Research Article
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Year 2025, Early View, 1 - 1
https://doi.org/10.35378/gujs.1322009

Abstract

References

  • [1] Meade, J. E., “The theory of economic externalities: The control of environmental pollution and similar social costs”, Vol. 2, Martinus Nijhoff Publishers, (2024).
  • [2] Punia, A.,” Role of temperature, wind, and precipitation in heavy metal contamination at copper mines: a review”, Environmental Science and Pollution Research, 28(4): 4056-4072, (2021).
  • [3] Luo, Y., Wang, Z., Zhang, Y. D., Zhang, J. Q., Zeng, Q. P., Zhang, Z. L., & Chen, L.,” Vertical migration behavior simulation and prediction of Pb and Cd in co-contaminated soil around Pb-Zn smelting slag site”, Journal of Hazardous Materials, 469: 133990, (2024).
  • [4] Kerur, S. S., Bandekar, S., Hanagadakar, M. S., Nandi, S. S., Ratnamala, G. M., & Hegde, P. G., “Removal of hexavalent Chromium-Industry treated water and Wastewater: A review”, Materials Today: Proceedings, 42: 1112-1121, (2021).
  • [5] Talukder, P., Ray, R., Sarkar, M., Das, A., & Chakraborty, S., “Adverse effects of mining pollutants on terrestrial and aquatic environment and its remediation”, Environmental Quality Management, 33(4): 595-610, (2024).
  • [6] Ertani, A., Mietto, A., Borin, M., Nardi, S., “Chromium in agricultural soils and crops: a review”, Water, Air, & Soil Pollution, 228: 1-12, (2017).
  • [7] Kenar, N., “Forecasting impacts of climate and land-use change on Vallonea oak (Quercus ithaburensis subsp. macrolepis) based on the ensemble modeling”, Plant Biosystems-An International Journal Dealing with all Aspects of Plant Biology, 159(1): 1-14, (2025).
  • [8] Xie, S.,” Water contamination due to hexavalent chromium and its health impacts: exploring green technology for Cr (VI) remediation”, Green Chemistry Letters and Reviews, 17(1): 2356614, (2024).
  • [9] Dong, F. X., Yan, L., Zhou, X. H., Huang, S. T., Liang, J. Y., Zhang, W. X., Diao, Z. H., “Simultaneous adsorption of Cr (VI) and phenol by biochar-based iron oxide composites in water: Performance, kinetics and mechanism”, Journal of Hazardous Materials, 416: 125930, (2021).
  • [10] Baglieri, A., Gennari, M., Arena, M., Abbate, C., “The adsorption and degradation of chlorpyriphos-methyl, pendimethalin and metalaxyl in solid urban waste compost”, Journal of Environmental Science and Health, Part B, 46(6): 454-460, (2011).
  • [11] Dim, P. E., Mustapha, L. S., Termtanun, M., Okafor, J. O., “Adsorption of chromium (VI) and iron (III) ions onto acid-modified kaolinite: Isotherm, kinetics and thermodynamics studies”, Arabian Journal of Chemistry, 14(4): 103064, (2021).
  • [12] Cao, J., He, G., Ning, X., Wang, C., Fan, L., Yin, Y., Cai, W., “Hydroxypropyl chitosan-based dual self-healing hydrogel for adsorption of chromium ions”, International Journal of Biological macromolecules, 174: 89-100, (2021).
  • [13] Erduran, N., Gökgöz, M., Ada, K., “Adsorption of Chromium (VI) Metal Ions from Aqueous Solution Using Hexagonal ZnO PArticles: Equilibrium, Kinetic and Thermodynamic Modelling Studies”, The Canadian Journal of Chemical Engineering. 92: 496-502, (2014).
  • [14] Kul, Z. E., Nuhoğlu, Y., Kul, S., Nuhoğlu, Ç., Torun, F. E., “Mechanism of heavy metal uptake by electron paramagnetic resonance and FTIR: Enhanced manganese (II) removal onto waste acorn of Quercus ithaburensis”, Separation Science and Technology, 51(1): 115-125, (2016).
  • [15] Egbosiuba, T. C., Abdulkareem, A. S., Kovo, A. S., Afolabi, E. A., Tijani, J. O., Bankole, M. T., & Roos, W. D., “Adsorption of Cr (VI), Ni (II), Fe (II) and Cd (II) ions by KIAgNPs decorated MWCNTs in a batch and fixed bed process”, Scientific Reports, 11(1): 75, (2021).
  • [16] Zeng, H., Zeng, H., Zhang, H., Shahab, A., Zhang, K., Lu, Y., & Ullah, H., “Efficient adsorption of Cr (VI) from aqueous environments by phosphoric acid activated eucalyptus biochar” Journal of Cleaner Production, 286: 124964, (2021).
  • [17] Kul, S., “Removal of Cu (II) from aqueous solutions using modified sewage sludge ash”, International Journal of Environmental Science and Technology, 18(12): 3795-3806, (2021).
  • [18] Malkoc E., Nuhoğlu Y., Abalı Y., “Cr (VI) adsorption by waste acorn of Quercus ithaburensis in fixed beds: Prediction of breakthrough curves”. Chemical Engineering Journal, 119: 61-68, (2006).
  • [19] Harshala, K., & Wagh, N. D., “Use of Agricultural Waste-Based Biosorbents for the Removal of Heavy Metals from Aqueous Solution: A Review”, Nature Environment & Pollution Technology, 21(3): (2022).
  • [20] Mao, Y., Gao, S., Yao, L., Wang, L., Qu, H., Wu, Y., & Zheng, L., “Single-atom nanozyme enabled fast and highly sensitive colorimetric detection of Cr (VI)”, Journal of Hazardous Materials, 408, 124898: (2021).
  • [21] Sreenivas, K., Inarkar, M., Gokhale S., Lele S., “Reutilization of ash gourd (Benincasa hispida) peel waste for chromium (VI) biosorption: equilibrium and column studies”, Journal of Environmental Chemical Engineering, 2: 455–462, (2014).
  • [22] Tural, B., Ertaş, E., Güzel, M., & Tural, S., “Effect of structural differences of pumice on synthesis of pumice-supported nFe0: removal of Cr (VI) from water”, Applied Water Science, 11: 1-11, (2021).

Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste

Year 2025, Early View, 1 - 1
https://doi.org/10.35378/gujs.1322009

Abstract

Chromium (VI) is a heavy metal which is the cause of water pollution and toxic effect on the living structures. In this study, the adsorption of Cr (VI) and the removal of other pollution parameters were investigated using natural adsorbent as waste acorn of Quercus ithaburensis (Oak tree) which was produced by valeks industries. The study consists of two experimental parts. In the first part, principal factors affecting the adsorption were investigated by batch experiment methods. Optimum conditions of stirring rate, pH, particular size of adsorbent, starting concentration, amount of adsorbent, mixing time and temperature for effective chromium removal were determined. The best adsorption conditions were found as 10 min contact time at 7 of pH with 550 rpm stirring rate in 100 ml sample volume using 1.00 g of adsorbent.

In the second part, adsorption tests were exercised with wastewater under pre-determined optimum conditions for the adsorbent. Experimental studies were taken place on the removal of COD (Chemical Oxygen Demand), SS (Suspend Solid), BOD (Biological Oxygen Demand) and chromium (VI) from composite sample of the tannery wastewater. The outputs of adsorption using oak acorn waste for COD, SS, BOD and chromium (VI) respectively about 1%, 17%, 12.5%, 12% was obtained.

References

  • [1] Meade, J. E., “The theory of economic externalities: The control of environmental pollution and similar social costs”, Vol. 2, Martinus Nijhoff Publishers, (2024).
  • [2] Punia, A.,” Role of temperature, wind, and precipitation in heavy metal contamination at copper mines: a review”, Environmental Science and Pollution Research, 28(4): 4056-4072, (2021).
  • [3] Luo, Y., Wang, Z., Zhang, Y. D., Zhang, J. Q., Zeng, Q. P., Zhang, Z. L., & Chen, L.,” Vertical migration behavior simulation and prediction of Pb and Cd in co-contaminated soil around Pb-Zn smelting slag site”, Journal of Hazardous Materials, 469: 133990, (2024).
  • [4] Kerur, S. S., Bandekar, S., Hanagadakar, M. S., Nandi, S. S., Ratnamala, G. M., & Hegde, P. G., “Removal of hexavalent Chromium-Industry treated water and Wastewater: A review”, Materials Today: Proceedings, 42: 1112-1121, (2021).
  • [5] Talukder, P., Ray, R., Sarkar, M., Das, A., & Chakraborty, S., “Adverse effects of mining pollutants on terrestrial and aquatic environment and its remediation”, Environmental Quality Management, 33(4): 595-610, (2024).
  • [6] Ertani, A., Mietto, A., Borin, M., Nardi, S., “Chromium in agricultural soils and crops: a review”, Water, Air, & Soil Pollution, 228: 1-12, (2017).
  • [7] Kenar, N., “Forecasting impacts of climate and land-use change on Vallonea oak (Quercus ithaburensis subsp. macrolepis) based on the ensemble modeling”, Plant Biosystems-An International Journal Dealing with all Aspects of Plant Biology, 159(1): 1-14, (2025).
  • [8] Xie, S.,” Water contamination due to hexavalent chromium and its health impacts: exploring green technology for Cr (VI) remediation”, Green Chemistry Letters and Reviews, 17(1): 2356614, (2024).
  • [9] Dong, F. X., Yan, L., Zhou, X. H., Huang, S. T., Liang, J. Y., Zhang, W. X., Diao, Z. H., “Simultaneous adsorption of Cr (VI) and phenol by biochar-based iron oxide composites in water: Performance, kinetics and mechanism”, Journal of Hazardous Materials, 416: 125930, (2021).
  • [10] Baglieri, A., Gennari, M., Arena, M., Abbate, C., “The adsorption and degradation of chlorpyriphos-methyl, pendimethalin and metalaxyl in solid urban waste compost”, Journal of Environmental Science and Health, Part B, 46(6): 454-460, (2011).
  • [11] Dim, P. E., Mustapha, L. S., Termtanun, M., Okafor, J. O., “Adsorption of chromium (VI) and iron (III) ions onto acid-modified kaolinite: Isotherm, kinetics and thermodynamics studies”, Arabian Journal of Chemistry, 14(4): 103064, (2021).
  • [12] Cao, J., He, G., Ning, X., Wang, C., Fan, L., Yin, Y., Cai, W., “Hydroxypropyl chitosan-based dual self-healing hydrogel for adsorption of chromium ions”, International Journal of Biological macromolecules, 174: 89-100, (2021).
  • [13] Erduran, N., Gökgöz, M., Ada, K., “Adsorption of Chromium (VI) Metal Ions from Aqueous Solution Using Hexagonal ZnO PArticles: Equilibrium, Kinetic and Thermodynamic Modelling Studies”, The Canadian Journal of Chemical Engineering. 92: 496-502, (2014).
  • [14] Kul, Z. E., Nuhoğlu, Y., Kul, S., Nuhoğlu, Ç., Torun, F. E., “Mechanism of heavy metal uptake by electron paramagnetic resonance and FTIR: Enhanced manganese (II) removal onto waste acorn of Quercus ithaburensis”, Separation Science and Technology, 51(1): 115-125, (2016).
  • [15] Egbosiuba, T. C., Abdulkareem, A. S., Kovo, A. S., Afolabi, E. A., Tijani, J. O., Bankole, M. T., & Roos, W. D., “Adsorption of Cr (VI), Ni (II), Fe (II) and Cd (II) ions by KIAgNPs decorated MWCNTs in a batch and fixed bed process”, Scientific Reports, 11(1): 75, (2021).
  • [16] Zeng, H., Zeng, H., Zhang, H., Shahab, A., Zhang, K., Lu, Y., & Ullah, H., “Efficient adsorption of Cr (VI) from aqueous environments by phosphoric acid activated eucalyptus biochar” Journal of Cleaner Production, 286: 124964, (2021).
  • [17] Kul, S., “Removal of Cu (II) from aqueous solutions using modified sewage sludge ash”, International Journal of Environmental Science and Technology, 18(12): 3795-3806, (2021).
  • [18] Malkoc E., Nuhoğlu Y., Abalı Y., “Cr (VI) adsorption by waste acorn of Quercus ithaburensis in fixed beds: Prediction of breakthrough curves”. Chemical Engineering Journal, 119: 61-68, (2006).
  • [19] Harshala, K., & Wagh, N. D., “Use of Agricultural Waste-Based Biosorbents for the Removal of Heavy Metals from Aqueous Solution: A Review”, Nature Environment & Pollution Technology, 21(3): (2022).
  • [20] Mao, Y., Gao, S., Yao, L., Wang, L., Qu, H., Wu, Y., & Zheng, L., “Single-atom nanozyme enabled fast and highly sensitive colorimetric detection of Cr (VI)”, Journal of Hazardous Materials, 408, 124898: (2021).
  • [21] Sreenivas, K., Inarkar, M., Gokhale S., Lele S., “Reutilization of ash gourd (Benincasa hispida) peel waste for chromium (VI) biosorption: equilibrium and column studies”, Journal of Environmental Chemical Engineering, 2: 455–462, (2014).
  • [22] Tural, B., Ertaş, E., Güzel, M., & Tural, S., “Effect of structural differences of pumice on synthesis of pumice-supported nFe0: removal of Cr (VI) from water”, Applied Water Science, 11: 1-11, (2021).
There are 22 citations in total.

Details

Primary Language English
Subjects Pollution and Contamination (Other)
Journal Section Research Article
Authors

Mehmet Sadrettin Zeybek 0000-0002-4753-1226

Murat Çanlı 0000-0002-5275-861X

Taliha Banu Öztekin 0009-0006-5707-212X

Yüksel Abalı 0000-0002-4165-8656

Early Pub Date October 29, 2025
Publication Date November 17, 2025
Published in Issue Year 2025 Early View

Cite

APA Zeybek, M. S., Çanlı, M., Öztekin, T. B., Abalı, Y. (2025). Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste. Gazi University Journal of Science1-1. https://doi.org/10.35378/gujs.1322009
AMA Zeybek MS, Çanlı M, Öztekin TB, Abalı Y. Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste. Gazi University Journal of Science. Published online October 1, 2025:1-1. doi:10.35378/gujs.1322009
Chicago Zeybek, Mehmet Sadrettin, Murat Çanlı, Taliha Banu Öztekin, and Yüksel Abalı. “Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste”. Gazi University Journal of Science, October (October 2025), 1-1. https://doi.org/10.35378/gujs.1322009.
EndNote Zeybek MS, Çanlı M, Öztekin TB, Abalı Y (October 1, 2025) Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste. Gazi University Journal of Science 1–1.
IEEE M. S. Zeybek, M. Çanlı, T. B. Öztekin, and Y. Abalı, “Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste”, Gazi University Journal of Science, pp. 1–1, October2025, doi: 10.35378/gujs.1322009.
ISNAD Zeybek, Mehmet Sadrettin et al. “Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste”. Gazi University Journal of Science. October2025. 1-1. https://doi.org/10.35378/gujs.1322009.
JAMA Zeybek MS, Çanlı M, Öztekin TB, Abalı Y. Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste. Gazi University Journal of Science. 2025;:1–1.
MLA Zeybek, Mehmet Sadrettin et al. “Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste”. Gazi University Journal of Science, 2025, pp. 1-1, doi:10.35378/gujs.1322009.
Vancouver Zeybek MS, Çanlı M, Öztekin TB, Abalı Y. Eco-Friendly Chromium Removal from Tannery Wastewater Using Oak Acorn Waste. Gazi University Journal of Science. 2025:1-.