Yeni Tip Kaliks[4]aren Temelli Bütünüyle Katı-Hal PVC Membrane Cu(II) Seçici Potansiyometrik Mikrosensör

Year 2024, , 460 - 473, 31.08.2024

Çiğdem Çay , Murat Yolcu , Serkan Sayın

https://doi.org/10.18185/erzifbed.1478285

Abstract

All-Solid-State PVC-Membrane Cu(II)-Selective Potentiometric Microsensor Based on a Novel Calix[4]arene Derivative

Abstract

In this study, 25,27-dihydroxy-26,28-bis(ethoxycarbonylbutyoxy)-5,11,17,23-p-tert-butylcalix[4]arene was used as an ionophore for the preparation of a novel all-solid-state type microsensor to make a selective potentiometric response towards Cu(II) ions. The optimum membrane composition of the microsensor was determined as 2% (w/w) ionophore, 67% (w/w) bis (2-ethylhexyl) sebacate (DOS), 30% (w/w) polyvinylchloride (PVC), and 1%(w/w) potassium tetrakis 4-chlorophenyl borate (KTpClPB). The Cu(II)-selective microsensor exhibited a highly selective Nernstian response of 31.3±2.1 mV slope (R2: 0.997) with a short response time (15 s) over the concentration range of 10−5 to 10−1 mol L−1 of Cu(II) ions for 8 weeks with no significant difference in potentials. The microsensor was effectively performed in the pH range of 5.0–8.0, with low detection limit as 7.63×10−7 mol L−1, and a temperature range of 15−40 °C. The prepared microsensor was successfully used both as an indicator electrode in the potentiometric titration of Cu(II) ions with EDTA and also in the determination of the Cu(II) content of environmental water samples. When the potentiometric results were compared with ICP-OES, they were found to be in good agreement with ICP-OES results at a 95% confidence level.

Keywords

Calixarene, all-solid-state, ion-selective sensor, copper, PVC membrane

References

• [1] N. Dere, Z. Yolcu, M. Yolcu, A Novel Solid-State PVC-Membrane Potentiometric Dopamine-Selective Sensor Based on Molecular Imprinted Polymer, Acta Chim Slov, 69 (2022) 108-115.
• [2] O. Özbek, Ö. Isildak, Potentiometric determination of copper(II) ions based on a porphyrin derivative, J Chin Chem Soc-Taip, 69 (2022) 1060-1069.
• [3] M. Yolcu, N. Dere, A novel copper selective sensor based on ion imprinted 2-vinylpyridine polymer, Can J Chem, 96 (2018) 1027-1036.
• [4] C.J. Mei, S.A.A. Ahmad, A review on the determination heavy metals ions using calixarene-based electrochemical sensors, Arab J Chem, 14 (2021).
• [5] M.S. Engin, S. Sayin, S. Cay, E. Kir, T. Sardohan-Koseoglu, Preparation and characterisation of thiol functionalised-butylcalix[4]arene-embedded polymer inclusion membranes: performance and selectivity, Int J Environ an Ch, 99 (2019) 1103-1111.
• [6] V.K. Gupta, S. Kumar, R. Singh, L.P. Singh, S.K. Shoora, B. Sethi, Cadmium (II) ion sensing through p-butyl calix[6]arene based potentiometric sensor, J Mol Liq, 195 (2014) 65-68.
• [7] L.X. Chen, H.F. Ju, X.S. Zeng, X.W. He, Z.Z. Zhang, Silver ion-selective electrodes based on novel containing benzothiazolyl calix[4]arene, Anal Chim Acta, 437 (2001) 191-197.
• [8] B. Sonmez, S. Sayin, E. E. Yalcinkaya, D. A. Seleci, H. B. Yildiz, D. O. Demirkol, S. Timur, Calixarene modified montmorillonite: a novel design for biosensing applications. RSC Adv., 2014, 4, 62895–62902
• [9] H. E. K. Ertürün, A.D. Özel, S. Sayın, M. Yılmaz, E. Kılıç, Development of a pH sensing membrane electrode based on a new calix[4]arene derivative. Talanta132(2015)669–675.;
• [10] S. Kucukkolbasi, S. Sayin, M. Yilmaz, Fabrication and Application of a New Modified Electrochemical Sensor Using Newly Synthesized Calixarene-Grafted Mwcnts for Simultaneous Determination of Cu(II) and Pb(II). Acta Chim. Slov. 2019, 66, 839–849.;
• [11] S. Sayin, S. Cay, Novel An Efficient Fluorescent Probe Based on Calix[4]triazacrown‑5 With Naphthalimide Group for Co2+, Cd2+ and Dopamine Detection. Journal of Fluorescence (2024) 34:729–741
• [12] P. Kumar, All Solid State Nickel(II)-Selective Potentiometric Sensor Based on an Upper Rim Substituted Calixarene, Electroanal, 24 (2012) 2005-2012.
• [13] C. Wardak, M. Grabarczyk, Analytical application of solid contact ion-selective electrodes for determination of copper and nitrate in various food products and drinking water, J Environ Sci Heal B, 51 (2016) 519-524.
• [14] K. Pietrzak, C. Wardak, B. Cristóvao, Copper ion-selective electrodes based on newly synthesized salen-type Schiff bases and their complexes, Ionics, 28 (2022) 2423-2435.
• [15] M. Bost, S. Houdart, M. Oberli, E. Kalonji, J.F. Huneau, I. Margaritis, Dietary copper and human health: Current evidence and unresolved issues, J Trace Elem Med Bio, 35 (2016) 107-115.
• [16] C. Wardak, J. Lenik, Application of ionic liquid to the construction of Cu(II) ion-selective electrode with solid contact, Sensor Actuat B-Chem, 189 (2013) 52-59.
• [17] V.K. Gupta, R. Prasad, A. Kumar, Preparation of ethambutol-copper(II) complex and fabrication of PVC based membrane potentiometric sensor for copper, Talanta, 60 (2003) 149-160.
• [18] L.P. Singh, J.M. Bhatnagar, Copper(II) selective electrochemical sensor based on Schiff Base complexes, Talanta, 64 (2004) 313-319.
• [19] C.D. Gutsche, K.C. Nam, Calixarenes .22. Synthesis, Properties, and Metal Complexation of Aminocalixarenes, J Am Chem Soc, 110 (1988) 6153-6162.
• [20] K. Kurzatkowska, S. Sayin, M. Yilmaz, H. Radecka, J. Radecki, Calix[4]arene derivatives as dopamine hosts in electrochemical sensors, Sensor Actuat B-Chem, 218 (2015) 111-121.
• [21] I. Bitter, A. Grün, G. Toth, B. Balazs, G. Horvath, L. Töke, Studies on CaIix(aza)crowus, II.I Synthesis of Novel Proximal Doubly Bridged CalixlrlJareaes by Intramolecular Ring Closure of syn l,3- and 1,2- ω- Chtoroalkylamides. Tetrahedron 54 (1998) 3857-3870.
• [22] I. Isildak, M. Yolcu, O. Isildak, N. Demirel, G. Topal, H. Hosgoren, All-solid-state PVC membrane Ag-selective electrodes based on diaza-18-crown-6 compounds, Microchim Acta, 144 (2004) 177-181.
• [23] P. R. Buck and E. Lindner, “Recommendations for Nomenclature of Ionselective Electrodes,” Pure and Applied Chemistry, 66-12 (1994) 2527-2536.
• [24] O. Özbek, M.B. Gürdere, C. Berkel, Ö. Isildak, Electroanalytical Determination of Copper(II) Ions Using a Polymer Membrane Sensor, J Electrochem Sci Te, 14 (2023) 66-74.
• [25] K. Udomphan, I. Sontawee, I. Dangsanga, 8-Hydroxyquinoline intercalated montmorillonite composite: characterization and application for copper ion determination as potentiometric electrode, J Solid State Electr, 27 (2023) 977-989.
• [26] S. Kaur, J. Kaur, M. Rana, J. Sharma, I. Kaur, Salicylaldehyde based Schiff base: synthesis, characterisation and application for selective electrochemical detection of Cu in real samples, Int J Environ an Ch, (2023).
• [27] M.A. Abu-Dalo, A.A. Salam, N.S. Nassory, Ion Imprinted Polymer Based Electrochemical Sensor for Environmental Monitoring of Copper(II), Int J Electrochem Sc, 10 (2015) 6780-6793.
• [28] V.K. Gupta, L.P. Singh, R. Singh, N. Upadhyay, S.P. Kaur, B. Sethi, A novel copper (II) selective sensor based on Dimethyl 4, 4′ (o-phenylene) bis(3-thioallophanate) in PVC matrix, J Mol Liq, 174 (2012) 11-16.