Çok bileşenli kurşunsuz alaşımlara eşlik eden termodinamik özelliklerin belirlenmesi

Yıl 2019, Cilt: 34 Sayı: 2, 597 - 608, 23.05.2019

Hüseyin Arslan , Ali Dogan

https://doi.org/10.17341/gazimmfd.416431

Cited By: 2

Öz

Bu çalışmada, üç, dört ve altı bileşenli sıvı alaşımlara, yüksek sıcaklıklar için, Chuo’nun genel çözüm modeli (GSM) ve geleneksel geometrik modeller uygulandı. Tüm geometrik modeller, deneysel sonuçlarla karşılaştırmak maksadıyla altı bileşenli Ni-Cr-Co-Al-Ti-Cu sıvı karışımın entalpileri ve kısmi entalpileri,  xNi/xCr =1, xNi/xCo =1, xCr/xCo =1, r=xAl / xTi oranları, dört bileşenli kurşunsuz Au–In–Sn–Zn alaşımının xIn / xSn  = 2,  xSn / xZn = 1 oranı ve üç bileşenli In-Pd-Sn alaşımının xIn/xSn =1 oranı için sırasıyla 2000K, 773K and 1173K sıcaklıklarında belirlendi. Geometrik modellerden elde edilen sonuçlar deneylerden elde edilenlerle karşılaştırılmış ve uyum içinde oldukları görülmüştür.

Anahtar Kelimeler

Geometrik modeller, Redlich-Kister katsayıları, Fazlalık Gibbs entalpisi, Termodinamik modeller

Kaynakça

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