Research Article
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Investigation of Isotherm Data for Biosorption of Eosin Y Dye from Aqueous Solution using Tea Stem Pruning Wastes

Year 2020, , 274 - 282, 20.03.2020
https://doi.org/10.18185/erzifbed.571429

Abstract

In
this study, by evaluating the low-cost, abundant, efficient and
environment-friendly bio-waste obtained from the waste of tea stem, it has been
ensured that this waste will be an alternative to the current expensive methods
and raw materials in terms of the removal of environmental pollutants. Eosin Y
(EY) adsorption from the aqueous solution, the effects of various parameters
such as adsorbent dosage, interaction time and pH were investigated and optimum
experimental conditions were determined. In the Langmuir isotherm model,
experimental results were obtained at a maximum adsorption capacity of 3.56
mg/g at 25 ° C. In the light of the data, it was determined that the Freundlich
model is more compatible with the experimental data. It is concluded that tea
stem can be applied as an option since it is a low cost and natural product for
removing EY from aqueous solution, compared with the present research and other
adsorbents reported in the literature

References

  • Akar, S. T., Celik, S., Tunc, D., Balk, Y. Y., & Akar, T. (2016). Biosorption potential of surface-modified waste sugar beet pulp for the removal of Reactive Yellow 2 (RY2) anionic dye. Turkish Journal of Chemistry, 40(6), 1044-1054. Retrieved from <Go to ISI>://WOS:000390326500018
  • Al-Ghouti, M. A., Khraisheh, M. A. M., Allen, S. J., & Ahmad, M. N. (2003). The removal of dyes from textile wastewater: a study of the physical characteristics and adsorption mechanisms of diatomaceous earth. Journal of Environmental Management, 69(3), 229-238. Retrieved from <Go to ISI>://WOS:000187208500002
  • Bai, H. H., Zhang, Q. S., He, T., Zheng, G., Zhang, G. Q., Zheng, L. B., & Ma, S. Q. (2016). Adsorption dynamics, diffusion and isotherm models of poly(NIPAm/LMSH) nanocomposite hydrogels for the removal of anionic dye Amaranth from an aqueous solution. Applied Clay Science, 124, 157-166. Retrieved from <Go to ISI>://WOS:000375162300019
  • Bazylevich, A., Patsenker, L. D., & Gellerman, G. (2017). Exploiting fluorescein based drug conjugates for fluorescent monitoring in drug delivery. Dyes and Pigments, 139, 460-472.
  • Cyprych, K., Kopczyńska, Z., Kajzar, F., Rau, I., & Mysliwiec, J. (2015). Tunable wavelength light emission and amplification in Rhodamine 6G aggregates. Advanced Device Materials, 1(2), 69-73. doi:10.1179/2055031615Y.0000000004
  • Dai, Y., Sun, Q., Wang, W., Lu, L., Liu, M., Li, J., . . . Xu, J. (2018). Utilizations of agricultural waste as adsorbent for the removal of contaminants: A review. Chemosphere.
  • Errais, E., Duplay, J., Darragi, F., M'Rabet, I., Aubert, A., Huber, F., & Morvan, G. (2011). Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters. Desalination, 275(1-3), 74-81. Retrieved from <Go to ISI>://WOS:000292584900009
  • Kamkaew, A., Lim, S. H., Lee, H. B., Kiew, L. V., Chung, L. Y., & Burgess, K. (2013). BODIPY dyes in photodynamic therapy. Chemical Society Reviews, 42(1), 77-88. Retrieved from <Go to ISI>://WOS:000311968700006
  • Kaushik, P., Mishra, A., Malik, A., & Pant, K. K. (2014). Biosorption of Textile Dye by Aspergillus lentulus Pellets: Process Optimization and Cyclic Removal in Aerated Bioreactor. Water Air and Soil Pollution, 225(6). Retrieved from <Go to ISI>://WOS:000338334200017
  • Lin, Y. C., Ma, J., Liu, W., Li, Z. Y., & He, K. (2019). Efficient removal of dyes from dyeing wastewater by powder activated charcoal/titanate nanotube nanocomposites: adsorption and photoregeneration. Environmental Science and Pollution Research, 26(10), 10263-10273. Retrieved from <Go to ISI>://WOS:000464852200075
  • Moghazy, R. M. (2019). Activated biomass of the green microalga Chlamydomonas variabilis as an efficient biosorbent to remove methylene blue dye from aqueous solutions. Water Sa, 45(1), 20-28. Retrieved from <Go to ISI>://WOS:000457592900003
  • Molupe, N., Babu, B., Oluwole, D. O., Prinsloo, E., Mack, J., & Nyokong, T. (2018). The investigation of in vitro dark cytotoxicity and photodynamic therapy effect of a 2,6-dibromo-3,5-distyryl BODIPY dye encapsulated in Pluronic (R) F-127 micelles. Journal of Coordination Chemistry, 71(21), 3444-3457. Retrieved from <Go to ISI>://WOS:000461451600002
  • Oymak, T., & Eruygur, N. (2019). Effective and rapid removal of cationic and anionic dyes from aqueous solutions using Elaeagnus angustifolia L. fruits as a biosorbent. Desalination and Water Treatment, 138, 257-264. Retrieved from <Go to ISI>://WOS:000454437500028
  • Patil, N. N., & Datar, A. G. (2016). Applications of natural dye from Ixora coccinea L. in the field of textiles and cosmetics. Coloration Technology, 132(1), 98-103.
  • Ponnusami, A. B., Kumar, S., & Bansal, P. (2018). Biosorption and kinetic studies of Malachite Green (MG) dye removal from aqueous solution using a low-cost adsorbent prepared from male palm tree flower (Borassus flabellifer). Desalination and Water Treatment, 121, 219-232. Retrieved from <Go to ISI>://WOS:000446586600030
  • Raj, R. A., Manimozhi, V., & Saravanathamizhan, R. (2019). Adsorption studies on removal of Congo red dye from aqueous solution using petroleum coke. Petroleum Science and Technology, 37(8), 913-924. Retrieved from <Go to ISI>://WOS:000463851200007
  • Rapo, E., Szep, R., Keresztesi, A., Suciu, M., & Tonk, S. (2018). Adsorptive Removal of Cationic and Anionic Dyes from Aqueous Solutions by Using Eggshell Household Waste as Biosorbent. Acta Chimica Slovenica, 65(3), 709-717. Retrieved from <Go to ISI>://WOS:000444705500025
  • Shak, A., Dawood, S., & Sen, T. K. (2017). Performance and dynamic modelling of mixed biomass-kaolin packed bed adsorption column for the removal of aqueous phase methylene blue (MB) dye. Desalination and Water Treatment, 82, 67-80. Retrieved from <Go to ISI>://WOS:000410814600008
  • Sharma, S., Hasan, A., Kumar, N., & Pandey, L. M. (2018). Removal of methylene blue dye from aqueous solution using immobilized Agrobacterium fabrum biomass along with iron oxide nanoparticles as biosorbent. Environmental Science and Pollution Research, 25(22), 21605-21615. Retrieved from <Go to ISI>://WOS:000440115600033
  • Singh, H., Chauhan, G., Jain, A. K., & Sharma, S. (2017). Adsorptive potential of agricultural wastes for removal of dyes from aqueous solutions. Journal of environmental chemical engineering, 5(1), 122-135.
  • Subramaniam, R., & Ponnusamy, S. K. (2015). Novel adsorbent from agricultural waste (cashew NUT shell) for methylene blue dye removal: optimization by response surface methodology. Water Resources and Industry, 11, 64-70.
  • Zhou, L., Zhou, H. J., Hu, Y. X., Yan, S., & Yang, J. L. (2019). Adsorption removal of cationic dyes from aqueous solutions using ceramic adsorbents prepared from industrial waste coal gangue. Journal of Environmental Management, 234, 245-252. Retrieved from <Go to ISI>://WOS:00046019500002

Çay Çalısı Budama Atıkları Kullanılarak Eosin Y Boyarmaddesinin Sulu Çözeltiden Biyosorpsiyonu için İzoterm Verilerinin İncelenmesi

Year 2020, , 274 - 282, 20.03.2020
https://doi.org/10.18185/erzifbed.571429

Abstract

Bu çalışmada, atık çay çalısından
elde edilen düşük maliyetli, bol miktarda bulunan, verimli ve çevre dostu bir
biyo-atık, adsorban olarak değerlendirilmiştir. Çevreyi kirleten maddelerin
giderimleri için bu çalışmada kullanılan doğal ürün, mevcut pahalı yöntem ve
hammaddelerine alternatif olarak sunulmuştur. Eosin Y (EY) sulu çözeltiden
adsorpsiyonunda, etkileşim süresi, pH, adsorban miktarı vb. gibi çeşitli
parametrelerin etkileri incelenmiş ve optimum deney koşulları ortaya konmuştur.
Deneysel sonuçlar ışığında, Langmuir izoterm modelinde, 25°C'da maksimum
adsorpsiyon kapasitesi 3,56 mg/g olarak hesaplanmıştır. Veriler ışığında
Freundlich modelinin deneysel verilerle daha iyi bir uyum sağladığı tespit
edilmiştir. Mevcut araştırmalar ve bildirilen diğer adsorbanlarla
karşılaştırıldığında, çay çalısının, sulu çözeltiden EY'nin giderilmesi için
düşük maliyetli doğal ürün olması sebebiyle, bir seçenek olarak
uygulanabileceği sonucuna varılmıştır.

References

  • Akar, S. T., Celik, S., Tunc, D., Balk, Y. Y., & Akar, T. (2016). Biosorption potential of surface-modified waste sugar beet pulp for the removal of Reactive Yellow 2 (RY2) anionic dye. Turkish Journal of Chemistry, 40(6), 1044-1054. Retrieved from <Go to ISI>://WOS:000390326500018
  • Al-Ghouti, M. A., Khraisheh, M. A. M., Allen, S. J., & Ahmad, M. N. (2003). The removal of dyes from textile wastewater: a study of the physical characteristics and adsorption mechanisms of diatomaceous earth. Journal of Environmental Management, 69(3), 229-238. Retrieved from <Go to ISI>://WOS:000187208500002
  • Bai, H. H., Zhang, Q. S., He, T., Zheng, G., Zhang, G. Q., Zheng, L. B., & Ma, S. Q. (2016). Adsorption dynamics, diffusion and isotherm models of poly(NIPAm/LMSH) nanocomposite hydrogels for the removal of anionic dye Amaranth from an aqueous solution. Applied Clay Science, 124, 157-166. Retrieved from <Go to ISI>://WOS:000375162300019
  • Bazylevich, A., Patsenker, L. D., & Gellerman, G. (2017). Exploiting fluorescein based drug conjugates for fluorescent monitoring in drug delivery. Dyes and Pigments, 139, 460-472.
  • Cyprych, K., Kopczyńska, Z., Kajzar, F., Rau, I., & Mysliwiec, J. (2015). Tunable wavelength light emission and amplification in Rhodamine 6G aggregates. Advanced Device Materials, 1(2), 69-73. doi:10.1179/2055031615Y.0000000004
  • Dai, Y., Sun, Q., Wang, W., Lu, L., Liu, M., Li, J., . . . Xu, J. (2018). Utilizations of agricultural waste as adsorbent for the removal of contaminants: A review. Chemosphere.
  • Errais, E., Duplay, J., Darragi, F., M'Rabet, I., Aubert, A., Huber, F., & Morvan, G. (2011). Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters. Desalination, 275(1-3), 74-81. Retrieved from <Go to ISI>://WOS:000292584900009
  • Kamkaew, A., Lim, S. H., Lee, H. B., Kiew, L. V., Chung, L. Y., & Burgess, K. (2013). BODIPY dyes in photodynamic therapy. Chemical Society Reviews, 42(1), 77-88. Retrieved from <Go to ISI>://WOS:000311968700006
  • Kaushik, P., Mishra, A., Malik, A., & Pant, K. K. (2014). Biosorption of Textile Dye by Aspergillus lentulus Pellets: Process Optimization and Cyclic Removal in Aerated Bioreactor. Water Air and Soil Pollution, 225(6). Retrieved from <Go to ISI>://WOS:000338334200017
  • Lin, Y. C., Ma, J., Liu, W., Li, Z. Y., & He, K. (2019). Efficient removal of dyes from dyeing wastewater by powder activated charcoal/titanate nanotube nanocomposites: adsorption and photoregeneration. Environmental Science and Pollution Research, 26(10), 10263-10273. Retrieved from <Go to ISI>://WOS:000464852200075
  • Moghazy, R. M. (2019). Activated biomass of the green microalga Chlamydomonas variabilis as an efficient biosorbent to remove methylene blue dye from aqueous solutions. Water Sa, 45(1), 20-28. Retrieved from <Go to ISI>://WOS:000457592900003
  • Molupe, N., Babu, B., Oluwole, D. O., Prinsloo, E., Mack, J., & Nyokong, T. (2018). The investigation of in vitro dark cytotoxicity and photodynamic therapy effect of a 2,6-dibromo-3,5-distyryl BODIPY dye encapsulated in Pluronic (R) F-127 micelles. Journal of Coordination Chemistry, 71(21), 3444-3457. Retrieved from <Go to ISI>://WOS:000461451600002
  • Oymak, T., & Eruygur, N. (2019). Effective and rapid removal of cationic and anionic dyes from aqueous solutions using Elaeagnus angustifolia L. fruits as a biosorbent. Desalination and Water Treatment, 138, 257-264. Retrieved from <Go to ISI>://WOS:000454437500028
  • Patil, N. N., & Datar, A. G. (2016). Applications of natural dye from Ixora coccinea L. in the field of textiles and cosmetics. Coloration Technology, 132(1), 98-103.
  • Ponnusami, A. B., Kumar, S., & Bansal, P. (2018). Biosorption and kinetic studies of Malachite Green (MG) dye removal from aqueous solution using a low-cost adsorbent prepared from male palm tree flower (Borassus flabellifer). Desalination and Water Treatment, 121, 219-232. Retrieved from <Go to ISI>://WOS:000446586600030
  • Raj, R. A., Manimozhi, V., & Saravanathamizhan, R. (2019). Adsorption studies on removal of Congo red dye from aqueous solution using petroleum coke. Petroleum Science and Technology, 37(8), 913-924. Retrieved from <Go to ISI>://WOS:000463851200007
  • Rapo, E., Szep, R., Keresztesi, A., Suciu, M., & Tonk, S. (2018). Adsorptive Removal of Cationic and Anionic Dyes from Aqueous Solutions by Using Eggshell Household Waste as Biosorbent. Acta Chimica Slovenica, 65(3), 709-717. Retrieved from <Go to ISI>://WOS:000444705500025
  • Shak, A., Dawood, S., & Sen, T. K. (2017). Performance and dynamic modelling of mixed biomass-kaolin packed bed adsorption column for the removal of aqueous phase methylene blue (MB) dye. Desalination and Water Treatment, 82, 67-80. Retrieved from <Go to ISI>://WOS:000410814600008
  • Sharma, S., Hasan, A., Kumar, N., & Pandey, L. M. (2018). Removal of methylene blue dye from aqueous solution using immobilized Agrobacterium fabrum biomass along with iron oxide nanoparticles as biosorbent. Environmental Science and Pollution Research, 25(22), 21605-21615. Retrieved from <Go to ISI>://WOS:000440115600033
  • Singh, H., Chauhan, G., Jain, A. K., & Sharma, S. (2017). Adsorptive potential of agricultural wastes for removal of dyes from aqueous solutions. Journal of environmental chemical engineering, 5(1), 122-135.
  • Subramaniam, R., & Ponnusamy, S. K. (2015). Novel adsorbent from agricultural waste (cashew NUT shell) for methylene blue dye removal: optimization by response surface methodology. Water Resources and Industry, 11, 64-70.
  • Zhou, L., Zhou, H. J., Hu, Y. X., Yan, S., & Yang, J. L. (2019). Adsorption removal of cationic dyes from aqueous solutions using ceramic adsorbents prepared from industrial waste coal gangue. Journal of Environmental Management, 234, 245-252. Retrieved from <Go to ISI>://WOS:00046019500002
There are 22 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Makaleler
Authors

Mehmet Kaya 0000-0001-9680-3622

Publication Date March 20, 2020
Published in Issue Year 2020

Cite

APA Kaya, M. (2020). Çay Çalısı Budama Atıkları Kullanılarak Eosin Y Boyarmaddesinin Sulu Çözeltiden Biyosorpsiyonu için İzoterm Verilerinin İncelenmesi. Erzincan University Journal of Science and Technology, 13(1), 274-282. https://doi.org/10.18185/erzifbed.571429