REAL TEXTILE WASTEWATER RECLAMATION USING A COMBINED COAGULATION/ FLOCCULATION/ MEMBRANE FILTRATION SYSTEM AND THE EVALUATION OF SEVERAL NATURAL MATERIALS AS FLOCCULANT AIDS
Abstract
A coagulation/flocculation/membrane filtration process was applied to two real textile wastewaters in Turkey. Aluminum sulfate and ferric sulfate were used as coagulants and several natural materials, namely limestone, magnesite, kaoline, pumice, and sedipür (polyelectrolyte), were used as flocculant aids. The effects of pH, coagulant dosage, and the type and dosage of flocculant aids on the color and chemical oxygen demand (COD) of wastewater were studied. The experimental results showed that treatment with aluminum sulfate (0.5 g/L) and ferric sulfate (0.18 g/L) at a pH of 6 was very effective. The color removal for aluminum sulfate and ferric sulfate reached 81% and, 86%, respectively, and the COD was reduced by 70% and 47%, respectively. The natural flocculant aids behaved differently for color removal and COD reduction. Treatment with aluminum sulfate and limestone at pH 6 removed 89% of the color and reduced the COD by 80% in the presence of magnesite. Treatment with ferric sulfate aided with natural materials at pH 6 did not significantly remove the color and reduced the COD value by 50% in the presence of magnesite. Cellulose nitrate membranes can be easily cleaned using nitric acid.
Keywords
References
- REFERENCES
- Barın, A. Y., “Removal of phenol from aqueous solutions by coagulation”, M.Sc. Thesis, Gazi University Institute of Science and Technology, Ankara, Turkey, 2006.
- Verma, A. K., Dash, R. R., Bhunia, P., “A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters”, J. Environmental Management, 93, 154-168, (2012).
- Zahrim, A.Y., Tizaoui, C., Hilal, N., “Coagulation with polymers for nanofiltration pre-treatment of highly concentrated dyes: A review”, Desalination, 266, 1-16, (2011).
- Khayet, M., Zahrim, A. Y., Hilal N., “Modelling and optimization of coagulation of highly concentrated industrial grade leather dye by response surface methodology”, Chemical Engineering Journal, 167, 77-83, (2011).
- Joo, D. J., Shin, W. S., Choi, J. H., Choi, S. J., Kim, M. C., Han, M. H., Ha, T. W., Kim, Y. H., “Decolorization of reactive dyes using inorganic coagulants and synthetic polymer”, Dyes and Pigments, 73, 59-64, (2007).
- Gaydardzhiew, S., Karthikeyan, J., Ay, P., “Colour removal from model solutions by coagulation-surface charge and floc characterization aspects”, Environmental Technology, 27, 193-199, (2006).
- Kim, S. H., Moon, S. Y., Yoon, C. H., Yim, S. K., Cho, J. W., “Role of coagulation in membrane filtration of wastewater for reuse”, Desalination, 173, 301-307, (2005).
Details
Primary Language
English
Subjects
Engineering
Journal Section
Conference Paper
Publication Date
September 30, 2016
Submission Date
February 8, 2016
Acceptance Date
-
Published in Issue
Year 2016 Volume: 29 Number: 3