Polydopamine Mediated Growth of Ag Nanostructures on ZnO Thin Films for Catalytic Degradation of Organic Dyes

Year 2020, Volume: 33 Issue: 4, 857 - 870, 01.12.2020

Mehmet Kuru Sami Pekdemır

https://doi.org/10.35378/gujs.646532

Cited By: 3

Abstract

In this study, multi-functional films were produced by the solution-phase growth of plasmonic Ag nanostructures (NSs) on ZnO fabricated by RF magnetron sputtering technique. The Ag NSs was grown on ZnO coated surface by functionalizing the thin film with mussel-inspired polydopamine. The structural analysis was performed by Grazing Incident X-ray diffraction (GIXRD) and Fouirer Transform Infrared Spectrometer (FTIR) technique in order to observe the effect of the Ag NSs deposition times. The effect of growth conditions on the structure and size of Ag NSs was investigated by Field Emission Scanning Electron Microscope (FESEM) imaging technique. The chemical compositions of as-deposited and Ag decorated ZnO films confirms using Energy-dispersive X-ray spectroscopy (EDX) analysis. The catalytic performance of the multi-functional films was investigated by the degradation of organic dyes (methyl orange (MO) and rhodamine B (RhB)).The catalytic activity of Ag on the is examined in details where it is found that maximum catalytic performance was observed within first 15 min for the ZnO thin films that were decorated with Ag NSs for 24h. The rate constant for the degradation reaction was 33.8x10-3 min-1 and 43.2x10-3 min-1 for MO and RhB, respectively. These results show the promise of integrating metal oxide films with plasmonic structures for efficient degradation of organic dyes. 

Keywords

ZnO thin film, Ag nanostructures, Polydopamine, Catalytic activity

References

• [1] Grassi, M., Kaykioglu, G., Belgiorno, V. and Lofrano, G., Removal of Emerging Contaminants from Water and Wastewater by Adsorption Process Emerging Compounds Removal from Wastewater: Natural and Solar Based Treatments, ed. by G. Lofrano, Springer, Netherlands: Dordrecht, 15-37, (2012).
• [2] Kümmerer, K., “The presence of pharmaceuticals in the environment due to human use–present knowledge and future challenges”, J. Environ. Manag., 90(8): 2354–2366, (2009).
• [3] Robinson, T., McMullan, G., Marchant, R. and Nigam, P., “Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative”, Biores. Technol., 77(3): 247–255, (2001).
• [4] Ghosh, B. K., Hazra, S., Naik, B. and Ghosh, N. N., “Preparation of Cu nanoparticle loaded SBA-15 and their excellent catalytic activity in reduction of variety of dyes”, Powder Technol., 269; 371–378, (2015).
• [5] Singh, K. and Arora, S., “Removal of synthetic textile dyes from wastewaters: A critical review on present treatment technologies”, Crit. Rev. Environ. Sci. Technol., 41(9): 807–878, (2011).
• [6] Dong, W., Zhu Y., Huang H., Jiang L., Zhu H., Li C., Chen B., Shi Z. and Wang G., “A performance study of enhanced visible-light-driven photocatalysis and magnetical protein separation of multifunctional yolk-shell nanostructures”, J. Mater. Chem. A, 1(34): 10030-10036, (2013).
• [7] Chen, F., Ho P., Ran R., Chen W., Si Z., Wu X., Weng D., Huang Z. and Lee C., “Synergistic effect of CeO2 modified TiO2 photocatalyst on the enhancement of visible light photocatalytic performance”, J. Alloys Compd., 714:560-566, (2017).
• [89 Kumar, D. R., Ranjith, K.S., Nivedita, L.R., Asokan, K., Kumar, R. T. R., “Swift heavy ion induced effects on structural, optical and photo-catalytic properties of Ag irradiated vertically aligned ZnO nanorod arrays”, Nuclear Inst. Methods Phys. Res. B 450;95–99, (2019).
• [9] Chakrabarti, S. and Dutta, B. K., “Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst”, J. Hazard. Mater., 112(3);269–278, (2004).
• [10] Veziroglu, S., Kuru, M., Ghori, M. Z., Dokan, F. K., Hinz, A. M., Strunskus, T., Faupel, F. and Aktas, O. C., “Ultra-fast degradation of methylene blue by Au/ZnO-CeO2 nano-hybrid catalyst”, Mater. Lett., 209:486–491 (2017).
• [11] Whang, T. J., Hsieh, M. T. and Chen, H. H., “Visible-light photocatalytic degradation of methylene blue with laser-induced Ag/ZnO nanoparticles”, Appl. Surf. Sci., 258: 2796–2801, (2012).
• [12] Zhang, P., Chen, Y., Yang, X., Gui, J., Li, Y., Peng, H., Liu, D. and Qiu, J., “Pt/ZnO@C nanocable with dual-enhanced photocatalytic performance and superior photostability”, Langmuir 33:4452–4460, (2017).
• [13] Muñoz-Fernandez, L., Sierra-Fernandez, A., Milošević, O. and Rabanal, M. E., “Solvothermal synthesis of Ag/ZnO and Pt/ZnO nanocomposites and comparison of their photocatalytic behaviors on dyes degradation”, Adv. Powder Technol., 27(3):983–993, (2016).
• [14] Wang, L., Hu, Q., Li, Z., Guo, J., and Li, Y., “Microwave-assisted synthesis and photocatalytic performance of Ag-doped hierarchical ZnO architectures”, Mater. Lett., 79:277–280, (2012).
• [15] Wang, Y., Arandiyan, H., Scott, J., Bagheri, A., Dai, H. and Amal, R., “Recent advances in porous metal oxides for heterogeneous catalysis: a review”, J. Mater. Chem. A, 5:8825-8846, (2017).
• [16] Gupta, V.K. and Nayak, A., “Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles”, Chem. Eng. J. 180:81–90 (2012).
• [17] Mallick, K., Witcomb, M.J. and Scurrell, M.S., “Redox catalytic property of gold nanoclusters: evidence of an electron-relay effect”, Appl. Phys. A Mater. Sci. Process, 80:797–801, (2005).
• [18] Gupta, N., Singh, H.P., and Sharma, R.K., “Metal nanoparticles with high catalytic activity in degradation of methyl orange: An electron relay effect”, J Mol Catal A-Chem., 335(1–2): 248-252, (2011).
• [19] Khan, M. M., Lee, J., and Cho, M.H., “Au@TiO2 nanocomposites for the catalytic degradation of methyl orange and methylene blue: An electron relay effect”. Ind Eng Chem Res., 20(4):1584-1590, (2014).
• [20] Şakir, M., and Onses, M. S., “Solid substrates decorated with Ag nanostructures for the catalytic degradation of methyl orange”, Results in Physics, 12:1133-1141, (2019).
• [21] Abed, C., Bouzidi, C., Elhouichet, H., Gelloz, B., and Ferid, M., “Mg doping induced high structural quality of sol–gel ZnO nanocrystals: Application in photocatalysis”, Appl. Surf. Sci. 349:855–863, (2015).
• [22] Kuru, M. and Narsat, H., “The effect of heat treatment temperature and Mg doping on structural and photocatalytic activity of ZnO thin films fabricated by RF magnetron co-sputtering technique”, J Mater Sci: Mater Electron., 30(20): 18484–18495 (2019).
• [23] Lee, H., Dellatore, S. M., Miller, W. M. and Messersmith, P. B., “Mussel-Inspired Surface Chemistry for Multifunctional Coatings”, Science, 318(5849):426-430, (2007).
• [24] Rafaie, H.A., Nor, R.M., Azmina, M.S., Ramli, N.I.T. and Mohamed, R., “Decoration of ZnO microstructures with Ag nanoparticles enhanced the catalytic photodegradation of methylene blue dye”, J. Environ. Chem. Eng., 5(4):3963–3972, (2017).
• [25] Cullity, B.D. and Graham, C.D., “Introduction to Magnetic Materials”, Wiley, (2009).
• [26] Jayram, N. D., Sonia, S., Poongodi, S., Kumar, P. S., Masuda, Y., Mangalaraj, D., Ponpandian, N. and Viswanathan C., “Superhydrophobic Ag decorated ZnO nanostructured thin film as effective surface enhanced Raman scattering substrates”, Appl. Surf. Sci., 355:969–977, (2015).
• [27] Fageria, P., Gangopadhyay, S. and Pande, S., “Synthesis of ZnO/Au and ZnO/Ag nanoparticles and their photocatalytic application using UV and visible light”, RSC Adv., 4: 24962-24972 (2014).
• [28] Li, Z., “Sorption Kinetics of Hexadecyltrimethylammonium on Natural Clinoptilolite”, Langmuir, 15:6438-6445, (1999).
• [29] Kumar, K. V., Porkodi, K. and Rocha, F., “Langmuir–Hinshelwood kinetics – A theoretical study”, Catal. Commun., 9:82–84, (2008).