Çapraz Bağlı Kitosan Selüloz Grafen Kompozitinin Şişme Davranışlarının İncelenmesi

Yıl 2021, Cilt: 33 Sayı: 1, 329 - 337, 15.02.2021

Betul Çiçek Ozkan

https://doi.org/10.35234/fumbd.858462

Cited By: 2

Öz

Kitosan/selüloz biyopolimer matrisi grafen ile katkılandıktan sonra basit ve pratik bir yolla çapraz bağlı üçlü absorban kompozit sistemi üretildi. Bu kapsamda üç farklı oranda çapraz bağlayıcı kullanılarak hazırlanan kompozitlerin sıvı absorplama özelliklerine pH’ın ve çapraz bağlayıcı miktarının etkisi şişme testleri ile araştırıldı. Çapraz bağlayıcı olarak glutaraldehit kullanıldı. Artan çapraz bağlayıcı miktarı ve pH ile birlikte şişme ve absorplanan sıvı oranının azaldığı gözlenmiştir. Ayrıca çapraz bağlayıcı miktarı kompozitin çekme dayanımını arttırırken bu artış çapraz bağlayıcı miktarı ile orantılı değildir. Hazırlanan kompozitin yapısal ve moleküler özellikleri FT-IR ve FESEM analizleri ile tespit edildi. Bu analizlerin sonucunda üç bileşenin birbiri içerisinde iyi bir biçimde dağıldığı, bu bileşenler arasında molekül içi ve moleküller arası bağlar ve sinerjik etki sebebiyle güçlü bir etkileşimin olduğu bunun sonucunda da kompozitin yeniden yapılandığı gösterildi.

Anahtar Kelimeler

Kitosan, Grafen, Selüloz, Çapraz Bağlanma

Kaynakça

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