Kombucha çayı kullanarak yeşil sentez ve kimyasal sol-jel yöntemi ile ZnO nanoparçacıklarının sentezlenmesi ve fotokatalitik aktivitelerinin karşılaştırılması

Yıl 2025, Cilt: 40 Sayı: 1, 43 - 58, 16.08.2024

Sevil Cetınkaya Gürer , Zeynep Özserçe Haste

https://doi.org/10.17341/gazimmfd.1250471

Öz

Bu çalışmada Kombucha çayı (KÇ) kullanılarak yeşil sentez ve kimyasal sol-jel yöntemleri ile çinko oksit nanoparçacıkları sentezlenerek özellikleri incelendi. Kombucha çayı ile çinko oksit nanoparçacıklarının ( ZnO-NP(KÇ) ) en uygun sentez şartlarını belirlemek amacı ile reaksiyon sıcaklığı 25, 40 ve 60 0C ve 1, 2, 3 ve 4 h reaksiyon süresini alınarak deneyler gerçekleştirildi. . İncelenen bu parametrelerde 60 0C sıcaklık ve reaksiyon süresi 3 olarak belirlendi. Karşılaştırma amacı ile kimyasal bir yöntem olan sol-jel yöntemiyle de çinko oksit nanoparçacıkları ( ZnO-NP(SJ) ) 60 0C reaksiyon sıcaklığında ve 3 h reaksiyon süresinde sentezi gerçekleştirildi. Her iki yöntemle kullanılarak hazırlanan ZnO-NP’nin karakterizasyon UV/Vis, FTIR, XRD, SEM teknikleri kullanılarak incelendi. Her iki yöntem kullanılarak sentezlenen ZnO-NP(KÇ) ve ZnO-NP(SJ)”nin ortalama kristalit boyutu sırasıyla 22 nm ve 89 nm Debye Schrerrer denklemi ile belirlendi. Çalışmanın ikinci bölümünde her iki yöntemle hazırlanan ZnO-NP’nin, UV lamba altında ve 180 min sonunda, metilen mavisi (MM) çözeltisinde boya giderimi incelenerek fotokatalitik aktiviteleri karşılaştırıldı. Hazırlanan ZnO-NP(KÇ)’nin %76 ve ZnO-NP(SJ)’nin %67 sulu çözeltiden MM’yi giderdiği belirlendi. Her iki yöntemle de sentezlenen ZnO-NP’i kullanarak MM’nin fotokatalitik bozunma kinetiğinin birinci dereceden reaksiyon kinetiğine uyduğu belirlendi.

Anahtar Kelimeler

Çinko oksit nanoparçacık, kombucha çayı, yeşil sentez, metilen mavisi, fotokatalitik aktivite

Kaynakça

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