Kozmetik atık sularından fenton prosesiyle organik madde gideriminin ve kinetiğinin incelenmesi

Year 2017, Volume: 32 Issue: 1, 0 - 0, 23.03.2017

Yalçın Kemal Bayhan Gökçe Didar Değermenci

https://doi.org/10.17341/gazimmfd.300609

Cited By: 6

Abstract

Kozmetik endüstrisi atık suların arıtımı için fenton prosesinin uygulanabilirliği araştırılmıştır. Proses süresince KOİ ve TOK giderimi üzerine reaksiyon süresi, pH, sıcaklık, Fe⁺² ve H₂O₂ konsantrasyonlarının etkileri karakterize edilmiştir. Elde edilen sonuçlara göre, 36ºC’de optimum reaksiyon süresi, pH, Fe⁺² ve H₂O₂ konsantrasyonları sırasıyla 90 dakika, pH 3, 1 g/L, 17,5 g/L,  KOİ ve TOK giderim etkinliği ise %89,6 ve %76,9 olarak belirlenmiştir. Ayrıca, farklı sıcaklık değerleri araştırılarak prosesin kinetik analizi gerçekleştirilmiştir. Prosesin yalancı birinci dereceden reaksiyon kinetiğine uyduğu ve aktivasyon enerjisinin (E_a) 117,7 kJ/mol olduğu belirlenmiştir.

Keywords

Kozmetik atık suyu, fenton prosesi; oksidasyon; kinetik

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