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Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu

Year 2023, Volume: 38 Issue: 1, 309 - 318, 21.06.2022
https://doi.org/10.17341/gazimmfd.1009881

Abstract

Bu çalışmada, Ti6Al4V alaşımı önce sıcak daldırma alüminyumlama (SDA) işlemine ardından difüzyon tavlamasına tabi tutulmuştur. SDA 750ºC'de 3 dk uygulanmış ve bu işlemin uygulanmasıyla yüzeyde en üst tabaka bir Al ile Al3Ti difüzyon tabakasından bir kaplama oluşturulmuştur. Difüzyon tavlaması için sıcak daldırma alüminyumlanmış numuneler ısıtma hızı <12°C/s olan bir rezistans fırınında 1000°C'ye yükselecek şekilde ayarlanmış ve bu sıcaklıkta 1 saat tutulmuştur. Difüzyon tavlamasından sonra yeni bir formda Al3Ti ve oksit fazlarından (Al2TiO5, Al2O3) oluşan bir kompozit tabaka oluşmuştur. Numunelerin yapısal, mekaniksel ve aşınma özellikleri SEM-EDS, XRD, sertlik ve kuru ortam “ball-on disc ” konfigürasyonunda tribometre testleri kullanılarak karakterize edilmiştir. Ti-6Al-4V alaşımı üzerine uygulanan SDA ve difüzyon tavlaması ile sertlik sadece SDA uygulanmış numuneye kıyasla ~11 kat ve başlangıç haline kıyasla ~1,4 kat yükselmiştir. Aşınma testi sonuçlarına göre, numuneler arasında en iyi aşınma direncini SDA ve ardından difüzyon tavlaması uygulanmış numune göstermiştir.

References

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  • Deqing W., Ziyuan S., Yingli T., Microstructure and oxidation of hot-dip aluminized titanium at high temperature, Appl. Surf. Sci., 250, 238–246, 2005.
  • Zhang Q.Y., Zhou Y., Liu J.Q., Chen K.M., Mo J.G., Cui X.H., S.Q. Wang, Comparative research on dry sliding wear of hot-dip aluminized and uncoated AISI H13 steel, Wear., 344, 22–31, 2015.
  • Jiang W., Zhang B., Chen W., Wang S., Cui X., Dry Sliding Wear Behavior of Hot-Dip Aluminized Ti-6Al-4V Alloy as a Function of Sliding Velocity, J. Mater. Eng. Perform., 27, 5450–5459, 2018.
  • Li X.T., Huang L.J., Wei S.L., An Q., Cui X.P., Geng L., Cycle oxidation behavior and anti-oxidation mechanism of hot-dipped aluminum coating on TiBw/Ti6Al4V composites with network microstructure, Sci. Rep., 8, 1–11, 2018.
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  • Sitek R., Kaminski J., Borysiuk J., Matysiak H., Kubiak K., Kurzydlowski K.J., Microstructure and properties of titanium aluminides on Ti6Al4V titanium alloy produced by chemical vapor deposition method, Intermetallics., 36, 36–44, 2013.
  • Rastkar A.R., Parseh P., Darvishnia N., Hadavi S.M.M., Microstructural evolution and hardness of TiAl3 and TiAl2 phases on Ti–45Al–2Nb–2Mn–1B by plasma pack aluminizing, Appl. Surf. Sci., 276, 112–119, 2013.
  • Klimova-Korsmik O.G., Turichin G.A., Shalnova S.A., Gushchina M.O., Cheverikin V.V., Structure and properties of Ti-6Al-4V titanium alloy products obtained by direct laser deposition and subsequent heat treatment, in: J. Phys. Conf. Ser., IOP Publishing, 12061, 2018.
  • Liu J.-P., Luo L.-S., Su Y.-Q.,. Xu Y.-J, Li X.-Z., Chen R.-R., Guo J.-J., Fu H.-Z., Numerical simulation of intermediate phase growth in Ti/Al alternate foils, Trans. Nonferrous Met. Soc. China., 21, 598–603, 2011.
  • Sujata M., Bhargava S., Sangal S., On the formation of TiAl 3 during reaction between solid Ti and liquid Al, J. Mater. Sci. Lett., 16, 1175–1178, 1997.
  • Zhao Y.G., Zhou W., Qin Q.D., Liang Y.H., Jiang Q.C., Effect of pre-oxidation on the properties of aluminide coating layers formed on Ti alloys, J. Alloys Compd., 391, 136–140, 2005.
  • Li J., Lu Y., Zhang H., Xin L., Effect of grain size and hardness on fretting wear behavior of Inconel 600 alloys, Tribol. Int., 81, 215–222, 2015.
  • Wang P., Hirose M., Suzuki Y., Adachi K., Carbon tribo-layer for super-low friction of amorphous carbon nitride coatings in inert gas environments, Surf. Coatings Technol., 221, 163–172, 2013.
  • Suh N.P., The delamination theory of wear, Wear., 25, 111–124, 1973.
  • Kakaš D., Škorić B., Mitrović S., Babić M., Terek P., Miletić A., Vilotić M., Influence of load and sliding speed on friction coefficient of IBAD deposited TiN, Tribol. Ind., 31, 3–10, 2009.
Year 2023, Volume: 38 Issue: 1, 309 - 318, 21.06.2022
https://doi.org/10.17341/gazimmfd.1009881

Abstract

References

  • Chung D.D.L., 7 - Carbon-Matrix Composites, Carbon Composites, Editör: Chung D.D.L., Butterworth-Heinemann, 387-466, 2017.
  • Wang G., Li J., Lv K., Zhang W., Ding X., Yang G., Liu X, Jiang X., Surface thermal oxidation on titanium implants to enhance osteogenic activity and in vivo osseointegration, Sci. Rep., 6 (1), 1-13, 2016.
  • Yang C., Cui S., Wu Z., Zhu J., Huang J., Ma Z., Fu R.K.Y., Tian X., Chu P.K., Wu, Z, High efficient co-doping in plasma electrolytic oxidation to obtain long-term self-lubrication on Ti6Al4V, Tribol. Int., 160, 107018, 2021.
  • Tao X., Yao Z., Luo X., Comparison of tribological and corrosion behaviors of Cp Ti coated with the TiO2/graphite coating and nitrided TiO2/graphite coating, J. Alloys Compd., 718, 126-133, 2017.
  • Zhang L.C., Chen L.Y., Wang L, Surface modification of titanium and titanium alloys: technologies, developments, and future interests, Adv. Eng. Mater., 22 (5), 1901258, 2020.
  • Torres Y., Sarria P., Gotor F.J., Gutiérrez E., Peon E., Beltrán A.M., González J.E., Surface modification of Ti-6Al-4V alloys manufactured by selective laser melting: Microstructural and tribo-mechanical characterization, Surf. Coatings Technol., 348, 31-40, 2018.
  • Probst J., Gbureck U., Thull R, Binary nitride and oxynitride PVD coatings on titanium for biomedical applications, Surf. Coatings Technol., 148 (2-3), 226-233, 2001.
  • Fazel M., Salimijazi H.R., Shamanian M., Improvement of corrosion and tribocorrosion behavior of pure titanium by subzero anodic spark oxidation, ACS applied materials & interfaces, 10 (17), 15281-15287, 2018.
  • Guleryuz H., Cimenoglu H., Surface modification of a Ti–6Al–4V alloy by thermal oxidation, Surf. Coatings Technol., 192 (2-3), 164-170, 2005.
  • Patel P., Jamnapara N.I., Zala A., Kahar S.D., Investigation of hot-dip aluminized Ti6Al4V alloy processed by different thermal treatments in an oxidizing atmosphere, Surf. Coatings Technol., 385, 125323, 2020.
  • Yürektürk Y., Baydoğan M., Characterization of ferritic ductile iron subjected to successive aluminizing and austempering, Surf. Coatings Technol., 347, 142–149, 2018.
  • Awan G.H., Ul Hasan F., The morphology of coating/substrate interface in hot-dip-aluminized steels, Mater. Sci. Eng. A. 472, 157–165, 2008.
  • Ei-Mahallawy N.A., Taha M.A., Shady M.A., Ei-Sissi A.R., Attia A.N., Reif W., Analysis of coating layer formedon steel strips during aluminising by hot dipping in Al-Si baths, Mater. Sci. Technol., 13, 832–840, 1997.
  • Jeng S.-C., Oxidation behavior and microstructural evolution of hot-dipped aluminum coating on Ti-6Al- 4V alloy at 800 C, Surf. Coatings Technol., 235, 867–874, 2013.
  • Zhang Z.G., Peng Y.P., Mao Y.L., Pang C.J., Lu L.Y., Effect of hot-dip aluminizing on the oxidation resistance of Ti–6Al–4V alloy at high temperatures, Corros. Sci., 55, 187–193, 2012.
  • Deqing W., Ziyuan S., Yingli T., Microstructure and oxidation of hot-dip aluminized titanium at high temperature, Appl. Surf. Sci., 250, 238–246, 2005.
  • Zhang Q.Y., Zhou Y., Liu J.Q., Chen K.M., Mo J.G., Cui X.H., S.Q. Wang, Comparative research on dry sliding wear of hot-dip aluminized and uncoated AISI H13 steel, Wear., 344, 22–31, 2015.
  • Jiang W., Zhang B., Chen W., Wang S., Cui X., Dry Sliding Wear Behavior of Hot-Dip Aluminized Ti-6Al-4V Alloy as a Function of Sliding Velocity, J. Mater. Eng. Perform., 27, 5450–5459, 2018.
  • Li X.T., Huang L.J., Wei S.L., An Q., Cui X.P., Geng L., Cycle oxidation behavior and anti-oxidation mechanism of hot-dipped aluminum coating on TiBw/Ti6Al4V composites with network microstructure, Sci. Rep., 8, 1–11, 2018.
  • Wang Y., Xiong J., Yan J., Fan H., Wang J., Oxidation resistance and corrosion behavior of hot-dip aluminized coatings on commercial-purity titanium, Surf. Coatings Technol., 206, 1277–1282, 2011.
  • Sitek R., Kaminski J., Borysiuk J., Matysiak H., Kubiak K., Kurzydlowski K.J., Microstructure and properties of titanium aluminides on Ti6Al4V titanium alloy produced by chemical vapor deposition method, Intermetallics., 36, 36–44, 2013.
  • Rastkar A.R., Parseh P., Darvishnia N., Hadavi S.M.M., Microstructural evolution and hardness of TiAl3 and TiAl2 phases on Ti–45Al–2Nb–2Mn–1B by plasma pack aluminizing, Appl. Surf. Sci., 276, 112–119, 2013.
  • Klimova-Korsmik O.G., Turichin G.A., Shalnova S.A., Gushchina M.O., Cheverikin V.V., Structure and properties of Ti-6Al-4V titanium alloy products obtained by direct laser deposition and subsequent heat treatment, in: J. Phys. Conf. Ser., IOP Publishing, 12061, 2018.
  • Liu J.-P., Luo L.-S., Su Y.-Q.,. Xu Y.-J, Li X.-Z., Chen R.-R., Guo J.-J., Fu H.-Z., Numerical simulation of intermediate phase growth in Ti/Al alternate foils, Trans. Nonferrous Met. Soc. China., 21, 598–603, 2011.
  • Sujata M., Bhargava S., Sangal S., On the formation of TiAl 3 during reaction between solid Ti and liquid Al, J. Mater. Sci. Lett., 16, 1175–1178, 1997.
  • Zhao Y.G., Zhou W., Qin Q.D., Liang Y.H., Jiang Q.C., Effect of pre-oxidation on the properties of aluminide coating layers formed on Ti alloys, J. Alloys Compd., 391, 136–140, 2005.
  • Li J., Lu Y., Zhang H., Xin L., Effect of grain size and hardness on fretting wear behavior of Inconel 600 alloys, Tribol. Int., 81, 215–222, 2015.
  • Wang P., Hirose M., Suzuki Y., Adachi K., Carbon tribo-layer for super-low friction of amorphous carbon nitride coatings in inert gas environments, Surf. Coatings Technol., 221, 163–172, 2013.
  • Suh N.P., The delamination theory of wear, Wear., 25, 111–124, 1973.
  • Kakaš D., Škorić B., Mitrović S., Babić M., Terek P., Miletić A., Vilotić M., Influence of load and sliding speed on friction coefficient of IBAD deposited TiN, Tribol. Ind., 31, 3–10, 2009.
There are 30 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Makaleler
Authors

Yakup Yürektürk 0000-0001-8199-4032

Publication Date June 21, 2022
Submission Date October 14, 2021
Acceptance Date February 3, 2022
Published in Issue Year 2023 Volume: 38 Issue: 1

Cite

APA Yürektürk, Y. (2022). Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38(1), 309-318. https://doi.org/10.17341/gazimmfd.1009881
AMA Yürektürk Y. Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu. GUMMFD. June 2022;38(1):309-318. doi:10.17341/gazimmfd.1009881
Chicago Yürektürk, Yakup. “Sıcak daldırma alüminyumlama (SDA) Ve difüzyon Tavlaması Ile yüzeyi Modifiye Edilmiş Ti-6Al-4V alaşımının Karakterizasyonu”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38, no. 1 (June 2022): 309-18. https://doi.org/10.17341/gazimmfd.1009881.
EndNote Yürektürk Y (June 1, 2022) Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38 1 309–318.
IEEE Y. Yürektürk, “Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu”, GUMMFD, vol. 38, no. 1, pp. 309–318, 2022, doi: 10.17341/gazimmfd.1009881.
ISNAD Yürektürk, Yakup. “Sıcak daldırma alüminyumlama (SDA) Ve difüzyon Tavlaması Ile yüzeyi Modifiye Edilmiş Ti-6Al-4V alaşımının Karakterizasyonu”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38/1 (June 2022), 309-318. https://doi.org/10.17341/gazimmfd.1009881.
JAMA Yürektürk Y. Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu. GUMMFD. 2022;38:309–318.
MLA Yürektürk, Yakup. “Sıcak daldırma alüminyumlama (SDA) Ve difüzyon Tavlaması Ile yüzeyi Modifiye Edilmiş Ti-6Al-4V alaşımının Karakterizasyonu”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol. 38, no. 1, 2022, pp. 309-18, doi:10.17341/gazimmfd.1009881.
Vancouver Yürektürk Y. Sıcak daldırma alüminyumlama (SDA) ve difüzyon tavlaması ile yüzeyi modifiye edilmiş Ti-6Al-4V alaşımının karakterizasyonu. GUMMFD. 2022;38(1):309-18.