Olea europea L. ekstresinde sentezlenmiş AgNP'lerle katkılı PLA liflerin elektroeğirme yöntemiyle üretilmesi, karakterizasyonu ve antibakteriyel aktivitesi

Yıl 2025, Cilt: 40 Sayı: 3, 2119 - 2128, 21.08.2025

Numan Hoda , Leyla Budama Akpolat , Firdevs Mert Sivri , Çağlar Sivri

https://doi.org/10.17341/gazimmfd.1566658

Öz

Yeşil kimya, tehlikeli kirleticilerin oluşumunu en aza indiren veya tamamen durduran kimyasal ürünler ve süreçler geliştirme olanağı sunmaktadır. Bitki bazlı nanopartiküllerin yeşil sentezi, çok yönlülüğü ve uygulama kolaylığı nedeniyle şu anda en çok tercih edilen teknik olarak kabul edilmektedir. Bu çalışma, Olea europea L.'nin sulu ekstresi kullanılarak AgNP'lerin sentezlenmesi ve bu sentezlenen nanopartiküllerle katkılanmış PLA polimerinden elektro eğirme ile nanolif üretimini amaçlamaktadır. Sentezlenen nanopartikülleri karakterize etmek için UV-Vis spektroskopisi, geçirimli elektron mikroskobu (TEM), optik mikroskopi, X-ışını kırınımı (XRD), ve taramalı elektron mikroskobu (SEM) kullanılmıştır. AgNP'lerin etkili sentezi, UV-vis analizi kullanılarak 429 nm'de bir yüzey plazmon rezonans tepe noktasının gözlemlenmesiyle kanıtlanmıştır. TEM analizinde ise, yüzey merkezli kübik yapıya sahip AgNP'lerin ortalama çapı ölçülmüş ve XRD analizi bu ölçümü doğrulamıştır. Sentezlenen AgNP’lerin yüzey merkezli kübik yapıda olduğu XRD analizi ile ortaya konulmuş ve ortalama çapı TEM ile 6±4 nm olarak ölçülmüştür. ASTM E 2149'a göre, AgNP'leri içeren Olea europea L. ekstresi E. Coli'ye karşı antibakteriyel aktivite göstermiştir. Ayrıca optik mikroskopi incelemeleri, nanopartikül katkılamasından dolayı nanoliflerin homojenliğinin arttığını göstermiştir. Elektroeğirme ile üretilen nanopartikül katkılı nanoliflerin ortalama boyutu 0,96 ± 0,41 µm olarak ölçülmüştür.

Anahtar Kelimeler

Yeşil sentez , Olea europea L , AgNPs , elektroeğirme , nanofiberler

Etik Beyan

Gerek yoktur.

Destekleyen Kurum

Bu çalışma, FDK-2015-757 ve FBA-2014-83 proje numaralarıyla Akdeniz Üniversitesi Bilimsel Araştırma Projeleri Birimi tarafından desteklenmiştir.

Teşekkür

Yazarlar, Zeytin yaprağı bitkisinin tür tanımlaması için Prof. Dr. Ahmet AKSOY'a teşekkür eder.

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