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Elemental and Crystal Structure Properties on Milled Nanosize Colemanite Mineral

Year 2017, Volume: 10 Issue: 2, 303 - 313, 22.12.2017

Abstract

Colemanite minerals in three different
sizes (C-3 mm, C-75 µm and C-45 µm) were supplied from the Eti Mine Company. These
minerals were used as initial materials. It is well known that nanosize
materials have a lot of positive technical properties. Therefore, in this
study, C-3 mm mineral was ground by a high-energy ball mill in order to obtain
nanocrystallite sized colemanite. Afterwards, milled powder was passed through
a sieve of 25 µm of a vibratory sieve shaker (C-25 µm). Elemental properties of
initial materials and milled powder were investigated with an oxide compound
test and an energy dispersive spectrometer (EDS). Their crystal structure
properties were examined with an X-ray diffractometer (XRD). Results of elemental
property indicate that the materials were not pure colemanite compound and the amount
of boron oxide did not change significantly at the end of milling process.
Results of crystal structure property show that crystallite size of the
colemanite mineral at the end of milling process was reduced to nanoscale with
a value of 63.6 nm. The findings obtained from this study will be useful for future
science and engineering studies with not only colemanite mineral but also other
boron minerals.

References

  • Abdellahi, M., Bahmanpour, H. and Bahmanpour, M. 2014. The best conditions for minimizing the synthesis time of nanocomposites during high energy ball milling: Modeling and optimizing, Ceramics International, 40 (7 Part A), 9675–9692.
  • Alam, S. N. 2006. Synthesis and characterization of W-Cu nanocomposites developed by mechanical alloying, Materials Science and Engineering A, 433(1–2), 161–168.
  • Alizadeh, M., Sharifianjazi, F., Haghshenasjazi, E., Aghakhani, M. and Rajabi, L. 2015. Production of nanosized boron oxide powder by high-energy ball milling, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 45(1), 11–14.
  • Bayca, S. U., Kocan, F. and Abali, Y. 2014. Investigation of leaching kinetics of ulexite waste in oxalic acid solutions, Chemical and Biochemical Engineering Quarterly, 28(3), 273–280.
  • Canakci, A., Varol, T., Cuvalci, H., Erdemir, F., Ozkaya, S. and Yalcin, E. D. 2014. Synthesis of novel CuSn10-graphite nanocomposite powders by mechanical alloying, Micro and Nano Letters, 9(2), 109–112.
  • Demir, F. and Un, A. 2013. Radiation transmission of colemanite, tincalconite and ulexite for 6 and 18MV X-rays by using linear accelerator, Applied Radiation and Isotopes, 72, 1–5.
  • Emrullahoglu Abi, C. B. 2014. Effect of borogypsum on brick properties, Construction and Building Materials, 59, 195–203.
  • Eskibalci, M. F. and Ozkan, S. G. 2012. An investigation of effect of microwave energy on electrostatic separation of colemanite and ulexite, Minerals Engineering, 31, 90–97.
  • Eti Mine (2013). Areas of Usage of Boron "2013 Annual Raport", p. 35, Ankara, Eti Mine Works General Management Publishing.
  • Eti Mine (2014a). Kestelek colemanite "Product catalogue", p. 2, Ankara, Eti Mine Works General Management Publishing.
  • Eti Mine (2014b). Milled colemanite "Product catalogue", p. 3, Ankara, Eti Mine Works General Management Publishing.
  • Guo, S., Hu, C. and Kagawa, Y. 2011. Mechanochemical processing of nanocrystalline zirconium diboride powder, Journal of the American Ceramic Society, 94(11), 3643–3647.
  • Kutuk-Sert, T. 2016. Stability analyses of submicron-boron mineral prepared by mechanical milling process in concrete roads, Construction and Building Materials, 121, 255–264.
  • Kutuk-Sert, T. 2017. Sub-mikron boyutlarında üleksit mineralinin asfalt karışımların suya hassasiyetine etkisinin incelenmesi, Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 7(2), 141–152.
  • Kutuk-Sert, T. and Kutuk, S. 2013. Physical and marshall properties of borogypsum used as filler aggregate in asphalt concrete, Journal of Materials in Civil Engineering, 25(2), 266–273.
  • Kutuk, S. 2016. Influence of milling parameters on particle size of ulexite material, Powder Technology, 301, 421–428.
  • Kutuk, S., Bolat, S., Terzioglu, C. and Altintas, S. P. 2015. An investigation of magnetoresistivity properties of an Y3Ba5Cu8Oy bulk superconductor, Journal of Alloys and Compounds, 650, 159–164.
  • Kutuk, S. and Kutuk-Sert, T. 2017. Effect of PCA on nanosized ulexite material prepared by mechanical milling, Arabian Journal for Science and Engineering, 42(11), 4801-4809.
  • Mishra, S. K., Das, S. and Pathak, L. C. 2004. Defect structures in zirconium diboride powder prepared by self-propagating high-tempeture synthesis, Materials Science and Engineering A, 364(1–2), 249–255.
  • Sert, H., Yildiran, H. and Toscal, D. 2012. An investigation on the production of sodium metaborate dihydrate from ulexite by using trona and lime, International Journal of Hydrogen Energy, 37(7), 5833–5839.
  • Uysal, T., Mutlu, H. S. and Erdemoğlu, M. 2016. Effects of mechanical activation of colemanite (Ca2B6O11·5H2O) on its thermal transformations, International Journal of Mineral Processing, 151, 51–58.
  • Vignolo, M., Bovone, G., Matera, D., Nardelli, D., Bernini, C. and Siri, A. S. 2014. Nano-sized boron synthesis process towards the large scale production, Chemical Engineering Journal, 256, 32–38.
  • Zhang, F. L., Zhu, M. and Wang, C. Y. 2008. Parameters optimization in the planetary ball milling of nanostructured tungsten carbide/cobalt powder, International Journal of Refractory Metals and Hard Materials, 26(4), 329–333.

Öğütülmüş Nano Boyutlu Kolemanit Mineralinin Elementel ve Kristal Yapı Özellikleri

Year 2017, Volume: 10 Issue: 2, 303 - 313, 22.12.2017

Abstract

Üç farklı boyutta olan (C-3 mm, C-75 µm ve C-45 µm) kolemanit mineralleri, Eti Maden Şirketinden
tedarik edildi. Bu mineraller başlangıç malzemesi olarak kullanıldı. Nano boyutlu malzemelerin pek
çok pozitif teknik özelliklere sahip olduğu bilinmektedir. Bu yüzden bu çalışmada nano kristal boyutlu
kolemanit elde edebilmek için, C-3 mm minerali yüksek enerjili bilyalı değirmende öğütüldü. Sonra
öğütülmüş toz 25 µm’lik eleğe sahip elek sarsma cihazından geçirildi (C-25 µm). Başlangıç
malzemelerinin ve öğütülmüş tozun elementel özellikleri oksitli bileşik deneyi ve enerji dağılımlı
spektrometre (EDS) ile araştırıldı. Onların kristal yapı özellikleri X-ışını difraktometresi (XRD)
vasıtasıyla incelendi. Elementel özellik sonuçları, malzemelerin saf kolemanit bileşiği olmadığını ve
öğütme işlemi neticesinde bor oksit miktarının önemli ölçüde değişmediğini gösterdi. Kristal yapı
özellik sonuçları, öğütme işlemi neticesinde kolemanit minerali kristal boyutunun 63.6 nm değeri ile
nano ölçeğe indirgendiğini gösterdi. Bu çalışmanın sonuçları, bilim ve mühendislik çalışmaları
açısından sadece kolemanit minerali için değil diğer bor mineralleri için de gelecek vadetmektedir.

References

  • Abdellahi, M., Bahmanpour, H. and Bahmanpour, M. 2014. The best conditions for minimizing the synthesis time of nanocomposites during high energy ball milling: Modeling and optimizing, Ceramics International, 40 (7 Part A), 9675–9692.
  • Alam, S. N. 2006. Synthesis and characterization of W-Cu nanocomposites developed by mechanical alloying, Materials Science and Engineering A, 433(1–2), 161–168.
  • Alizadeh, M., Sharifianjazi, F., Haghshenasjazi, E., Aghakhani, M. and Rajabi, L. 2015. Production of nanosized boron oxide powder by high-energy ball milling, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 45(1), 11–14.
  • Bayca, S. U., Kocan, F. and Abali, Y. 2014. Investigation of leaching kinetics of ulexite waste in oxalic acid solutions, Chemical and Biochemical Engineering Quarterly, 28(3), 273–280.
  • Canakci, A., Varol, T., Cuvalci, H., Erdemir, F., Ozkaya, S. and Yalcin, E. D. 2014. Synthesis of novel CuSn10-graphite nanocomposite powders by mechanical alloying, Micro and Nano Letters, 9(2), 109–112.
  • Demir, F. and Un, A. 2013. Radiation transmission of colemanite, tincalconite and ulexite for 6 and 18MV X-rays by using linear accelerator, Applied Radiation and Isotopes, 72, 1–5.
  • Emrullahoglu Abi, C. B. 2014. Effect of borogypsum on brick properties, Construction and Building Materials, 59, 195–203.
  • Eskibalci, M. F. and Ozkan, S. G. 2012. An investigation of effect of microwave energy on electrostatic separation of colemanite and ulexite, Minerals Engineering, 31, 90–97.
  • Eti Mine (2013). Areas of Usage of Boron "2013 Annual Raport", p. 35, Ankara, Eti Mine Works General Management Publishing.
  • Eti Mine (2014a). Kestelek colemanite "Product catalogue", p. 2, Ankara, Eti Mine Works General Management Publishing.
  • Eti Mine (2014b). Milled colemanite "Product catalogue", p. 3, Ankara, Eti Mine Works General Management Publishing.
  • Guo, S., Hu, C. and Kagawa, Y. 2011. Mechanochemical processing of nanocrystalline zirconium diboride powder, Journal of the American Ceramic Society, 94(11), 3643–3647.
  • Kutuk-Sert, T. 2016. Stability analyses of submicron-boron mineral prepared by mechanical milling process in concrete roads, Construction and Building Materials, 121, 255–264.
  • Kutuk-Sert, T. 2017. Sub-mikron boyutlarında üleksit mineralinin asfalt karışımların suya hassasiyetine etkisinin incelenmesi, Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 7(2), 141–152.
  • Kutuk-Sert, T. and Kutuk, S. 2013. Physical and marshall properties of borogypsum used as filler aggregate in asphalt concrete, Journal of Materials in Civil Engineering, 25(2), 266–273.
  • Kutuk, S. 2016. Influence of milling parameters on particle size of ulexite material, Powder Technology, 301, 421–428.
  • Kutuk, S., Bolat, S., Terzioglu, C. and Altintas, S. P. 2015. An investigation of magnetoresistivity properties of an Y3Ba5Cu8Oy bulk superconductor, Journal of Alloys and Compounds, 650, 159–164.
  • Kutuk, S. and Kutuk-Sert, T. 2017. Effect of PCA on nanosized ulexite material prepared by mechanical milling, Arabian Journal for Science and Engineering, 42(11), 4801-4809.
  • Mishra, S. K., Das, S. and Pathak, L. C. 2004. Defect structures in zirconium diboride powder prepared by self-propagating high-tempeture synthesis, Materials Science and Engineering A, 364(1–2), 249–255.
  • Sert, H., Yildiran, H. and Toscal, D. 2012. An investigation on the production of sodium metaborate dihydrate from ulexite by using trona and lime, International Journal of Hydrogen Energy, 37(7), 5833–5839.
  • Uysal, T., Mutlu, H. S. and Erdemoğlu, M. 2016. Effects of mechanical activation of colemanite (Ca2B6O11·5H2O) on its thermal transformations, International Journal of Mineral Processing, 151, 51–58.
  • Vignolo, M., Bovone, G., Matera, D., Nardelli, D., Bernini, C. and Siri, A. S. 2014. Nano-sized boron synthesis process towards the large scale production, Chemical Engineering Journal, 256, 32–38.
  • Zhang, F. L., Zhu, M. and Wang, C. Y. 2008. Parameters optimization in the planetary ball milling of nanostructured tungsten carbide/cobalt powder, International Journal of Refractory Metals and Hard Materials, 26(4), 329–333.
There are 23 citations in total.

Details

Subjects Engineering
Journal Section Makaleler
Authors

Sezai KÜTÜK

Publication Date December 22, 2017
Published in Issue Year 2017 Volume: 10 Issue: 2

Cite

APA KÜTÜK, S. (2017). Elemental and Crystal Structure Properties on Milled Nanosize Colemanite Mineral. Erzincan University Journal of Science and Technology, 10(2), 303-313. https://doi.org/10.18185/erzifbed.334656