18650 lityum-iyon ve 6HR61 nikel-metal hidrit tekrar şarj edilebilir pillerinin elektrokimyasal empedans analizi

Year 2020, Volume: 35 Issue: 1, 297 - 310, 25.10.2019

Uğur Moralı Salim Erol

https://doi.org/10.17341/gazimmfd.463280

Cited By: 5

Abstract

Bu çalışmada ikincil piller arasında yaygın olarak kullanılan ticari
18650 lityum-iyon ve 6HR61 nikel-metal hidrit pillerinin aynı hücre
potansiyeli, sabit sıcaklık ve frekans aralığındaki elektrokimyasal empedans
analizi gerçekleştirilmiştir. Bu iki tekrar şarj edilebilir pilin empedans
cevapları ve geliştirilen eşdeğer devre modeli ile pillerin önemli fiziksel
parametreleri saptanmıştır. Elde edilen parametreler ile pillerin enerji
depolama sistemlerinde tercih edilebilirliğini önemli ölçüde belirleyen
performans ve kapasite özellikleri kıyaslanmıştır. Bunun sonucunda, lityum-iyon
pilinin nikel-metal hidrit piline göre birçok üstün özelliğe sahip olduğu
belirlenmiştir. Ayrıca, kullanılan elektrokimyasal empedans spektroskopi
tekniği ile geliştirilen modelin, enerji ihtiyacının karşılanması ve gelecekte
üretilecek pillerin tasarımı için etkili olabileceği ve büyük bir potansiyele
sahip olduğu ortaya konmuştur. 

Keywords

empedans spektroskopisi, tekrar şarj edilebilir pil, eşdeğer devre, pil performansı, gözenekli elektrot

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