Tekstil Atıksularındaki Metal Kompleks Boyarmaddelerin Yumurta Kabukları İle Giderimi

Year 2013, Volume: 28 Issue: 4, 0 - , 05.03.2014

Müjgan Okur

Abstract

Bu çalışmada AV90 (C.I.Acid Violet 90) ve AY194 (C.I.Acid Yellow 194) boyarmaddelerinin yumurta kabukları kullanılarak adsorpsiyonu araştırılmıştır. pH (2-7), adsorplayıcı miktarı (3-25 g/L), partikül boyutu (30-710 μm), sıcaklık (20-40ºC) ve başlangıç boyarmadde derişimi (50-200 mg/L) gibi parametrelerin adsorpsiyona etkileri incelenmiştir. En yüksek giderim her iki boyarmadde için pH 2 de elde edilmiştir. Deneysel denge verilerine Langmuir, Freundlich ve Temkin adsorpsiyon izoterm modelleri uygulanmıştır ve izoterm sabitleri belirlenmiştir. En yüksek boyarmadde giderimi 20oC sıcaklıkta gerçekleştirilmiş olup bu sıcaklıkta sırasıyla 9,7 mg/g ve 9,60 mg/g giderim kapasitesi ve % 82,3 ve % 91,5 giderim elde edilmiştir. Boyarmaddelerin adsorpsiyon kinetiği en iyi Pseudo ikinci derece model ile tanımlanmıştır.

Keywords

Metal-kompleks boyarmadde, adsorpsiyon, yumurta kabukları

References

• Aksu, Z., “Application of biosorption for the removal of organic pollutants : a review”, Process Biochemistry, Cilt 40, 997-1026, 2005.
• Fu, Y. and Viraraghavan, T., “Fungal decolorization of dye wastewaters : a review”, Bioresource Technology, Cilt 79, 251-262, 2001.
• Karapınar Kapdan, İ., Kargı, F., “ Atıksulardan Tekstil Boyar Maddelerinin Adsorpsiyonlu Biyolojik Arıtım ile Giderimi”, Turk J. Engin. Environ. Sci., Cilt 24, 161-169, 2000.
• Arora, S., Saini, S.H., Singh, K., “Decolorisation of a monoazo disperse dye with Candida tropicalis”, Coloration Technology, Cilt 121, 298-303, 2005.
• Rai, H.S., Bhattacharyya, M.S., Singh, J., Bansal, T.K., Vats, P., Banerjee, U.C., “Removal of dyes from the effluent of textile and dyestuff manufacturing industry: A review of emerging techniques with reference to biological treatment”, Critical Reviews in Environmental Science and Technology, Cilt 35, 219-238, 2005.
• Aksu, Z., “Reactive dye bioaccumulation by Saccharomyces cerevisiae”, Process Biochemistry, Cilt 38, 1437-1444, 2003.
• Kocaer, F.O., Alkan, U., “Boyar madde içeren tekstil atık sularının arıtım alternatifleri” , Uludağ Üniv. Müh.Mim.Fak.Dergisi, Cilt 7, No 1, 47-55, 2002.
• Jain, R., Gupta, V.K., Sikarwa, S., “Adsorption and desorption studies on hazardous dye Naphthol Yellow S”, Journal of Hazardous Materials, Cilt 182, 749-756, 2010.
• Arami, M., Limaee, N.Y., Mahmoodi,N.M., Tabrizi, N.S., “Equilibrium and kinetics studies for the adsorption of direct and acid dyes from aqueous solution by soy meal hull”, Journal of Hazardous Materials, Cilt 135, 171-179, 2006.
• Osma, J.F., Saravia, V., Toca-Herrera, J.L., Couto, S.R., “ Sunflower seed shells: A novel and effective low-cost adsorbent for the removal of the diazo dye Reactive Black 5 from aqueous solutions”, Journal of Hazardous Materials, Cilt 147, 900-905, 2007.
• Gong,R., Jin,Y.,Chen,J., Hu,Y., Sun, J., “Removal of basic dyes from aqueous solution by sorption on phosphoric acid modified rice straw”, Dyes and Pigments, Cilt 73, 332-337, 2007.
• Vijaykumar, M.H., Veeranagouda, Y., Neelakanteshwar, K., Karegoudar,T.B., “ decolorization of 1:2 metal complex dye Acid blue 193 by a newly isolated fungus, Cladosporium cladosporioides”, World Journal of Microbiology and Biotechnology, Cilt 22, 157-162, 2006.
• Yang, Q., Yang, M., Pritsch, K., Yediler, A., Hagn, A., Schloter, M., Kettrup,A., “Decolorization of synthetic dyes and production of manganese-dependent peroxidase by new fungal isolates”, Biotechnology Letter, Cilt 25, 709-713, 2003.
• Dönmez, G., “Bioaccumulation of the reactive textile dyes by Candida tropicalis growing in molasses medium”, Enzyme and Microbial Technology, Cilt 30, 363-366, 2002.
• Meehan, C., Banat, I.M., McMullan, G., Nigam, P., Smyth, F., Marchant, R., “Decolorization of Remazol Black-B using thermotolerant yeast, Kluyveromyces marxianus IMB3”, Environment International, Cilt 26, 75-79, 2000.
• Bulut, Y., Gözübenli, N., Aydın, H., “Equilibrium and kinetics studies for adsorption of direct blue 71 from aqueous solution by wheat shells”, Journal of Hazardous Materials, Cilt 144, 300-306, 2007.
• Tsai, W.T., Hsien, K.J., Hsu, H.C., Lin, C.M., Lin, K.Y., Chiu, C.H., “Utilization of ground eggshell waste as an adsorbent for the removal of dyes from aqueous solution”, Bioresource Technology, Cilt 99, 1623-1629, 2008.
• Guezguez, I., Dridi-Dhaouadi, S., Mhenni, F., “Sorption of Yellow 59 on Posidonia oceanica,a non-conventional biosorbent: Comparison with activated carbons”, Industrial Crops and Products, Cilt 29, 197-204, 2009.
• Özer, D., Dursun, G., Özer, A., “Methylene blue adsorption from aqueous solution by dehydrated peanut hull”, Journal of Hazardous Materials, Cilt 144, 171-179, 2007.
• Çiçek, F., Özer, D., Özer, A., Özer, A., “Low cost removal of reactive dyes using wheat bran”, Journal of Hazardous Materials, Cilt 146, 408-416, 2007.
• Sivaraj, R., Namasivayam, C., Kadirvelu, K., “Orange peel as an adsorbent in the removal of Acid violet 17 (acid dye) from aqueous solutions”, Waste Management, Cilt 21, 105-110, 2001.
• Ardejani, F.D., Badii, K., Limaee, N.Y., Mahmoodi, N.M., Arami, M., Shafaei, S.Z., Mirhabibi, A.R., “Numerical modelling and laboratory studies on the removal of Direct Red 23 and Direct Red 80 dyes from textile effluents using orange peel, a low cost adsorbent”, Dyes and Pigments, Cilt 73, 178-185, 2007.
• Elkady, M.F., Ibrahim, A.M., Abd El-Latif, M.M., “Assessment of the adsorption kinetics, equilibrium and thermodynamics fort he potential removal of reactive red dye using eggshell biocomposite beads”, Desalination, Cilt 278, 412-423, 2011.
• Vijayaraghavan, K., Jegan, J., Palanivelu, K., Velan, M., “Removal ad recovery of copper from aqueous solution by eggshell in a packed column”, Minerals Engineering, Cilt 18, 545-547, 2005.
• Cesla, P., Fischer, J., Tesarova, E., Jandera, P., Stanek, V., “Effects of capillary coating and _-cyclodextrin additive to the background electrolyte on separation of sulphonated azodyes by capillary zone electrophoresis”, Journal of Chromatography A, Cilt 1149, 358-367, 2007.
• İleri, R., Çakır, G., “Bakır iyonlarının (Cu+2) sıvı ortamdan biyosorpsiyonla gideriminin izoterm sabitlerinin Matlab programı ilebelirlenmesi”, Ekoloji, Cilt 59, 8-17, 2006.
• Namasivayam, C., Kavitha, D., “Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste”, Dyes and Pigments, Cilt 54, 47-58, 2002.
• Kaya, N., Yücel, A.T., Konkan, A., Mocur, D., Gültekin, M., “Ceviz kabuğu ve fındık kabuğu kullanılarak sulu çözeltilerden dispers azo boyaların giderimi”, J. Fac. Eng. Archit. Gazi Univ., Cilt 26, 509-514, 2011.
• Aksu, Z., Tezer, S., “Biosorption of reactive dyes on the green alga Chlorella vulgaris”, Process Biochemistry, Cilt 40, 1347-1361, 2005.