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Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation

Year 2018, Volume: 1 Issue: 4, 6 - 13, 01.12.2018

Abstract

Textile
industry is one of the most chemically intensive industries on Earth and the
major polluter of potable water. There are many methods for dye removal in the
textile industry. One of the most effective methods is colour removal by
ozonation. The application of ozonation has increased in recent years.
Preference of the ozonation method is the efficiency of colour removal and the
short application time. In ozonation process, not only colour but also the
toxicity caused by products of treated wastewater is important. So, suitable
ozonation period must be obtained. The aim of this study is the removal of
Reactive Black 5 (RB-5) and Reactive Orange 16 (RO-16) from the synthetic
aqueous solution by ozonation. In this study, dye removal (%) and chemical oxygen
demand (COD) removal (%) were determined and carried out by kinetic analyzing.
The maximum dye removals were 99.9 % and 99 % at all pH values in initial dye
concentration of 100 mg L
-1 for RB-5 (40 min) and RO-16 (70 min),
respectively. It was found that COD removal is 100 % for both dyes. Ozonation
kinetics were studied and it was found that it agreed with the pseudo first
order kinetics for two dyes. The highest pseudo first order kinetic constants
are 0.1918 min
-1 (R2: 0.9978, pH:2) and 0.0794 min-1
(R
2: 0.9918, pH:6) for RB-5 and RO-16, respectively. The results
obtained in this study showed that ozonation of reactive dyes at acidic or
neutral pH was more suitable than that of alkaline pH.

References

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  • [2]. C.M. Carliell, S.C. Barclay, N. Naidoo, C.A. Buckley, D.A. Mullholand and E. Senior, “Microbial decolourisation of a reactive azo dye under anaerobic conditions,” Water SA, Vol. 21, pp. 61–69, 1995.
  • [3]. E. Oğuz, B. Keskinler and Z. Çelik, “Ozonation of aqueous Bomaplex Red Cr-L dye in a semi-batch reactor,” Dyes and Pigments, Vol. 64, pp. 101-108, 2005.
  • [4]. H. Zhiqiao, S. Shuang, Z. Huamin, Y. Haiping and C. Jianmeng, “C.I. Reactive Black 5 decolorization by combined sonolysis and ozonation,” Ultrasonics Sonochemistry, Vol. 14, pp. 298–304, 2007.
  • [5]. Z. Zakaria, W.Y.W. Ahmad, M.R. Yusop and M.R. Othman, “COD and color removal of Reactive Orange 16 dye solution by electrochemical oxidation and adsorption method,” in AIP Conference Proceedings, 1678, 050007, 1-6, 2015.
  • [6]. C. Tizaoui and N. Grima, “Kinetics of the ozone oxidation of Reactive Orange 16 azo-dye in aqueous solution,” Chemical Engineering Journal, Vol. 173, pp. 463-473, 2011.
  • [7]. S. Şahinkaya, “Decolorization of reactive orange 16 via ferrate(VI) oxidation assisted by sonication,” Turkish Journal of Chemistry, Vol. 41, pp. 577-586, 2017.
  • [8]. S. Venkatesh, A.R. Quaff, N.D. Pandey and K. Venkatesh, “Impact of ozonation on decolourization and mineralization of azo dyes: Biodegradability enhancement, by-products formation, required energy and cost,” Ozone: Science & Engineering, Vol. 37, pp. 420-430, 2015.
  • [9]. C. Wang, A. Yediler, D. Lienert, Z. Wang and A. Kettrup, “Ozonation of an azo dye C.I. Remazol Black 5 and toxicological assessment of its oxidation products,” Chemosphere, Vol. 52, pp. 1225-1232, 2003.
  • [10]. S. Venkatesh, K. Venkatesh and A.R. Quaff, “Dye decomposition by combined ozonation and anaerobic treatment: Cost effective technology,” Journal of Applied Research and Technology, Vol. 15, pp. 340-345, 2017.
  • [11]. htpps:/www.sigmaaldrich.com/. Available. (2018)
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  • [13]. J. Staehelin, R.E. Bühler, and J.Hoigne, “Ozone decomposition in water studied by pulse radiolysis. 2. OH and HO4 as chain intermediates,” The Journal of Physical Chemistry, Vol. 88, pp. 5999-6004, 1984.
  • [14]. J. Staehelin and J.Hoigne, “Decomposition of ozone in water in the presence of organic solutes acting as promoters and inhibitors of radical chain reaction,” Environ. Sci. Technol., Vol. 19, pp. 1206-1213, 1985.
  • [15]. H. Tomiyasu, H. Fukutomi and G. Gordon, “Kinetics and mechanism of ozone decomposition in basic aqueous solution,” Inorganic Chemistry, Vol. 24, pp. 2962-2966, 1985.
  • [16]. A.Ö. Yıldırım, “ Investigation of the degradation of some reactive dyes by using advanced oxidation techniques,” PhD Thesis, University of Çukurova, Adana, Turkey, 2009.
  • [17]. B. Langlais, D.A. Reckhow and D.R. Brink. Ozone in Water Treatment Application and Engineering, Lewis Publishers, New York, USA, 1991.
  • [18]. H. Selçuk, “Decolorization and detoxification of textile wastewater by ozonation and coagulation processes,” Dyes and Pigments, Vol. 64, pp. 217-222, 2005.
  • [19]. H. Y. Shu andC.R. Huang, “Degradation of commercial azo dyes in water using ozonation and UV enhanced ozonation process,” Chemosphere, Vol. 31, pp. 3813-3825, 1995.
  • [20]. M. Muthukumar, D. Sargunamani and N. Selvakumar, “Statistical analysis of the effect of aromatic, azo and sulfonic acid groups on decolorization of aciddye effluents using advanced oxidation processes,” Dyes Pigments, Vol. 65, pp. 151-158, 2005.
  • [21]. T. Kabdaşlı, T. Ölmez and O. Tünay, “Factors affecting color removal from reactive dye bath by ozonation,” Water Science Technology, Vol. 45, pp. 261-270, 2002.
Year 2018, Volume: 1 Issue: 4, 6 - 13, 01.12.2018

Abstract

References

  • [1]. T.C. Hsu, C.S. Chiang, “Activated sludge treatment of dispersed dye factory wastewater,” Journal of Environmental Science and Health, Vol. 32, pp. 1921-1932, 1997.
  • [2]. C.M. Carliell, S.C. Barclay, N. Naidoo, C.A. Buckley, D.A. Mullholand and E. Senior, “Microbial decolourisation of a reactive azo dye under anaerobic conditions,” Water SA, Vol. 21, pp. 61–69, 1995.
  • [3]. E. Oğuz, B. Keskinler and Z. Çelik, “Ozonation of aqueous Bomaplex Red Cr-L dye in a semi-batch reactor,” Dyes and Pigments, Vol. 64, pp. 101-108, 2005.
  • [4]. H. Zhiqiao, S. Shuang, Z. Huamin, Y. Haiping and C. Jianmeng, “C.I. Reactive Black 5 decolorization by combined sonolysis and ozonation,” Ultrasonics Sonochemistry, Vol. 14, pp. 298–304, 2007.
  • [5]. Z. Zakaria, W.Y.W. Ahmad, M.R. Yusop and M.R. Othman, “COD and color removal of Reactive Orange 16 dye solution by electrochemical oxidation and adsorption method,” in AIP Conference Proceedings, 1678, 050007, 1-6, 2015.
  • [6]. C. Tizaoui and N. Grima, “Kinetics of the ozone oxidation of Reactive Orange 16 azo-dye in aqueous solution,” Chemical Engineering Journal, Vol. 173, pp. 463-473, 2011.
  • [7]. S. Şahinkaya, “Decolorization of reactive orange 16 via ferrate(VI) oxidation assisted by sonication,” Turkish Journal of Chemistry, Vol. 41, pp. 577-586, 2017.
  • [8]. S. Venkatesh, A.R. Quaff, N.D. Pandey and K. Venkatesh, “Impact of ozonation on decolourization and mineralization of azo dyes: Biodegradability enhancement, by-products formation, required energy and cost,” Ozone: Science & Engineering, Vol. 37, pp. 420-430, 2015.
  • [9]. C. Wang, A. Yediler, D. Lienert, Z. Wang and A. Kettrup, “Ozonation of an azo dye C.I. Remazol Black 5 and toxicological assessment of its oxidation products,” Chemosphere, Vol. 52, pp. 1225-1232, 2003.
  • [10]. S. Venkatesh, K. Venkatesh and A.R. Quaff, “Dye decomposition by combined ozonation and anaerobic treatment: Cost effective technology,” Journal of Applied Research and Technology, Vol. 15, pp. 340-345, 2017.
  • [11]. htpps:/www.sigmaaldrich.com/. Available. (2018)
  • [12]. A.D. Eaton, L.S. Clesceri, E.W. Rice, A. E. Greenberg. Standart Methods for the Examination of Water & Wastewater, 21st Ed., [M. A. H. Franson (man. ed.)]. American Public Health Association, Washington, USA, 2005.
  • [13]. J. Staehelin, R.E. Bühler, and J.Hoigne, “Ozone decomposition in water studied by pulse radiolysis. 2. OH and HO4 as chain intermediates,” The Journal of Physical Chemistry, Vol. 88, pp. 5999-6004, 1984.
  • [14]. J. Staehelin and J.Hoigne, “Decomposition of ozone in water in the presence of organic solutes acting as promoters and inhibitors of radical chain reaction,” Environ. Sci. Technol., Vol. 19, pp. 1206-1213, 1985.
  • [15]. H. Tomiyasu, H. Fukutomi and G. Gordon, “Kinetics and mechanism of ozone decomposition in basic aqueous solution,” Inorganic Chemistry, Vol. 24, pp. 2962-2966, 1985.
  • [16]. A.Ö. Yıldırım, “ Investigation of the degradation of some reactive dyes by using advanced oxidation techniques,” PhD Thesis, University of Çukurova, Adana, Turkey, 2009.
  • [17]. B. Langlais, D.A. Reckhow and D.R. Brink. Ozone in Water Treatment Application and Engineering, Lewis Publishers, New York, USA, 1991.
  • [18]. H. Selçuk, “Decolorization and detoxification of textile wastewater by ozonation and coagulation processes,” Dyes and Pigments, Vol. 64, pp. 217-222, 2005.
  • [19]. H. Y. Shu andC.R. Huang, “Degradation of commercial azo dyes in water using ozonation and UV enhanced ozonation process,” Chemosphere, Vol. 31, pp. 3813-3825, 1995.
  • [20]. M. Muthukumar, D. Sargunamani and N. Selvakumar, “Statistical analysis of the effect of aromatic, azo and sulfonic acid groups on decolorization of aciddye effluents using advanced oxidation processes,” Dyes Pigments, Vol. 65, pp. 151-158, 2005.
  • [21]. T. Kabdaşlı, T. Ölmez and O. Tünay, “Factors affecting color removal from reactive dye bath by ozonation,” Water Science Technology, Vol. 45, pp. 261-270, 2002.
There are 21 citations in total.

Details

Primary Language English
Subjects Environmental Engineering
Journal Section Conference Paper
Authors

İrem Onder This is me

Okan Aydin This is me

Afife Guvenc

Publication Date December 1, 2018
Submission Date June 28, 2018
Acceptance Date October 25, 2018
Published in Issue Year 2018 Volume: 1 Issue: 4

Cite

APA Onder, İ., Aydin, O., & Guvenc, A. (2018). Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation. Environmental Research and Technology, 1(4), 6-13.
AMA Onder İ, Aydin O, Guvenc A. Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation. ERT. December 2018;1(4):6-13.
Chicago Onder, İrem, Okan Aydin, and Afife Guvenc. “Decolorization of Reactive Orange 16 and Reactive Black 5 in Aqueous Solution by Ozonation”. Environmental Research and Technology 1, no. 4 (December 2018): 6-13.
EndNote Onder İ, Aydin O, Guvenc A (December 1, 2018) Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation. Environmental Research and Technology 1 4 6–13.
IEEE İ. Onder, O. Aydin, and A. Guvenc, “Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation”, ERT, vol. 1, no. 4, pp. 6–13, 2018.
ISNAD Onder, İrem et al. “Decolorization of Reactive Orange 16 and Reactive Black 5 in Aqueous Solution by Ozonation”. Environmental Research and Technology 1/4 (December 2018), 6-13.
JAMA Onder İ, Aydin O, Guvenc A. Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation. ERT. 2018;1:6–13.
MLA Onder, İrem et al. “Decolorization of Reactive Orange 16 and Reactive Black 5 in Aqueous Solution by Ozonation”. Environmental Research and Technology, vol. 1, no. 4, 2018, pp. 6-13.
Vancouver Onder İ, Aydin O, Guvenc A. Decolorization of Reactive Orange 16 and Reactive Black 5 in aqueous solution by ozonation. ERT. 2018;1(4):6-13.