Research Article
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Year 2025, Volume: 8 Issue: 2, 245 - 254, 30.06.2025
https://doi.org/10.35208/ert.1498026

Abstract

Project Number

Not Applicable

References

  • M. G. Kibria, N. I. Masuk, R. Safayet, H. Q. Nguyen, and M. Mourshed, “Plastic Waste: Challenges and Opportunities to Mitigate Pollution and Effective Management,” Int. J. Environ. Res., vol. 17(1), p. 20, 2023.
  • J. Simitzis and D. Fountas, “Utilization of wastes of foam polystyrene as sorbents,” J. Appl. Polym. Sci., vol. 55 (6), pp. 879–887, 1995.
  • J. Bartram, L. Fewtrell, and T.-A. Stenstrom, “Harmonised assessment of risk and risk management for water-related infectious disease: an overview. In Water Quality: Guidelines, Standards and Health – Assessment of risk and risk management for water-related infectious disease. (eds L. Fewtrell and J.,” Water Qual. Guidel. Stand. Heal., pp. 1–16, 2001.
  • T. A. Moghny, “Preparation of sorbent materials for the removal of hardness and organic pollutants from water and wastewater,” vol. 11(5), pp. 461–468, 2017.
  • Z. Zhao and X. Wang, “Application of AnMBR Ion Exchange Technology in Water Treatment,” IOP Conf. Ser. Earth Environ. Sci., vol. 791(1), 2021.
  • J. N. Apell and T. H. Boyer, “Combined ion exchange treatment for removal of dissolved organic matter and hardness,” Water Res., vol. 44(8), pp. 2419–2430, 2010.
  • S. Rengaraj, K.-H. Yeon, and S.-H. Moon, “Removal of chromium from water and wastewater by ion exchange resins,” J. Hazard. Mater., vol. 87 (1), pp. 273–287, 2001.
  • A. Da̧browski, Z. Hubicki, P. Podkościelny, and E. Robens, “Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method,” Chemosphere, vol. 56(2), pp. 91–106, 2004.
  • S. M. Moosavirad, R. Sarikhani, E. Shahsavani, and S. Z. Mohammadi, “Removal of some heavy metals from inorganic industrial wastewaters by ion exchange method,” J. Water Chem. Technol., vol. 37(4), pp. 191–199, 2015.
  • P. Pentamwa, W. Thipthara, and S. Nuangon, “Removal of Hardness from Groundwater by Synthetic Resin from Waste Plastics,” Int. J. Environ. Sci. Dev., vol. 19, pp. 479–482, 2011.
  • E. Nassef, M. Mousa, D. Elgayar, and M. Hussein, “A Novel Technique for Water Hardness Removal by Using Polystyrene,” Aust. J. Basic Appl. Sci., vol. 12(7), pp. 126–138, 2018.
  • I. Bekri-Abbes, S. Bayoudh, and M. Baklouti, “A technique for purifying wastewater with polymeric flocculantproduced from waste plastic,” Desalination, vol. 204, pp. 198–203, 2007.
  • D. M. Hussein, D. E. Nassef, and M. A. Ibrahim, “Water Hardness Removal by Using Waste Polystyrene,” SDRP J. Nano Technol. Mater. Sci., vol. 1(1), pp. 40–44, 2016.
  • Y. Hailu, E. Tilahun, A. Brhane, H. Resky, and O. Sahu, “Ion exchanges process for calcium, magnesium and total hardness from ground water with natural zeolite,” Groundw. Sustain. Dev., vol. 8, pp. 457–467, 2019.
  • I. Bekri-Abbes, S. Bayoudh, and M. Baklouti, “Converting waste polystyrene into adsorbent: Potential use in the removal of lead and cadmium ions from aqueous solution,” J. Polym. Environ., vol. 14(3), pp. 249–256, 2006.
  • M. Moubark, T. A. Moghny, M. A. Mousa, A.-H. A.-A. El-Bellihi, and A. E. Awadallah, “Sulfonated Ion Exchange Polystyrene Composite Resin for Calcium Hardness Removal,” Int. J. Emerg. Technol. Adv. Eng., vol. 5, pp. 20–29, 2015.
  • M. R. Kazimi, T. Shah, S. Shima Binti Jamari, I. Ahmed, and C. Ku Mohammad Faizal, “Sulfonation of low-density polyethylene and its impact on polymer properties,” Polym. Eng. Sci., vol. 54(11), pp. 2522–2530, 2014.
  • M. Madhukar, S. P. Manjunath, and R. V. Gopal, “Preliminary studies on removal of nitrate and hardness from ground water using polystyrene beads,” Water Supply, vol. 14(2), pp. 299–303, 2014.
  • W. Bajdur, J. Pajączkowska, B. Makarucha, A. Sułkowska, and W. W. Sułkowski, “Effective polyelectrolytes synthesised from expanded polystyrene wastes,” Eur. Polym. J., vol. 38(2), pp. 299–304, 2002.
  • H. Tabekh, M. H. Al Kurdi, and Z. Ajji, “Sulphonation of expanded polystyrene waste with commercial sulphuric acid for potential use in removal of heavy metals from contaminated waters,” Polimeri, vol. 36(1), pp. 11–14, 2015.
  • Y. Inagaki, M. Kuromiya, T. Noguchi, and H. Watanabe, “Reclamation of waste polystyrene by sulfonation,” Langmuir, vol. 15(2), pp. 4171–4175, 1999.
  • L. B. Tran, T. T. Nguyen, S. Padungthon, T. T. Le, Q. A. Nguyen Thi, and N. H. Nguyen, “Advanced natural hydrated iron-alum oxides cation exchange resin for simultaneous phosphate and hardness removal,” npj Clean Water, vol. 5(1), p. 43, 2022.
  • S. Farmanbordar, D. Kahforoushan, and E. Fatehifar, “A new method in the removal of Ca and Mg ions from industrial wastewater,” Desalin. Water Treat., vol. 57(19), pp. 8904–8910, 2016.
  • N. Nori Ismail, “Experimental study on Ion Exchange Rate of Calcium Hardness in Water softening process Using Strong Acid Resin DOWEX HCR S/S,” Coll. Eng. J., vol. 91(1), pp. 107–114, 2016.
  • I. Bekri-Abbes, S. Bayoudh, and M. Baklouti, “The removal of hardness of water using sulfonated waste plastic,” Desalination, vol. 222, pp. 81–86, 2008.
  • D. Ruziwa, N. Chaukura, W. Gwenzi, and I. Pumure, “Removal of Zn2+ and Pb2+ ions from aqueous solution using sulphonated waste polystyrene,” J. Environ. Chem. Eng., vol. 3(4), pp. 2528–2537, 2015.

Sulfonated plastic waste: A solution for water hardness reduction

Year 2025, Volume: 8 Issue: 2, 245 - 254, 30.06.2025
https://doi.org/10.35208/ert.1498026

Abstract

This study focused on the utilisation of waste plastic as an ion exchanger to reduce water hardness. The three identical glass columns R1, R2, and R3 were used, each containing different types of waste plastic resin, such as styrofoam resin (SR), air bubble plastic resin (AR), or a mixture of both resins (MR), respectively. The plastics underwent a sulfonation process after crushing and sieving; their sulfonation was confirmed using FTIR analysis. For lab-scale experiments, each glass column was filled with sand, gravel, and coconut fiber as supporting media and equipped with a pump and flow-control valves. Groundwater collected from an urban area was passed through the columns at different flow rates and contact times. The process takes place by exchanging the Na+ ions of resins with polluting ions present in hard water. The treatment parameters involved are total hardness, calcium hardness, magnesium hardness, chloride, TDS, and pH. During the treatment process, pH was maintained between 7 and 8.5. All the parameters were tested twice, and the average of the observations was noted. The results showed that the maximum total hardness reduction achieved in reactors R1, R2, and R3 was 63%, 52%, and 58.6%, respectively, at a contact time of 24 h.

Ethical Statement

Not Applicable

Supporting Institution

Not Applicable

Project Number

Not Applicable

Thanks

Not Applicable

References

  • M. G. Kibria, N. I. Masuk, R. Safayet, H. Q. Nguyen, and M. Mourshed, “Plastic Waste: Challenges and Opportunities to Mitigate Pollution and Effective Management,” Int. J. Environ. Res., vol. 17(1), p. 20, 2023.
  • J. Simitzis and D. Fountas, “Utilization of wastes of foam polystyrene as sorbents,” J. Appl. Polym. Sci., vol. 55 (6), pp. 879–887, 1995.
  • J. Bartram, L. Fewtrell, and T.-A. Stenstrom, “Harmonised assessment of risk and risk management for water-related infectious disease: an overview. In Water Quality: Guidelines, Standards and Health – Assessment of risk and risk management for water-related infectious disease. (eds L. Fewtrell and J.,” Water Qual. Guidel. Stand. Heal., pp. 1–16, 2001.
  • T. A. Moghny, “Preparation of sorbent materials for the removal of hardness and organic pollutants from water and wastewater,” vol. 11(5), pp. 461–468, 2017.
  • Z. Zhao and X. Wang, “Application of AnMBR Ion Exchange Technology in Water Treatment,” IOP Conf. Ser. Earth Environ. Sci., vol. 791(1), 2021.
  • J. N. Apell and T. H. Boyer, “Combined ion exchange treatment for removal of dissolved organic matter and hardness,” Water Res., vol. 44(8), pp. 2419–2430, 2010.
  • S. Rengaraj, K.-H. Yeon, and S.-H. Moon, “Removal of chromium from water and wastewater by ion exchange resins,” J. Hazard. Mater., vol. 87 (1), pp. 273–287, 2001.
  • A. Da̧browski, Z. Hubicki, P. Podkościelny, and E. Robens, “Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method,” Chemosphere, vol. 56(2), pp. 91–106, 2004.
  • S. M. Moosavirad, R. Sarikhani, E. Shahsavani, and S. Z. Mohammadi, “Removal of some heavy metals from inorganic industrial wastewaters by ion exchange method,” J. Water Chem. Technol., vol. 37(4), pp. 191–199, 2015.
  • P. Pentamwa, W. Thipthara, and S. Nuangon, “Removal of Hardness from Groundwater by Synthetic Resin from Waste Plastics,” Int. J. Environ. Sci. Dev., vol. 19, pp. 479–482, 2011.
  • E. Nassef, M. Mousa, D. Elgayar, and M. Hussein, “A Novel Technique for Water Hardness Removal by Using Polystyrene,” Aust. J. Basic Appl. Sci., vol. 12(7), pp. 126–138, 2018.
  • I. Bekri-Abbes, S. Bayoudh, and M. Baklouti, “A technique for purifying wastewater with polymeric flocculantproduced from waste plastic,” Desalination, vol. 204, pp. 198–203, 2007.
  • D. M. Hussein, D. E. Nassef, and M. A. Ibrahim, “Water Hardness Removal by Using Waste Polystyrene,” SDRP J. Nano Technol. Mater. Sci., vol. 1(1), pp. 40–44, 2016.
  • Y. Hailu, E. Tilahun, A. Brhane, H. Resky, and O. Sahu, “Ion exchanges process for calcium, magnesium and total hardness from ground water with natural zeolite,” Groundw. Sustain. Dev., vol. 8, pp. 457–467, 2019.
  • I. Bekri-Abbes, S. Bayoudh, and M. Baklouti, “Converting waste polystyrene into adsorbent: Potential use in the removal of lead and cadmium ions from aqueous solution,” J. Polym. Environ., vol. 14(3), pp. 249–256, 2006.
  • M. Moubark, T. A. Moghny, M. A. Mousa, A.-H. A.-A. El-Bellihi, and A. E. Awadallah, “Sulfonated Ion Exchange Polystyrene Composite Resin for Calcium Hardness Removal,” Int. J. Emerg. Technol. Adv. Eng., vol. 5, pp. 20–29, 2015.
  • M. R. Kazimi, T. Shah, S. Shima Binti Jamari, I. Ahmed, and C. Ku Mohammad Faizal, “Sulfonation of low-density polyethylene and its impact on polymer properties,” Polym. Eng. Sci., vol. 54(11), pp. 2522–2530, 2014.
  • M. Madhukar, S. P. Manjunath, and R. V. Gopal, “Preliminary studies on removal of nitrate and hardness from ground water using polystyrene beads,” Water Supply, vol. 14(2), pp. 299–303, 2014.
  • W. Bajdur, J. Pajączkowska, B. Makarucha, A. Sułkowska, and W. W. Sułkowski, “Effective polyelectrolytes synthesised from expanded polystyrene wastes,” Eur. Polym. J., vol. 38(2), pp. 299–304, 2002.
  • H. Tabekh, M. H. Al Kurdi, and Z. Ajji, “Sulphonation of expanded polystyrene waste with commercial sulphuric acid for potential use in removal of heavy metals from contaminated waters,” Polimeri, vol. 36(1), pp. 11–14, 2015.
  • Y. Inagaki, M. Kuromiya, T. Noguchi, and H. Watanabe, “Reclamation of waste polystyrene by sulfonation,” Langmuir, vol. 15(2), pp. 4171–4175, 1999.
  • L. B. Tran, T. T. Nguyen, S. Padungthon, T. T. Le, Q. A. Nguyen Thi, and N. H. Nguyen, “Advanced natural hydrated iron-alum oxides cation exchange resin for simultaneous phosphate and hardness removal,” npj Clean Water, vol. 5(1), p. 43, 2022.
  • S. Farmanbordar, D. Kahforoushan, and E. Fatehifar, “A new method in the removal of Ca and Mg ions from industrial wastewater,” Desalin. Water Treat., vol. 57(19), pp. 8904–8910, 2016.
  • N. Nori Ismail, “Experimental study on Ion Exchange Rate of Calcium Hardness in Water softening process Using Strong Acid Resin DOWEX HCR S/S,” Coll. Eng. J., vol. 91(1), pp. 107–114, 2016.
  • I. Bekri-Abbes, S. Bayoudh, and M. Baklouti, “The removal of hardness of water using sulfonated waste plastic,” Desalination, vol. 222, pp. 81–86, 2008.
  • D. Ruziwa, N. Chaukura, W. Gwenzi, and I. Pumure, “Removal of Zn2+ and Pb2+ ions from aqueous solution using sulphonated waste polystyrene,” J. Environ. Chem. Eng., vol. 3(4), pp. 2528–2537, 2015.
There are 26 citations in total.

Details

Primary Language English
Subjects Waste Management, Reduction, Reuse and Recycling
Journal Section Research Articles
Authors

Minjal Patel This is me 0009-0007-3983-1185

Bina Patel 0000-0002-3787-8496

Isha Lad This is me 0009-0001-9157-2797

Project Number Not Applicable
Publication Date June 30, 2025
Submission Date June 9, 2024
Acceptance Date August 20, 2024
Published in Issue Year 2025 Volume: 8 Issue: 2

Cite

APA Patel, M., Patel, B., & Lad, I. (2025). Sulfonated plastic waste: A solution for water hardness reduction. Environmental Research and Technology, 8(2), 245-254. https://doi.org/10.35208/ert.1498026
AMA Patel M, Patel B, Lad I. Sulfonated plastic waste: A solution for water hardness reduction. ERT. June 2025;8(2):245-254. doi:10.35208/ert.1498026
Chicago Patel, Minjal, Bina Patel, and Isha Lad. “Sulfonated Plastic Waste: A Solution for Water Hardness Reduction”. Environmental Research and Technology 8, no. 2 (June 2025): 245-54. https://doi.org/10.35208/ert.1498026.
EndNote Patel M, Patel B, Lad I (June 1, 2025) Sulfonated plastic waste: A solution for water hardness reduction. Environmental Research and Technology 8 2 245–254.
IEEE M. Patel, B. Patel, and I. Lad, “Sulfonated plastic waste: A solution for water hardness reduction”, ERT, vol. 8, no. 2, pp. 245–254, 2025, doi: 10.35208/ert.1498026.
ISNAD Patel, Minjal et al. “Sulfonated Plastic Waste: A Solution for Water Hardness Reduction”. Environmental Research and Technology 8/2 (June 2025), 245-254. https://doi.org/10.35208/ert.1498026.
JAMA Patel M, Patel B, Lad I. Sulfonated plastic waste: A solution for water hardness reduction. ERT. 2025;8:245–254.
MLA Patel, Minjal et al. “Sulfonated Plastic Waste: A Solution for Water Hardness Reduction”. Environmental Research and Technology, vol. 8, no. 2, 2025, pp. 245-54, doi:10.35208/ert.1498026.
Vancouver Patel M, Patel B, Lad I. Sulfonated plastic waste: A solution for water hardness reduction. ERT. 2025;8(2):245-54.