Year 2013,
Volume: 28 Issue: 3, 0 - , 03.03.2014
Abstract
Polimetin boyaların en önemli karakteristik özellikleri ultraviyole, görünür ve yakın kızıl ötesi bölgelerinde güçlü soğurma yapabilmeleridir. Bu özellik onların boyama dışı bir çok yeni alanda kullanımlarına imkân doğurmuştur. Bu çalışmada bir polimetin boya çeşidi olan Kloroheptametin Siyanin elde edilmiştir. Temel metot
olarak, boyanın sentezi için kuaternar amonyum tuzu ile bisaldehitin geri soğutucu altında kaynatılması yolu izlenmiştir. Üretilen boyanın molar kütlesi, erime noktası, floresans, uyarılma ve soğurma özellikleri belirlenmiştir. Çalışmanın son aşamasında ise üretilen boyanın boya lazerlerinde uygulanabilirliği araştırılmıştır.
Bunun için boya lazeri sistemi kullanılmış ve beklenildiği gibi boyanın floresans özelliği gösterdiği aralıkta, lazer ışını üretebildiği tespit edilmiştir.
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- intramolecular h-complex of novel heptamethine
- cyanine dyes”, Talanta, 67: 947-954, 2005.
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- polymethine dyes with human serum albumin: a
- spectroscopic study, Biophysical Chemistry,
- 33–49, 2004.
- Zhanga, J.P., Zhouas.S.Y., Chena, P., Okasaki,
- T., Hayami, M., The effect of solvent on the
- optical properties of cyanine dye films, Dyes and
- Pigments,< 51: 93–101, 2001.
- Kachkovsky, A., D., Pilipchuk N., V.,
- Kurdyukov V., V., “Electronic Properties of
- Polymethine Systems 10. Elektron Structure and
- Absorption Spectra of Cyanine Bases”, Dyes and
- Pigments, 70:212-219, 2006.
- Casalboni, M., De Matteis, F., Prosposito, P.,
- Quatela, A., Sarcinelli, F., Fluorescence
- efficiency of four infrared polymethine dyes,
- Chemical Physics Letters, 373 372–378, 2003.
Year 2013,
Volume: 28 Issue: 3, 0 - , 03.03.2014
Abstract
References
- Matsuoka, M., Infrared Absorbing Dyes,
- Plenum Press, New York and London, 1990.
- Mishra, A., R., Behera, K., Behera, P., Mishra,
- B., Gopa, B., “Cyanines during the 1990s: A
- Review” , Chem. Rev., 100: 1973-2011, 2000.
- Ramos, S., Santos, P., F., Reis, L., V., Almeida,
- P., “Some new symmetric rigidified
- triheterocyclic heptamethinecyanine dyes
- absorbing in the near infrared”, Dyes and
- Pigments, 53: 143-152, 2002.
- Quan, L., Tan, J., Bi-Xian, P., “Synthesis and
- characterization of heptamethine cyanine dyes”,
- Molecules, 2: 91-98, 1997.
- Aslan, T., Boya lazerlerinin optik ve
- spektroskopik özelliklerinin incelenmesi,
- Yüksek Lisans Tezi, Ankara Üniversitesi Fen
- Bilimleri Enstitüsü, Ankara, 1998.
- Soyal, A.D., Kloro heptametin siyanin boyanın
- eldesi ve boya lazerinde uygulanabilirliğinin
- incelenmesi, Gazi Üniversitesi Fen Bilimleri
- Enstitüsü, 2006
- Encinas, C., Miltsov, S., Otazo, E., Rivera, L.,
- “Synthesis and spectrocopic characterisation of
- heptamethincyanine NIR dyes for their use in
- optochemical sensors”, Dyes and Pigments, 71:
- -36, 2006.
- Zhang, J., Zhou, S., Chen, P., Tsuneki, O., “The
- effect of solvent on the optical properties of
- cyanine dye films”, Dyes and Pigments, 51: 93-
- , 2001.
- Nikolai, I., Toder, G., Seok, H., “Preparation of
- monomethine cyanine dyes as noncovalent labels
- for nucleic acids”, Dyes and Pigments, 40: 181-
- , 1999.
- Pardal, A., C., Ramos, P., F., Reis, V., Almeida,
- P., “Synthesis and spectroscopic characterisation
- of n-alkyl quaternary ammonium salts typical
- precursors of cyanines”, Molecules, 7:320-330,
- -
- Reynolds, G., Drexhage, K., “Stable
- heptamethine pyrylium dyes that absorb in the
- infrared”, J. Org. Chem., 42(5):885-888, 1977.
- Atsuhiro, O., Kazumasa, F., Naoyuki,
- S., Hiroyoshi, M., Tsukasa, Y., Hideki, M.,
- Design and synthesis of near-infrared-active
- heptamethine-cyanine dyes to suppress
- aggregation in a dye-sensitized porous zinc oxide
- solar cell, Chemical Soc. of Japan, 37(2) 176-
- , 2008.
- Shindy, H.A., El-Maghraby, M.A., Eissa, F.M.,
- “Novel quinone cyanine dyes: synthesis and
- spectral studies, Dyes and Pigments, 52 79–87,
- -
- Kazumasa ,F., Hiroyoshi, M., Atsuhiro, H.,
- Tanaka,N., Mizuhata, N., “Synthesis of a novel
- heptamethine–cyanine dye for use in nearinfrared
- active dye-sensitized solar cells with
- porous zinc oxide prepared at low temperature”,
- Energy Environmental Science, 6(4) 186-192,
- -
- Yau, C. M. S., Pascu, S. I., Odom, S. A., Warren,
- J. E., Klotz, E. J. F., Frampton, M. J., Williams,
- C. C., Coropceanu, V., Kuimova, M. K., Phillips,
- D., Barlow, S., Brédas, J.-L., Marder, S. R.,
- Millar, V. and Anderson, H. L., Stabilisation of a
- heptamethine cyanine dye by rotaxane
- encapsulation. Chemical Communications, 25,
- -2899, 2008.
- Joung-Il Shın, Soo-Youl Park, Seung-Rim Shın,
- Kun Jun, Hye-Soo Youn, Kyoung-Lyong An and Young-A Son, Synthesıs and characterızatıon of
- heptamethıne nırabsorbıng cyanıne dye
- compounds, Rev. Roum. Chim., 55(10), 621-
- , 2010.
- Donald D. Nolting D.D., Gore, J.C., and
- Pham,W., Near-Infrared Dyes: Probe
- Development and Applications in Optical
- Molecular Imaging, Current Organic
- Synthesis, 8(4) 521-534, 2011.
- Narayanan, N., Patonay, G., A new method for
- the synthesis of heptamethine cyanine dyes:
- synthesis of new near-infrared fluorescent labels,
- J.Org. Chem., 60: 2391-2395. 1995.
- Kim, J., Kodagahally, R., “A study of
- intramolecular h-complex of novel heptamethine
- cyanine dyes”, Talanta, 67: 947-954, 2005.
- Tatikolov A.S., Costa S.M.B. , Complexation of
- polymethine dyes with human serum albumin: a
- spectroscopic study, Biophysical Chemistry,
- 33–49, 2004.
- Zhanga, J.P., Zhouas.S.Y., Chena, P., Okasaki,
- T., Hayami, M., The effect of solvent on the
- optical properties of cyanine dye films, Dyes and
- Pigments,< 51: 93–101, 2001.
- Kachkovsky, A., D., Pilipchuk N., V.,
- Kurdyukov V., V., “Electronic Properties of
- Polymethine Systems 10. Elektron Structure and
- Absorption Spectra of Cyanine Bases”, Dyes and
- Pigments, 70:212-219, 2006.
- Casalboni, M., De Matteis, F., Prosposito, P.,
- Quatela, A., Sarcinelli, F., Fluorescence
- efficiency of four infrared polymethine dyes,
- Chemical Physics Letters, 373 372–378, 2003.
There are 102 citations in total.
Details
| Primary Language | Turkish |
|---|---|
| Journal Section | Makaleler |
| Authors | |
| Publication Date | March 3, 2014 |
| Submission Date | March 3, 2014 |
| Published in Issue | Year 2013 Volume: 28 Issue: 3 |