2008.
• [15] X. Zhao, G. Zhang, Q. Jia, C. Zhao, W. Zhou and W. Li, “Adsorption of Cu(II), Pb(II), Co(II), Ni(II), and Cd(II) from aqueous solution by poly(aryl ether ketone) containing pendant carboxyl groups (PEK-L): equilibrium, kinetics, and thermodynamics”, Chemical Engineering Journal, Vol. 171, pp. 152–158, 2011.
• [16] S. Çavuş¸ G. Gürdağ, K. Sözgen and M.A. Gürkaynak, “The preparation and characterization of poly(acrylic acid-co-methacrylamide) gel and its use in the non-competitive heavy metal removal”, Polymers for Advanced Technologies, Vol. 20, pp.165–172, 2009.
• [17] R. Coşkun and A. Delibaş, “Removal of methylene blue from aqueous solutions by poly (2- acrylamido-2-methylpropane sulfonic acid-co-itaconic acid) hydrogels”, Polymer Bulletine, Vol. 68, pp. 1889–1903, 2012.
• [18] E. Demirhan and E. Culhaoğlu, “Adsorption of 2,4-dichlorophenoxyacetic acid on peanut shells: effect of initial concentration”, Environmental Research & Technology, Vol. 1(1), pp. 23-26, 2018.
• [19] R. Mohd, S. Othman, H. Rokiah and A. Anees, “Adsorption of methylene blue on low-cost adsorbents: a review”, Journal of Hazardous Materials, Vol. 177, pp. 70–80, 2010.
• [20] S. Deng, R. Bai and J. P. Chen, “Aminated polyacrylonitrile fibers for lead and copper removal”, Langmuir, Vol. 19, pp. 5058-5064, 2003.
• [21] R. Coşkun, C. Soykan and M. Saçak, “Adsorption of copper(II), nickel(II) and cobalt(II) ions from aqueous solution by methacrylic acid/acrylamide monomer mixture grafted poly(ethylene terephthalate) fiber”, Separation and Purification Technology, Vol. 49, pp. 107–114, 2006.
• [22] R. Coşkun, C. Soykan and M. Saçak, “Removal of some heavy metal ions from aqueous solution by adsorption using poly(ethylene terephthalate)-g-itaconic acid/ acryl amide fiber”, Reactive and Functional Polymers, Vol. 66, pp. 599–608, 2006.
• [23] M. Ismail, MAKM.t Hanafiah, MSZ. Abidin, ZM. Hussin and K. Khalid, “Kinetics of Methylene Blue Adsorption on Sulphuric Acid Treated Coconut (Cocos nucifiera) Frond Powder”, American Journal of Environmental Engineering, Vol. 5(3A), pp. 33-37, 2015.
• [24] R.Coşkun, A. Yıldız and A. Delibaş, “Removal of Methylene Blue Using Fast Sucking Adsorbent”, Journal of Materials and Environmental Science, Vol.8(2), pp. 398-409, 2017.
• [25] K. Beyhan and K. Erdem, “Batch and column removal of the dye blue 3R over pumice”, Desalination and Water Treatment, Vol. 57, pp. 1–14, 2016.
• [26] D.Hui, L. Guoxue, Y. Hongbing, T.Jiping and T. Jiangyun , “Preparation of activated carbons from cotton stalk by microwave assisted KOH and K2CO3 activation”, Chemical Engineering Journal, Vol. 163, pp. 373-381, 2010.
• [27] Y. Tang, X. Wang and L. Zhu, “Removal of methyl orange from aqueous solutions with poly(acrylic acid-co-acrylamide) superabsorbent resin”, Polymer Bulletine, Vol. 70, pp. 905–918, 2013.
• [28] D. Hui, L. Jianjiang, L. Guoxue, Z. Genlin and W. Xugen, “Adsorption of methylene blue on adsorbent materials produced from cotton stalk”, Chemical Engineering Journal, Vol. 172, pp. 326–334, 2011.
• [29] L. Hem, V.K. Garg and R.K. Gupta, “Removal of a basic dye from aqueous solution by adsorption using Parthenium hysterophorus: An agricultural waste”, Dyes and Pigments, Vol. 74, pp. 653-658, 2007.
• [30] P. Waranusantigul, P.Pokethitiyook, M. Kruatrachue and E.S. Upatham, “Kinetics of basic dye (methylene blue) biosorption by giant duckweed (Spirodela polyrrhiza)”, Environmental Pollution, Vol. 125, pp. 385-392, 2003.
• [31] V.K. Garg, A. Moirangthem, R. Kumar and R. Gupta, “Basic dye (methylene blue) removal from simulated waste water by adsorption using Indian Rosewood Sawdust: timber industry waste”, Dyes and Pigments, Vol. 63, pp. 243-250, 2004.
• [36] R.K. Ghosh and DD. Reddy, “Tobacco Stem Ash as an adsorbent for removal of methylene blue from aqueous solution: equilibrium, kinetics, and mechanism of adsorption”, Water Air and Soil Pollution,Vol. 224(6), pp. 1–12, 2013.
• [33] C.H. Weng and Y.F. Pan, “Adsorption of a cationic dye (methylene blue) onto spent activated clay”, Journal of Hazardous Materials,Vol. 144(1), pp. 355–362, 2007.
• [34] M.T. Yagub, T.K. Sen and H. Ang, “Equilibrium, kinetics, and thermodynamics of methylene blue adsorption by pine tree leaves”, Water Air and Soil Pollution, Vol. 223(8), pp. 5267–5282, 2012
• [35] T.K. Sen, S. Afroze and H. Ang, “Equilibrium, kinetics and mechanism of removal of methylene blue from aqueous solution by adsorption onto pine cone biomass of Pinus radiata”, Water Air and Soil Pollution, Vol. 218, pp. 499–515, 2011.
• [37] K.V. Kumar, V. Ramamurthi and S.Sivanesan, Modeling the mechanism involved during the sorption of methylene blue onto fly ash, Journal of Colloid and Interface Science, 284(1) (2005)14–21.
• [38] N. Kannan and M.M. Sundaram, “Kinetics and mechanism of removal of methylene blue by adsorption on various carbons—a comparative study”, Dyes and Pigments,Vol. 51(1), pp. 25–40, 2001.
• [39] W. Zou, H. Bai, S. Gao and K. Li, “Characterization of modified sawdust, kinetic and equilibrium study about methylene blue adsorption in batch mode”, Korean Jornal of Chemical Engineering, Vol. 30(1), pp. 111–122, 2013.
• [40] S.A. Omotayo, O.O. Akeem, O.A. Abass, G.F. Abolaji and A.A. Segun, “Adsorption of Methylene Blue from Aqueous Solution Using Steam-Activated Carbon Produced from Lantana camara Stem”, Journal of Enviromental Protection, Vol. 5, pp. 1352-1363, 2014.
• [41] D. Sara, K. S. Tushar and P. Chi, “Adsorption removal of Methylene Blue (MB) dye from aqueous solution by bio-char prepared from Eucalyptus sheathiana bark: kinetic, equilibrium, mechanism, thermodynamic and process design”, Desalination and Water Treatment, Vol: 57, pp. 28964–28980, 2016.
• [42] A.R. Tehrani-Bagha , H. Nikkar , N.M. Mahmoodi, M. Markazi and F.M. Menger, “The sorption of cationic dyes onto kaolin: kinetic, isotherm and thermodynamic studies”, Desalination, Vol. 266(1), pp. 274–280, 2011.
• [43] P.S. Kumar and et al. “Adsorption of basic dye onto raw and surface modified agricultural waste”, Environmental Progress & Sustainable Energy, Vol. 33(1), pp. 87-98, 2014.
• [44] J. Yener, T. Kopac, G. Dogu and T. Dogu, “Dynamic analysis of sorption of Methylene Blue dye on granular and powdered activated carbon”, Chemical Engineering Journal, Vol. 144, pp. 400–406, 2008.
• [45] S. Ragupathy, K. Raghu and P. Prabu, “Synthesis and characterization of TiO2 loaded cashew nut shell activated carbon and photocatalytic a activity on BG and MB dyes under sunlight radiation”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 138, pp. 314–320, 2015.
• [46] Z.A. AlOthman, M.A. Habila, R. Ali, A. Abdel Ghafar and M.S. El-din Hassouna, “Valorization of two waste streams into activated carbon and studying its adsorption kinetics, equilibrium isotherms and thermodynamics for methylene blue removal”, Arabian Journal of Chemistry, Vol. 7, pp. 1148–1158, 2014.
• [47] A. Aygun, S. Yenisoy-Karaka and I. Duman, “Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties”, Microporous Mesoporous Materials, Vol. 66, pp.189–195, 2003.
• [48] D. Kavitha and C. Namasivayam, “Experimental and kinetic studies on methylene blue adsorption by coir pith carbon”, Bioresource Technology, Vol. 98, pp. 14–21, 2007.