C.I. ASİT VİYOLET 90 METAL-KOMPLEKS BOYARMADDESİNİN SULU ORTAMLARDAN SENTETİK VE DOĞAL ZEOLİT KULLANILARAK UZAKLAŞTIRILMASI

Yıl 2016, , 0 - 0, 06.09.2016

Müjgan Okur , Filiz Aktı

https://doi.org/10.17341/gummfd.86378

Cited By: 2

Öz

C.I. Asit Viyolet 90 (AV 90) boyarmaddesinin gideriminde Manisa- Gördes zeoliti (M-GZ) ve sentetik bir zeolit olan moleküler elek 10 Å (Z-10A) adsorplayıcı olarak kullanılmıştır. pH 2’de en yüksek boyarmadde adsorpsiyonu Z-10A ile % 93, M-GZ ile % 73 olarak elde edilmiştir. En yüksek adsorpsiyon kapasitesi, 150 mg/L başlangıç boyarmadde derişiminde M-GZ ve Z-10A için sırasıyla 51,4 mg/g ve 1461 mg/g olarak belirlenmiştir. Sıcaklığın 303K’den 333K’e arttırılması, her iki zeolite adsorplanan boyarmadde miktarının azalmasına neden olmuştur. Adsorpsiyon denge verilerinin M-GZ için Freundlich, Z-10A için Temkin izoterm modelleri ile uyumlu olduğu belirlenmiş, boyarmadde adsorpsiyonunu en iyi tanımlayan modelin ise pseudo-ikinci derece kinetik model olduğu saptanmıştır. AV 90’ın zeolitlere adsorpsiyonunda, düşük boyarmadde derişimlerinde sadece yüzey adsorpsiyonu gerçekleşirken yüksek derişimlerde hem yüzey hemde partikül içi difüzyonun birlikte gerçekleştiği gözlemlenmiştir. Termodinamik analizler ve deneysel sonuçlar, adsorpsiyonun kendiliğinden ve ekzotermik bir proses olduğunu göstermiştir.

Anahtar Kelimeler

Doğal ve sentetik zeolit, C.I. Asit Violet 90 metal-kompleks boyarmadde, adsorpsiyon

Kaynakça

• Cheung, W.H., Szeto, Y.S., McKay, G., “Intraparticle Diffusion Processes During Acid Dye Adsorption onto Chitosan”, Bioresource Technology, Cilt 98, 2897–2904, 2007.
• Gaikwad, R.W., Misal, S.A., “Sorption Studies of Methylene Blue on Silica Gel”, International Journal of Chemical Engineering and Applications, Cilt 1, No. 4, 2010.
• Elsherbiny, A.S., “Adsorption Kinetics and Mechanism of Acid Dye onto Montmorillonite from Aqueous Solutions: Stopped-flow Measurements”, Applied Clay Science, Cilt 83–84, 56–62, 2013.
• Belaid, K.D., Kacha, S., Kameche, M., Derriche, Z., “Adsorption Kinetics of Some Textile Dyes onto Granular Activated Carbon”, Journal of Environmental Chemical Engineering, Cilt 1, 496–503, 2013.
• Toor, M., Jin, B., “Adsorption Characteristics, Isotherm, Kinetics, and Diffusion of Modified Natural Bentonite for Removing Diazo Dye”, Chemical Engineering Journal, Cilt 187, 79– 88, 2012.
• Elemen, S., Akçakoca Kumbasar, E.P., Yapar, S., “Modeling the Adsorption of Textile Dye on Organoclay using an Artificial Neural Network” Dyes and Pigments, Cilt 95, 102-111, 2012.
• Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z., Amouzgar, P., “Application of Chitosan and its Derivatives as Adsorbents for Dye Removal from Water and Wastewater: A Review”, Carbohydrate Polymers, Cilt 113, 115–130, 2014.
• Benkli, Y.E., Can, M.F., Turan M., Çelik , M.S., “Modification of Organo-zeolite Surface for the Removal of Reactive Azo Dyes in Fixed-bed Reactors”, Water Research, Cilt 39, 487–493, 2005.
• Rida, K., Bouraoui, S., Hadnine, S., “Adsorption of Methylene Blue from Aqueous Solution by Kaolin and Zeolite”, Applied Clay Science, Cilt 83–84, 99–105, 2013.
• Armağan, B., Turan B.,Çelik, S.M., “Equlibrium Studies on the Adsorption of Reactive Azo Dyes into Zeolite”, Desalination, Cilt 170, 33-39, 2004.
• Wang, L., Zhang, J., Zhao, R., Li, C., Li, Y., Zhang, C., “Adsorption of Basic Dyes on Activated Carbon Prepared from Polygonum Orientale Linn: Equilibrium, Kinetic and Thermodynamic Studies”, Desalination, Cilt 254, 68–74, 2010.
• Crini, G., “Non-Conventional Low-Cost Adsorbents For Dye Removal: A Review”, Bioresource Technology, 97, 1061–1085, 2006.
• Malamis, S., Katsoua, E., “A Review on Zinc and Nickel Adsorption on Natural and Modified Zeolite, Bentonite and Vermiculite: Examination of Process Parameters, Kinetics and Isotherms”, Journal of Hazardous Materials, Cilt 252– 253, 428–461, 2013.
• Panic, V.V., Velickovic, S.J., “Removal of Model Cationic Dye by Adsorption onto Poly(methacrylic acid)/Zeolite Hydrogel Composites: Kinetics, Equilibrium Study and Image Analysis”, Separation and Purification Technology, Cilt 122, 384–394, 2014.
• Yagub, M.T., Sen, T.K., Afroze, S., Ang, H.M., “Dye and its Removal from Aqueous Solution by Adsorption: A Review”, Advances in Colloid and Interface Science, Cilt 209, 172–184, 2014.
• Liu, S., Ding, Y., Li, P., Diao, K., Tan, X., Lei, F., Zhan, Y., Li, Q., Huang, B., Huang, Z.,“Adsorption of the Anionic Dye Congo Red from Aqueous Solution onto Natural Zeolites Modified with N,N-Dimethyl Dehydroabietylamine Oxide”, Chemical Engineering Journal, Cilt 248, 135–144, 2014.
• Dikmen, Z., Orhun, Ö., “Manyetik Modifiye Edilmiş Sentetik ve Doğal Zeolitlerin Hazırlanması ve Bazı Fiziksel Özelliklerinin Kıyaslanması”, Anadolu Unıversıty Journal Of Science and Technology –A Applied Sciences and Engineering, Cilt 14, 75-90, 2013.
• Qiu, M., Qian, C., Xu, J., Wu, J., Wang, G., “Studies on the adsorption of dyes into clinoptilolite”, Desalination, Cilt 243, 286-292, 2009.
• Karadağ, D., “Modeling the mechanism, equilibrium and kinetics for the adsorption of Acid Orange 8 onto surfactant-modified clinoptilolite: The application of nonlinear regression analysis”, Dyes and Pigments, Cilt 74, 659-664, 2007.
• Nairat, M., Shahwan, T., Eroğlu, A. E., Fuchs, H., “Incorporation of iron nanoparticles into clinoptilolite and its application for the removal of cationic and anionic dyes” Journal of Industrial and Engineering Chemistry, Cilt 21, 1143–1151, 2015.
• Sakızcı, M., Yörükoğulları, E., “Gördes Yöresi Klinoptilolitin (Doğal Ve Modifiye) Su Buharı Adsorpsiyonu”, Eskişehir Osmangazi Üniversitesi Müh.Mim.Fak.Dergisi, Cilt 20, 33-46, 2007.
• Blackburn, R.S., Burkinshaw, S.M.,. “A greener approach to cotton dyeings. Part 2: Application of 1:2 metal complex acid dyes”, Green Chemistry, Cilt 4, 261-265, 2002.
• Elaiopoulos, K., Perraki T., Grigoropoulou, E., “Monitoring the Effect of Hydrothermal Treatments on the Structure of a Natural Zeolite Through a Combined XRD, FTIR, XRF, SEM and N2-Porosimetry Analysis”, Microporous and Mesoporous Materials, Cilt 134, 29–43, 2010.
• Nosrati, R., Olad, A., Nofouzi, K., “A Self-Cleaning Coating Based on Commercial Grade Polyacrylic Latex Modified By TiO2/Ag-Exchanged-Zeolite-A Nanocomposite, Applied Surface Science,Cilt 346, 543–553, 2015.
• Biçen, M., Apohan, N.K., Karataş, S., Dumludağ, F., Güngör, A., “The Effect of Surface Modification of Zeolite 4A on the Physical and Electrical Properties of Copolyimide Hybrid Films”, Microporous and Mesoporous Materials, Cilt 218, 79-87, 2015.
• Courtney, T.D., Chang, C.C., Gorte, R., Lobo, R.F., Fan, W.,Nikolakis, V., “Effect of Water Treatment on Sn-BEA Zeolite: Origin of 960 cm−1 FTIR Peak”, Microporous and Mesoporous Materials, Cilt 210, 69–76, 2015.
• Tapaswi, P.K., Moorthy, M.S., Park, S.S., Ha, C.S., “ Fast, Selective Adsorption of Cu2+ from Aqueous Mixed Ions Solution Using 1,4,7- Triazacyclononane Modified SBA-15 Silica Adsorbent (SBA-TACN)”, Journal of Solid State Chemistry, Cilt 211, 191-199, 2014.
• Chakarova, K., Hadjiivanov, K., “ FTIR study of N2 and CO adsorption on H-D-FER”, Microporous and Mesoporous Materials, Cilt 177, 59–65, 2013.
• Celis, J., Amadeo, N.E., Cukierman, A.L., “In Situ Modification of Activated Carbons Developed from A Native Invasive Wood on Removal of Trace Toxic Metals from Wastewater”, Journal of Hazardous Materials, Cilt 161 , 217–223, 2009.
• Hendawy, A.A., “Influence of HNO3 Oxidation on the Structure and Adsorptive Properties of Corncob-Based Activated Carbon”, Carbon, Cilt 41, 713–722, 2003.
• Nandi, B.K., Goswami, A., Purkait, M.K., “Adsorption characteristics of brilliant green dye on kaolin”, Journal of Hazardous Materials, Cilt 161, 387–395, 2009.
• Kılıç, M., Çepelioğullar, Ö., Özsin, G., Uzun, B.B., Pütün, A.E., “Nohut Samanı Tarla Atığının Sulu Çözeltilerden Metilen Mavisi Gideriminde Düşük Maliyetli Biyosorbent Olarak Değerlendirilmesi”, Gazi Üniv. Müh. Mim. Fak. Der., Cilt 29, No 4, 717-726, 2014.
• Jain, R., Gupta, V.K., Sikarwa, S., “Adsorption and Desorption Studies on Hazardous Dye Naphthol Yellow S”, Journal of Hazardous Materials, Cilt 182, 749-756, 2010.
• Elkady, M.F., Ibrahim, A.M., Abd El-Latif, M.M., “Assessment of the Adsorption Kinetics, Equilibrium and Thermodynamics for the Potential Removal Of Reactive Red Dye Using Eggshell Biocomposite Beads”, Desalination, Cilt 278, 412-423, 2011.
• Ying, Q., Andrew, H.F.A., Alan, C.L., Gil, G., “Characterisation of Lignite As An Industrial Adsorbent”, Fuel, Cilt 90, 1567–1574, 2011.
• Saikia, J., Das, G.,“Framboidal Vaterite for Selective Adsorption of Anionic Dyes”, Journal of Environmental Chemical Engineering, Cilt 2, 1165–1173,2014.