Fındık kabukları ile farklı model boyaların gideriminin kinetik ve termodinamik incelemesi

Year 2019, Volume: 34 Issue: 4, 2033 - 2044, 25.06.2019

Musa Büyükada

https://doi.org/10.17341/gazimmfd.418184

Abstract

Bu çalışmada,
tekstil endüstrisi atıksularının giderimi için Türkiye’ye katma değer
sağlayacak pratik bir yaklaşım hedeflenmiştir. Bu bağlamda, ülkemizin dünya
birincisi olduğu fındık üreticiliği göz önüne alınarak zararsız bir atık olan
fındık kabuğu, laboratuvar ortamında hazırlanmış sentetik atık suların
gideriminde değerlendirilmiştir. FTIR, SEM-EDS ve XRD analizleri ile
gerçekleştirilen karakterizasyon çalşmaları, FK’nin organik bağ yapısı, morfolojik
yapısı ve elementel içeriği ortaya konulmuştur. Çalışmanın devamında kısmında
farklı tekstil model boyalarla hazırlanan sentetik çözeltilerin farklı işletme
şartlarında FK ile giderimi incelenmiştir. Bu bağlamda; başlangıç pH’ı,
başlangıç boya konsantrasyonu, adsorbent konsantrasyonu, reaksiyon süresi ve
sıcaklığın etkileri incelenmiştir. Kinetik analizler, adsorpsiyonun sözde
ikinci mertebe model ve partiküler arası difüzyonun kontrolünde gerçekleştiğini
göstermiştir. Denge çalışmaları, Langmuir izoterminin süreci daha iyi ifade
ettiğini göstermiştir. Termodinamik parametreler ise, sürecin endotermik
olduğunu, kendiliğinden gerçekleştiğini ve sıcaklıla artan bir affiniteye sahip
olduğunu göstermiştir.

Keywords

Reaktif boya, Fındık kabuğu, Kinetik, Termodinamik

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