Atık sulardan boyar madde giderimi için çeltik artıklarından karbon esaslı sorbentlerin hazırlanması

Yıl 2024, Cilt: 39 Sayı: 2, 1271 - 1284, 30.11.2023

Zeynep Cansu Ulutaş , Dilşad Dolunay Eslek Koyuncu , Müjgan Okur

https://doi.org/10.17341/gazimmfd.1252497

Öz

Çeltik, ülkemizde fazla miktarda tarımı yapılan ve artıkları çevre için sorun teşkil eden bir tarım ürünüdür. Bu artıkların zengin silika ve karbon içeriği birçok alanda kullanılmasına olanak sağlamaktadır. Bu çalışmada, çeltik artıklarından karbon malzemesinin hazırlanması ve boyar madde adsorpsiyonunda kullanılması amaçlanmıştır. Çalışmada, karbon esaslı malzemeler (C-CTAB, K-CTAB, C-P123, K-P123), ham çeltik (C) ve çeltik külünün (K) iki farklı yüzey aktif madde olan setil trimetil amonyum bromür (CTAB) ve triblok kopolimer Pluronic (P123) ile modifiye edilmesiyle hazırlanmıştır. Hazırlanan karbon esaslı malzemeler atık sulardan boyar madde giderimi amacıyla Asit Viyolet 90 (AV 90) boyar maddesinin giderimi için test edilmiştir. Bu çalışmada, hazırlanan malzemeler için XRF, FT-IR, SEM-EDS, N2 adsorpsiyon-desorpsiyon ve zeta potansiyeli analizleri yapılmıştır. Bu analizler sonucunda, K-CTAB malzemesi için ortalama gözenek çapı 3,8 nm, toplam gözenek hacmi 0,26 cm3/g, BET yüzey alanı 180 m2/g bulunmuştur. Çalışılan bütün malzemelerde en yüksek boyar madde giderimi pH 2’de elde edilmiştir. K-CTAB sorbenti çalışılan tüm pH değerlerinde %95’ın üzerinde boyar madde giderimi sergilemiştir. Deneysel verilerin Langmuir, Freundlich ve Temkin izoterm modelleri ile uyumlu olması adsorpsiyonun tek ve çok tabakalı homojen ve heterojen yüzeylerde gerçekleştiğini göstermektedir. Sonuç olarak çeltik artıklarının atık sulardan boyar madde gidermek amacıyla sorbent geliştirilmesinde etkin olarak değerlendirilebileceği görülmüştür.

Anahtar Kelimeler

Çeltik artıkları, boyar madde giderimi, adsorpsiyon, karbon esaslı sorbent, CTAB

Destekleyen Kurum

TUBİTAK

Proje Numarası

1919B012004938

Teşekkür

Bu çalışma 2209/A Üniversite Öğrencileri Araştırma Projeleri Destek Programı (1919B012004938) kapsamında TÜBİTAK tarafından finansal olarak desteklenmiştir.

Kaynakça

• 1. Sharma, P., Prakash, J., Kaushal, R., An insight into the green synthesis of SiO2 nanostructures as a novel adsorbent for removal of toxic water pollutants, Environmental Research, 212, 113328, 2022.
• 2. Tabassam, N., Mutahir, S., Khan, M. A., Khan, I. U., Habiba, U., Refat, M. S., Facile synthesis of cinnamic acid sensitized rice husk biochar for removal of organic dyes from wastewaters: Batch experimental and theoretical studies, Materials Chemistry and Physics, 288, 126327, 2022.
• 3. Osma J.F., Saravia V., Toca-Herrera J.L., Couto S.R., Sunflower seed shells: A novel and effective low-cost adsorbent for the removal of the diazo dye Reactive Black 5 from aqueous solutions, Journal of Hazardous Materials, 147, 900-905, 2007.
• 4. Haider, J. B., Haque, M. I., Hoque, M., Hossen, M. M., Mottakin, M., Khaleque, M. A., Johir, M.A.H., Zhou, J.L., Ahmed, M.B., Zargar, M., Efficient extraction of silica from openly burned rice husk ash as adsorbent for dye removal, Journal of Cleaner Production, 380, 135121, 2022.
• 5. Shirazi, E. K., Metzger, J. W., Fischer, K., Hassani, A. H., Simultaneous removal of a cationic and an anionic textile dye from water by a mixed sorbent of vermicompost and Persian charred dolomite, Chemosphere, 234, 618-629, 2019.
• 6. Bianchi, C. L., Djellabi, R., Della Pina, C., Falletta, E., Doped-polyaniline based sorbents for the simultaneous removal of heavy metals and dyes from water: Unravelling the role of synthesis method and doping agent, Chemosphere, 286, 131941, 2022.
• 7. Malhotra, A., Srivastava, S., Manjhu, S., Lokhande, R. S., Sahu, R., Jain, S. K., Sharma, K.B., Tripathi, B., Study of adsorbent characteristics of palm leaves powder as a bio sorbent for removal of malachite green (MG) dye, Materials Today: Proceedings, 67, 900-904, 2022.
• 8. Mohammady, M.S., Hashemian, S., Tabatabaee, M., Cu-ZIF@ red soil nanocomposite sufficient sorbent for dye removal, Journal of Molecular Structure, 1275, 134566, 2023.
• 9. Ibrahim, N. A., Abdellatif, F. H., Hasanin, M. S., Abdellatif, M. M., Fabrication, characterization, and potential application of modified sawdust sorbents for efficient removal of heavy metal ions and anionic dye from aqueous solutions, Journal of Cleaner Production, 332, 130021, 2022.
• 10. Reçber, Z. B., Burhan, H., Bayat, R., Nas, M. S., Calimli, M. H., Demirbas, Ö., Şen, F., Hassan, K. M., Fabrication of activated carbon supported modified with bimetallic-platin ruthenium nano sorbent for removal of azo dye from aqueous media using enhanced ultrasonic wave, Environmental Pollution, 302, 119033, 2022.
• 11. Chen, W.H., Lin, T.S., Guo, G.L., Huang, W.S., Ethanol production from rice straw hydrolysates by Pichia stipitis, Energy Procedia, 14, 1261-1266, 2012.
• 12. Sangon, S., Hunt, A. J., Ngernyen, Y., Youngme, S., Supanchaiyamat, N., Rice straw-derived highly mesoporous carbon-zinc oxide nanocomposites as high-performance photocatalytic adsorbents for toxic dyes, Journal of Cleaner Production, 318, 128583, 2021.
• 13. Gebretatios, A. G., Pillantakath, A. R. K. K., Witoon, T., Lim, J. W., Banat, F., Cheng, C. K., Rice husk waste into various template-engineered mesoporous silica materials for different applications: A comprehensive review on recent developments, Chemosphere, 136843, 2022.
• 14. Liou, T.H., Wu, S.J., Kinetics study and characteristics of silica nanoparticles produced from biomass-based material, Industrial and Engineering Chemistry Research, 49, 8379-8387, 2010.
• 15. Okur, M., Koyuncu, D.D.E., Çeltik Artıklarının Sürdürülebilir Yeşil Teknoloji Ürünlerine Dönüşümü Güncel Multidisipliner Teknik Araştırmalar, Basım sayısı:1, Editör: Doç. Dr. Ali ÖZ, Strategic Researches Academy Academic Publishing, 105-132, 2022.
• 16. Yuan, Y., Sun, Y., Feng, Z., Li, X., Yi, R., Sun, W., Zhao, C., Yang, L., Nitrogen-doped hierarchical porous activated carbon derived from paddy for high-performance supercapacitors, Materials, 14, 318, 2021.
• 17. Horax, K.M., Bao, S., Wang, M., Li, Y., Analysis of graphene-like activated carbon derived from rice straw for application in supercapacitor, Chinese Chemical Letters, 28, 2290-2294, 2017.
• 18. Zhang, X., Li, Y., Li, G., Hu, C., Preparation of Fe/activated carbon directly from rice husk pyrolytic carbon and its application in catalytic hydroxylation of phenol, RSC Advances, 5, 4984–4992, 2015.
• 19. Costa, J.A.S., Paranhos, C.M., Evaluation of rice husk ash in adsorption of Remazol Red dye from aqueous media, SN Applied Sciences, 1, 397, 2019.
• 20. Quansah, J. O., Hlaing, T., Lyonga, F. N., Kyi, P.P., Hong S.H., Lee, C.G., Park, S. J., Nascent rice husk as an adsorbent for removing cationic dyes from textile wastewater, Applied Sciences, 10, 3437, 2020.
• 21. Homagai, P. L., Poudel, R., Poudel, S., Bhattarai, A., Adsorption and removal of crystal violet dye from aqueous solution by modified rice husk, Heliyon, 8, e09261, 2022.
• 22. Jilong, X, Zheming, N., Li, Z., Qiaoqiao, W., Qian, X., Lulu, R., Haitao, Z., Adsorption characteristics of calcined layered double hydroxides over Acid Violet 90, Journal of the Chinese Ceramic Society, 39 (2), 2011.
• 23. Hashem, A., Aly, A.A., Abdel-Mohsen, A.M., Novel Agro-waste for adsorption of Acid Violet 90 from contaminated water: Isotherms and Kinetics, Research Square, 2022.
• 24. Okur M., Aktı F., The removal of C.I. acid violet 90 metal-complex dye using synthetic and natural zeolite from aqueous solutions, Journal of the Faculty of Engineering and Architecture of Gazi University, 31 (3), 677-686, 2016.
• 25. Okur, M., Aktı, F., Çetintaş, A., Polianilin/aljinat malzemesinin Asit Violet 90 boyar maddesinin gideriminde kullanılması: Kinetik ve İzoterm Değerlendirmesi, Gazi University Journal of Science Part C, 6, 4, 729-740, 2018.
• 26. Koyuncu, D.D.E., Okur, M., Removal of AV 90 dye using ordered mesoporous carbon materials prepared via nanocasting of KIT-6: adsorption isotherms, kinetics and thermodynamic analysis, Separation and Purification Technology, 257, 117657, 2021.
• 27. Kauldhar, B.S., Yadav S.K., Turning waste to wealth: A direct process for recovery of nano-silica and lignin from paddy straw agro-waste, Journal of Cleaner Production, 194, 158–166, 2018.
• 28. Merkache, R., Fechete, I., Maamache, M., Bernard, M., Turek, P., Al-Dalama, K., Garin, F., 3D ordered mesoporous Fe-KIT-6 catalysts for methylcyclopentane (MCP) conversion and carbon dioxide (CO2) hydrogenation for energy and environmental applications, Applied Catalysis A: General, 504, 672–681, 2015.
• 29. Xu, J., Hong Y., Cheng, M.J., Xue, B., Li, Y.X., Vanadyl acetylacetonate grafted on ordered mesoporous silica KIT-6 and its enhanced catalytic performance for direct hydroxylation of benzene to phenol, Microporous & Mesoporous Materials, 285, 223–230, 2019.
• 30. Cruz, G., Braz, C.E.M., Ferreira, S.L., Santos, A.M., Crnkovic, P.M., Physicochemical properties of Brazilian biomasses: potential applications as renewable energy source. 22nd International Congress of Mechanical Engineering, 2013.
• 31. Mamilla, J.L.K., Novak, U., Grilc M., Likozar, B., Natural deep eutectic solvents (DES) for fractionation of waste lignocellulosic biomass and its cascade conversion to value-added bio-based chemicals, Biomass & Bioenergy, 120, 417–425, 2019.
• 32. Mohammadi, M., Shafiei, M., Abdolmaleki, A., Karimi, K., Mikkola, J.P., Larsson, C., A morpholinium ionic liquid for rice straw pretreatment to enhance ethanol production, Industrial Crops and Products, 139, 111494, 2019.
• 33. Belachew, N., Hinsene, H., Preparation of cationic surfactant‑modified kaolin for enhanced adsorption of hexavalent chromium from aqueous solution, Applied Water Science, 10 (38), 2020.
• 34. Ismail, N.H.C., Bakhtiar, N.S.A.A., Akil, H.M., Effects of cetyltrimethylammonium bromide (CTAB) on the structural characteristic of non-expandable muscovite, Materials Chemistry and Physics, 196, 324-332, 2017.
• 35. Ntakirutimana, S., Tan, W., Wang, Y., Enhanced surface activity of activated carbon by surfactants synergism, RSC Advances, 9 (45), 26519–26531, 2019.
• 36. Purnawira, B., Purwaningsih, H., Ervianto, Y., Pratiwi, V. M., Susanti, D., Rochiem, R., Purniawan, A., Synthesis and characterization of mesoporous silica nanoparticles (MSNp) MCM 41 from natural waste rice husk, IOP Conference Series: Materials Science and Engineering, 541, 012018, 2019.
• 37. Bala, T., Gunning, R. D., Venkatesan, M., Godsell, J. F., Roy, S., Ryan, K. M., Block copolymer mediated stabilization of sub-5 nm superparamagnetic nickel nanoparticles in an aqueous medium, Nanotechnology, 20 (41), 415603, 2009.
• 38. Pirbazari, A.E., Kisom, B.F., Khararoodi, M.G., Anionic surfactant-modified rice straw for removal of methylene blue from aqueous solution, Desalination and Water Treatment, 57 (39), 18202–18216, 2015.
• 39. Koyuncu D. D. E., Okur, M., Investigation of dye removal ability and reusability of green and sustainable silica and carbon-silica hybrid aerogels prepared from paddy waste ash, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 628, 127370, 2021.
• 40. Dhaneswara, D., Marito, H.S., Fatriansyah, J.F., Sofyan, N., Adhika, D.R., Suhariadi, I., Spherical SBA-16 particles synthesized from rice husk ash and corn cob ash for efficient organic dye adsorbent, Journal of Cleaner Production, 357, 131974, 2022.
• 41. Civan Çavuşoğlu, F., Bayazit, Ş.S., Salam, M.A., Montmorillonit bazlı nanokiller kullanılarak kristal viyolet boyar maddesinin sulu çözeltilerden giderimi: Kinetik ve denge çalışmaları, 38 (3), 1907-1918, 2023.
• 42. Cerit A., Using polyaniline/walnut shell waste composites for removal of methylene blue from wastewater, Journal of the Faculty of Engineering and Architecture of Gazi University, 36 (4), 1801-1816, 2021.