SOME DETERIORATION PARAMETERS OF EDIBLE OILS AND FATS SOLD IN TÜRKİYE MARKETS

Abstract

In this study, some deterioration parameters were determined in nine different types of edible fats and oils (46 samples) obtained from the Turkish market, their compliance with the Turkish Food Codex and Standards was evaluated and compared with the literature. Six samples including (3 margarines, 2 shortenings and 1 riviera olive oil) had peroxide value (PV) that exceeded the codex limit. The oils with the highest PVs were found to be fish oils (8.5-27.4 meqO2/kg), peanut oils (9.2-32.1 meqO2/kg) and extra virgin olive oils (10.37-17.66 meqO2/kg). Free fatty acidity (FFA) content of one of the riviera olive oils (1.29%) and extra virgin olive oil (0.81-1.13%) sample were above the limit value of the Codex. The highest conjugated-diene and -triene were determined in fish oils (9.12-12.3 and 2.42-5.60, respectively). The p-Anisidine values in hazelnut and fish oils ranged from 2 to 61.

Keywords

• Edible oils
• oxidation
• peroxide value
• p-Anisidine
• free fatty acidity
• deterioration parameters

Supporting Institution

Van Yüzüncü Yıl University Research Fund

Project Number

FYL-2019-8058

Thanks

This study is a part of a master dissertation. The authors gratefully acknowledge the support provided for this work by the Van Yüzüncü Yıl University Research Fund (FYL-2019-8058).

TÜRKİYE PAZARLARINDA SATILAN YEMEKLİK SIVI VE KATI YAĞLARIN BAZI BOZULMA PARAMETRELERİ

Abstract

Bu çalışmada, Türkiye pazarından temin edilen dokuz çeşit yemeklik katı ve sıvı yağda (46 numune) bazı bozulma parametreleri belirlenmiş, bunların Türk Gıda Kodeksi gerekliliklerine uygunluğu değerlendirilmiş ve literatür ile karşılaştırılmıştır. Altı numunede kodeks limitini aşan peroksit sayısı (PS) tespit edilmiştir (3 margarin, 2 katı yağ ve 1 riviera zeytinyağı). En yüksek PS'na sahip yağlar balık yağları (8.5-27.4 meqO2/kg), yer fıstığı yağları (9.2-32.1 meqO2/kg) ve natürel sızma zeytinyağı (10.37-17.66 meqO2/kg) olmuştur. Serbest yağ asitliği (SYA) oranları riviera zeytin yağlarının birinde ve sızma zeytinyağının tamamında sınır değerin üzerinde çıkmıştır. En yüksek konjuge-dien ve -trien balık yağlarında belirlenmiştir (sırasıyla 9.12-12.3 ve 2.42-5.60). SYA oranları riviera zeytinyağının birinde (%1.29) ve natürel sızma zeytinyağının tamamında (%0.81-1.13) sınır değerin üzerinde çıkmıştır. Fındık ve balık yağlarında bulunan p-Anisidin değerleri 2 ile 61 arasında değişmiştir.

Keywords

• Yemeklik yağlar
• oksidasyon
• peroksit değeri
• p-Anisidin
• serbest yağ asitliği
• bozulma parametreleri

Project Number

FYL-2019-8058

References

1. Ahmad, F., Al Kanhal Mohamad Ahmad, A. Z., Tariq, H., Marc, A., Achille, T. F., Mory, G., Koffi, P. V. N., Georges, A. N., Chuelong, S., Siriuthane, T. (2011). The Effect on Growth and Lipid Profile in Rats Fed Microwave Heated Corn Oil. Pakistan Journal of Nutrition, 10(12), 1104–1108.
2. Albert, B. B., Derraik, J. G., Cameron-Smith, D., Hofman, P. L., Tumanov, S., Villas-Boas, S. G., Garg, M. L., Cutfield, W. S. (2015). Fish oil supplements in New Zealand are highly oxidised and do not meet label content of n-3 PUFA. Scientific Reports, 5, 7928. https://doi.org/10.1038/srep07928
3. Ali, M. A., Bin Mesran, M. H., Abd Latip, R., Othman, N. H., Mahmood, N. A. N. (2016). Effect of microwave heating with different exposure times on the degradation of corn oil. International Food Research Journal, 23(2), 842–848.
4. Ali, M. A., Najmaldien, A. H. A., Latip, R. A., Othman, N. H., Majid, F. A. A., Salleh, L. M. (2013). Effect of heating at frying temperature on the quality characteristics of regular and high-oleic acid sunflower oils. Acta Scientiarum Polonorum Technologia Alimentaria, 12(2), 159–167.
5. Ali, M. A., Nouruddeen, Z. B., Muhamad, I. I., Abd Latip, R., Othman, N. H. (2014). Effect of Microwave Heating on Oxidative Degradation of Sunflower Oil in the Presence of Palm Olein. Sains Malaysiana, 43(8), 1189–1195.
6. Anjum, F., Anwar, F., Jamil, A., Iqbal, M. (2006). Microwave roasting effects on the physico-chemical composition and oxidative stability of sunflower seed oil. Journal of the American Oil Chemists Society, 83(9), 777–784. https://doi.org/DOI 10.1007/s11746-006-5014-1
7. AOCS. (1989a). Official Method Cd 8-53. Peroxide value. In Official methods and recommended practices of the American Oil Chemists’ Society (4th ed.). AOCS, Champaign, IL, USA.
8. AOCS. (1989b). Official Method Ch 5-91. Specific Extinction of Oils and Fats, Ultraviolet Absorption. In Official methods and recommended practices of the American Oil Chemists’ Society. AOCS, Champaign, IL, USA.

9. AOCS. (1998). Official Method Cd 18-90. p-Anisidine Value.Official methods and recommended practices of the American Oil Chemists’ Society. AOCS Champaign, IL, USA.
10. AOCS. (2004). Official Method Ca 5a-40. Free Fatty Acids in Crude and Refined Fats and Oils. In Official methods and recommended practices of the American Oil Chemists’ Society.
11. Bahmaei, M., Eshratabadi, P. (2016). Comparison of Physicochemical Characteristics of Margarine and Butter in Iranian Market During Storage. Journal of Pharmaceutical & Health Sciences, 4(3), 181–191.
12. Bantchev, G. B., Biresaw, G., Mohamed, A., Moser, J. (2011). Temperature dependence of the oxidative stability of corn oil and polyalphaolefin in the presence of sulfides. Thermochimica Acta, 513, 94–99. https://doi.org/10.1016/j.tca.2010.11.017
13. Baştürk, A. (2019). Effects of microwave and conventional heating on the oxidative stability of corn oil enriched with different antioxidants. Grasas y Aceites, 70(4), 1–12. https://doi.org/10.3989/gya.1044182
14. Baştürk, A., Ceylan, M. M., Çavuş, M., Boran, G., Javidipour, I. (2018). Effects of some herbal extracts on oxidative stability of corn oil under accelerated oxidation conditions in comparison with some commonly used antioxidants. LWT-Food Science and Technology, 89, 358–364. https://doi.org/https://doi.org/10.1016/j.lwt.2017.11.005
15. Benmoussa, H., Elfalleh, W., Farhat, A., Servili, M., Algabr, M., Romdhane, M. (2016). Impact of Microwave Assisted Infusion on the Quality and Volatile Composition of Olive Oil Aromatized with Rosemary Leaves. Journal of the American Oil Chemists Society, 93(7), 921–928. https://doi.org/10.1007/s11746-016-2847-0
16. Bozkurt, F., Baştürk, A. (2018). Farklı Depolama Sıcaklıklarının Kahvaltılık ve Mutfak Margarinlerinin Oksidatif Stabiliteleri Üzerine Etkileri. Yüzüncü Yıl Üniversitesi Tarım Bilimleri Dergisi, 28(1), 103–111.
17. Chinprahast, N., Tungsomboon, T., Nagao, P. (2016). Antioxidant activities of Thai pigmented rice cultivars and application in sunflower oil. International Journal of Food Science and Technology, 51(1), 46–53. https://doi.org/10.1111/ijfs.12952
18. Das, U. N. (1991). Lipids, lipid peroxidation and human health. Trends in Food Science & Technology, 2, 44–45.
19. Di Stefano, V., Melilli, M. G. (2020). Effect of storage on quality parameters and phenolic content of Italian extra-virgin olive oils. Natural Product Research, 34(1), 78–86. https://doi.org/10.1080/14786419.2019.1587434
20. El Boulifi, N., Bouaid, A., Martinez, M., Aracil, J. (2010). Process Optimization for Biodiesel Production from Corn Oil and Its Oxidative Stability. International Journal of Chemical Engineering, 2010, 1–9. https://doi.org/10.1155/2010/518070
21. Engler Ribeiro, P. C., de Britto Policarpi, P., Dal Bo, A., Barbetta, P. A., Block, J. M. (2017). Impact of pecan nut shell aqueous extract on the oxidative properties of margarines during storage. Journal of the Science of Food and Agriculture, 97(9), 3005–3012. https://doi.org/10.1002/jsfa.8141
22. Fazel, M., Sahari, M. A., Barzegar, M. (2009). Comparison of tea and sesame seed oils as two natural antioxidants in a fish oil model system by radical scavenging activity. International Journal of Food Sciences and Nutrition, 60(7), 567–576. https://doi.org/10.3109/09637480801987625
23. Ghanbari Shendi, E., Sivri Ozay, D., Ozkaya, M. T., Ustunel, N. F. (2018). Changes occurring in chemical composition and oxidative stability of virgin olive oil during storage. OCL - Oilseeds and Fats, Crops and Lipids, 25(6), 4–11. https://doi.org/10.1051/ocl/2018052
24. Günç Ergönül, P., Nergiz, C. (2014). The effect of different filter aid materials and winterization periods on the oxidative stability of sunflower and corn oils. CyTA - Journal of Food, 13(2), 174–180. https://doi.org/10.1080/19476337.2014.931889
25. Halvorsen, B. L., Blomhoff, R. (2011). Determination of lipid oxidation products in vegetable oils and marine omega-3 supplements. Food & Nutrition Research, 55(1), 5792. https://doi.org/10.3402/fnr.v55i0.5792
26. İnanç, A. L. (2022). Piyasada Satışa Sunulan Ayçiçeği Yağı, Mısır Yağı ve Riviera Zeytinyağlarının Saflık Kriterlerinin Belirlenmesi. Journal of the Institute of Science and Technology, 2(1), 241–253. https://doi.org/10.21597/jist.1016112
27. Inanc Horuz, T., Maskan, M. (2015). Effect of the phytochemicals curcumin, cinnamaldehyde, thymol and carvacrol on the oxidative stability of corn and palm oils at frying temperatures. Journal of Food Science and Technology-Mysore, 52(12), 8041–8049. https://doi.org/10.1007/s13197-015-1913-1
28. Inanc, T., Maskan, M. (2013). Testing the Antioxidant Effect of Essential Oils and BHT on Corn Oil at Frying Temperatures: a Response Surface Methodology. Journal of the American Oil Chemists Society, 90(12), 1845–1850. https://doi.org/10.1007/s11746-013-2351-8
29. Jabeur, H., Ben Hmida, R., Chtourou, I., Bouaziz, M. (2022). Blends of fresh olive oil and old olive oil: Characterization and quantification through chemical and sensory assessment. JAOCS, Journal of the American Oil Chemists’ Society, 99(1), 3–14. https://doi.org/10.1002/aocs.12550
30. Javidipour, I., Erinc, H., Basturk, A., Tekin, A. (2017). Oxidative changes in hazelnut, olive, soybean, and sunflower oils during microwave heating. International Journal of Food Properties, 20(7), 1582–1592. http://dx.doi.org/10.1080/10942912.2016.1214963
31. Kapich, A. N., Korneichik, T. V, Hatakka, A., Hammel, K. E. (2010). Oxidizability of unsaturated fatty acids and of a non-phenolic lignin structure in the manganese peroxidase-dependent lipid peroxidation system. Enzyme and Microbial Technology, 46(2), 136–140. https://doi.org/10.1016/j.enzmictec.2009.09.014
32. Karakaya, S., Simsek, S. (2011). Changes in Total Polar Compounds, Peroxide Value, Total Phenols and Antioxidant Activity of Various Oils Used in Deep Fat Frying. Journal of the American Oil Chemists Society, 88(9), 1361–1366. https://doi.org/10.1007/s11746-011-1788-x
33. Keramat, M., Golmakani, M. T. (2016). Effect of Thymus vulgaris and Bunium persicum essential oils on the oxidative stability of virgin olive oil. Grasas y Aceites, 67(4), 162. https://doi.org/ARTN e16210.3989/gya.0337161
34. Kindleysides, S., Quek, S. Y., Miller, M. R. (2012). Inhibition of fish oil oxidation and the radical scavenging activity of New Zealand seaweed extracts. Food Chemistry, 133(4), 1624–1631. https://doi.org/10.1016/j.foodchem.2012.02.068
35. Mason, R. P., Sherratt, S. C. R. (2017). Omega-3 fatty acid fish oil dietary supplements contain saturated fats and oxidized lipids that may interfere with their intended biological benefits. Biochemical and Biophysical Research Communications, 483(1), 425–429.
36. Özcan, M., Seven, S. (2003). Physıcal and chemıcal analysıs and fatty acıd composıtıon of peanut, peanut oıl and peanut butter from ÇOM and NC-7 cultıvars. Grasas y Aceites, 54(1), 12–18.
37. Reindl, B., Stan, H. J. (1982). Determination of volatile aldehydes in meat as 2, 4-dinitrophenylhydrazones using reversed-phase high-performance liquid chromatography. Journal of Agricultural and Food Chemistry, 30(5), 849–854.
38. Ritter, J. C., Budge, S. M., Jovica, F. (2013). Quality analysis of commercial fish oil preparations. Journal of the Science of Food and Agriculture, 93(8), 1935–1939. https://doi.org/10.1002/jsfa.5994
39. Rodriguez-Estrada, M. T., Caboni, M. F. (2002). Determination of cholesterol oxidation products by high-performance liquid chromatography. Cholesterol and Phytosterol Oxidation Products: Analysis, Occurrence, and Biological Effects, 66–100.
40. Shahidi, F. (1998). Indicators for evaluation of lipid oxidation and off-flavor development in food. In Food Flavors: Formation, Analysis, and Packaging Influences (Vol. 40). https://doi.org/https://doi.org/10.1016/S0167-4501(98)80032-0
41. Shahidi, F., Wanasundara, U. N. (2002). Methods for measuring oxidative rancidity in fats and oils. In Food lipids (pp. 484–507). CRC Press.
42. Shi, R., Guo, Y., Vriesekoop, F., Yuan, Q. P., Zhao, S. N., Liang, H. (2015). Improving oxidative stability of peanut oil under microwave treatment and deep fat frying by stearic acid-surfacant-tea polyphenols complex. European Journal of Lipid Science and Technology, 117(7), 1008–1015. https://doi.org/10.1002/ejlt.201400371
43. Tanrıverdi, E. (2011). Kızartma yağlarının stabilitesi üzerine bazı baharat uçucu yağlarının etkisi. Master's thesis, Selcuk University, Institute of Science and Technology, Konya, Türkiye
44. Tekin, L., Aday, M. S., Yilmaz, E. (2009). Physicochemical Changes in Hazelnut, Olive Pomace, Grapeseed and Sunflower Oils Heated at Frying Temperatures. Food Science and Technology Research, 15(5), 519–524.
45. TGK. (2012). Turkish Food Codex Communiqué on Oils Called by Plant Name, Communiqué no. 2012/29. Official Gazette, p. 28262.
46. TGK. (2017). Turkish Food Codex Communiqué on Olive Oil and Olive Pomace Oil, Communiqué No: 2017/26. Official Gazette, p. 30183.
47. TSE. (2022). TS 2812 Spreadable margarine/margarine.
48. Tohma, S., Turan, S. (2015). Rosemary plant (Rosmarinus officinalis L.), solvent extract and essential oil can be used to extend the usage life of hazelnut oil during deep frying. European Journal of Lipid Science and Technology, 117(12), 1978–1990. https://doi.org/10.1002/ejlt.201400382
49. Türkoğlu, H., Kanık, Z., Yakut, A., Güneri, A., Akın, M. (2012). Some Properties of Olive Oils Sold in Nizip and Surroundings. Journal of the Faculty of Agriculture of Harran University University, 16(3), 1–8.
50. Yüzereroğlu, Ö. (2021). The Effects of Laurel (Laurus Nobilis L.) and French Lavender (Lavandula Stoechas L.) Essential Oils on Oxidative Stabilities of Refined Sunflower and Riviera Olive Oil. Master's thesis, Aydın Adnan Menderes University, Institute of Science and Technology, Aydın, Türkiye.
51. Zhang, D., Li, X., Cao, Y., Wang, C., Xue, Y. (2020). Effect of roasting on the chemical components of peanut oil. Lwt, 125, 109249. https://doi.org/10.1016/j.lwt.2020.109249
52. Zhang, Y., Yang, L., Zu, Y. G., Chen, X. Q., Wang, F. J., Liu, F. (2010). Oxidative stability of sunflower oil supplemented with carnosic acid compared with synthetic antioxidants during accelerated storage. Food Chemistry, 118(3), 656–662. https://doi.org/10.1016/j.foodchem.2009.05.038