Melissa officinalis yaprakları kullanılarak kükürt nanopartiküllerinin yeşil sentezi ve üzüm bağlarında külleme (Erysiphe necator schw.) üzerindeki etkisi

Yıl 2025, Cilt: 40 Sayı: 4, 2425 - 2436

Ramazan Orhan , İnanç Özgen , Şahimerdan Türkölmez , Ercan Aydoğmuş , M. Deniz Turan , Buket Erzen , İsmail Rastgeldi

https://doi.org/10.17341/gazimmfd.1577441

Öz

Tüm dünyada ve ülkemiz bağcılığında önemli ölçüde ürün ve kalite kayıplarına yol açan fungal hastalıklardan birisi de Erysiphe necator Schw. tarafından oluşturulan küllemedir. Hastalık, sıcak ve kuru hava koşullarında salkım kalitesini ve verimini olumsuz yönde etkilemektedir. Bu hastalığın mücadelesinde toz kükürt kullanılmakta ancak çoğu zaman kükürtün kullanımından dolayı bitkide fitotoksisiteye neden olmaktadır. Günümüzde nanopartiküller farklı fizikokimyasal özelliklerinden dolayı oldukça ilgi çekmektedir. Nanoparçacıklar küçük boyutu, geniş yüzey alanı ve yüksek reaktiviteye sahip olmaları nedeniyle fungisit, bakterisit ve nanogübrelerde kullanılmaktadır. Nanomalzemelerin sürdürülebilir ve çevre dostu bir yöntemle üretilmesi önemlidir. Bu yöntemler arasında, basitliği, kullanımı, çevre dostu, mükemmel biyouyumluluğu ve düşük biyotoksisitesi nedeniyle yeşil sentez yöntemi en uygun yöntemdir. Mevcut çalışmada polifenol içeriği yüksek ve kolay temin edilen bir bitki olan melisa yaprağı (Melissa officinalis L.) kullanılarak nanokükürt sentezlenmiştir. Sentezlenen SNP’lerin etkin oluşumu UV-Görünür spektroskopisi, XRD, FTIR, FE-SEM, EDX, TEM, partikül boyut analizi ve zeta potansiyeli analizleri ile incelendi. Ortalama parçacık boyutunun 21,4 ile 126,8 nm arasında olduğu belirlendi. Sentezlenen nanokükürt üzüm bağındaki asmalara uygulanarak bağ küllemesi (Erysiphe necator Schw.) hastalığına karşı etkisi belirlendi ve toz kükürt ile karşılaştırıldı. Nanokükürt uygulamasının %79,21, toz kükürt uygulamasının ise bağ küllemesi hastalığını önlemede %68,28 etkili olduğu bulundu.

Anahtar Kelimeler

Yeşil sentez , Nanokükürt , Melisa yaprağı , Bağ küllemesi (Erysiphe necator Schw.)

Etik Beyan

Sunduğumuz bilgileri, dokümanları ve verileri akademik ve etik kurallar çerçevesinde elde ettiğimizi, çalışmamızda yararlandığımız eserlerin tamamına atıfta bulunarak kaynak gösterdiğimizi ve elde ettiğimiz verilerde ve sonuçlarda herhangi bir değişiklik yapmadığımızı beyan ederiz.

Destekleyen Kurum

Türkiye Bilimsel ve Teknik Araştırma Kurumu (TÜBİTAK) 1002 Hızlı Destek Programı tarafından 222O198 protokol numarası ile desteklenmiştir.

Proje Numarası

222O198

Teşekkür

Bu çalışma Türkiye Bilimsel ve Teknik Araştırma Kurumu (TÜBİTAK) 1002 Hızlı Destek Programı tarafından 222O198 protokol numarası ile desteklenmiştir. TÜBİTAK’a teşekkürlerimizi sunarız.

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