Development of a MOF Based Potentiometric Sensor for Determination of Rhodamine B

Year 2025, Volume: 18 Issue: 3, 933 - 950

Nurcan Kaya , Gülşah Saydan Kanberoğlu

Abstract

Rhodamine B is a basic, red and cationic dye belonging to the class of xanthene dyes. Rhodamine B is harmful to human and animal health when taken orally or in contact with skin. It causes irritation to the skin, eyes and respiratory tract. It has been shown experimentally to be carcinogenic, reproductive and developmental toxicity, neurotoxicity, and chronic toxicity to humans and animals. Because of its intense color and availability, Rhodamine B has been illegally added to food products, particularly paprika seasonings, to enhance the natural color. In this study, a Rhodamine B-selective potentiometric sensor was developed by using MIL-53 (Al) as ionophore in the prepared membrane composition. The sensor prepared with 6% MIL-53 (Al), 26% PVC, 68% DOS membrane composition exhibited the best potentiometric performance. The Rhodamine B-selective sensor exhibited a linear response in the concentration range of 1.0×10−6 M-1.0×10−2 M with a slope of 58 mV/decade and a detection limit of 5.0×10−7 M. The response time of the Rhodamine B-selective sensor was less than 5 seconds and it was not affected by hydronium ion in the pH range of 4.49-8.08. Analytical application of the sensor was successfully carried out in Van Lake, waste water and tap water.

Keywords

Determination of Rhodamine B , Metal organic framework , Potentiometric sensor

Project Number

FYL-2023-10450

Rodamin B Tayini için MOF Temelli Potansiyometrik Sensör Geliştirilmesi

Abstract

Rodamin B, ksanten boyaları sınıfına ait bazik, kırmızı ve katyonik bir boyar maddedir. Rodamin B, ağızdan alındığında veya deri ile teması halinde insan ve hayvan sağlığı için zararlıdır. Ciltte, gözlerde ve solunum yollarında tahrişe neden olur. Deneysel olarak, insanlara ve hayvanlara karşı kanserojen, üreme ve gelişimsel toksisite, nörotoksisite ve kronik toksisiteye sahip olduğu gösterilmiştir. Yoğun rengi ve kolay bulunabilmesi nedeniyle Rodamin B, doğal rengi geliştirmek için gıda ürünlerine, özellikle kırmızıbiber baharatlarına yasa dışı bir şekilde eklenmiştir. Bu çalışmada, hazırlanan membran bileşiminde iyonofor olarak MIL-53 (Al) kullanılarak Rodamin B-seçici potansiyometrik sensör geliştirildi. %6 MIL-53 (Al), %26 PVC, %68 DOS membran bileşimi ile hazırlanan sensör en iyi potansiyometrik performans özelliği sergiledi. Rodamin B-seçici sensör, 1.0×10−6 M-1.0×10−2 M konsantrasyon aralığında 58 mV/10 kat’lık eğim ve 5.0×10−7 M tayin limiti ile doğrusal bir cevap sergiledi. Rodamin B-seçici sensörün cevap zamanı 5 saniyeden düşük olduğu ve pH=4.49-8.08 aralığında hidronyum iyonundan etkilenmediği belirlendi. Sensörün analitik uygulaması Van Gölü, atık su ve çeşme suyunda başarıyla gerçekleştirildi.

Keywords

Metal organik kafes yapısı , potansiyometrik sensör , rodamin B tayini

Project Number

FYL-2023-10450

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