Monitoring of the Chemical Composition of Rainwater in a Semi-Urban Area in the Northern West of Turkey

Barış Güzel

doi:10.35378/gujs.727114

Research Article

Monitoring of the Chemical Composition of Rainwater in a Semi-Urban Area in the Northern West of Turkey

Year 2021, Volume: 34 Issue: 1, 1 - 17, 01.03.2021

Barış Güzel

https://doi.org/10.35378/gujs.727114

Cited By: 6

Abstract

In this study, the effect of possible pollutant sources on rainwater was investigated in Gebze, where is one of the most important industrial activity zones in the coastal district of Turkey. For this purpose, the collection of twenty-three samples were carried out from October 2019 to March 2020 to describe the chemical composition of the rainwater and possible sources of atmospheric emissions (major ions and trace elements) and finally to establish data of those species in the monitoring region. The pH range in the samples varied between 5.81 and 7.27 (average pH: 6.51). pH of the samples was predominantly neutral. the EC values of the 23 rainwater samples changed within a range of 22.1 μS cm-1-126.2 μS cm-1 (average EC: 63.0 μS cm-1). Dealing between EC values and Ca2+ concentrations of samples (good positive correlation (R2 = 0.84)) in graph) can be thought that dust particles, which include a significant amount of calcite and similar type of minerals, act as carriers for soluble solid materials in atmosphere. The order of percentage contribution of each ion species to total ion composition in rainwater was: Ca2+>Na+>SO42->Cl->Mg2+>NO3->NH4+>K+>PO43->NO2->F-. The most abundant ions (Ca2+, Na+ and SO42-) contributed approximately 45%, 13% and 11%, respectively. High Ca2+ profile points out construction activities, agricultural activity and various industrial activities producing building materials around the sampling site. The trend of trace elements (μg L-1) based on concentrations during the whole study period was: Al(34.52)>Fe(26.03)>Ba(20.67)>Mn(18.06)>B(16.39)>Sr(16.27)>Cu(10.42), respectively. Consequently, concentrations of ions and trace elements in rainwater samples collected in this study were compared with previous studies from similar locations in Turkey and in other countries.

Keywords

Chemical Composition, Major Ions, Trace Metals, Rainwater, Semi-Urban Area

Supporting Institution

TUBITAK MAM Environment and Cleaner Production Institute

Project Number

Thanks

The author would like to thank the TUBITAK MAM Environment and Cleaner Production Institute's laboratory heads and staff for their assistances in the experimental studies.

References

[1] Tuncay, E., Aşkın, B., Yücel, T., “Spatial fluctuation of sulphur dioxide (SO2) and particulate matter (PM) levels measured in Bursa”, Gazi Uni. J. Sci., 19(3): 143-148, (2006).
[2] Tiwari, S., Kulshrestha, U.C., Padmanabhamurty, B., “Monsoon rain chemistry and source apportionment using receptor modelling in and around National Capital Region (NCR) of Delhi, India”, Atmos. Environ., 41(27): 5595-5604, (2007).
[3] Martins, E.H., Nogarotto, D.C., Mortatti, J., Pozza, S.A., “Chemical composition of rainwater in an urban area of the southeast of Brazil”, Atmos. Pollut. Res., 10: 520-530, (2019).
[4] Prathibha, P., Kothai, P., Saradhi, I.V., Pandit, G.G., Puranik, V.D., “Chemical characterization of precipitation at a coastal site in Trombay, Mumbai, India”, Environ. Monit. Assess., 168: 45-53, (2010).
[5] Shen, W., Ren, H., Jenerette, G.D., Hui, D., Ren, H., “Atmospheric deposition and canopy exchange of anions and cations in two plantation forests under acid rain influence”, Atmos. Environ., 64: 242-250, (2013).
[6] De Oliveira Jr., R.C., Keller, M.M., Ramos, J.F.F., Beldini, T.P., Crill, P.M., Camargo, P.B., Van Haren, J., “Chemical analysis of rainfall and throughfall in the Tapajós national forest, Belterra, Pará, Brazil”, Ambiente e Agua - An Interdisciplinary J. Appl. Sci., 10(2): 263-285, (2015).
[7] Gonzáles, C.M., Aristizábal, B.H., “Acid rain and particulate matter dynamics in a mid-sized Andean city: the effect of rain intensity on ion scavenging”, Atmos. Environ., 60: 164-171, (2012).
[8] Cangemi, M., Madonia, P., Favara, R., “Chemical characterisation of rainwater at Stromboli Island (Italy): the effect of post-depositional processes”, J. Volcanol. Geoth. Res., 335: 82-91, (2017).
[9] Naik, M.S., Momin, G.A., Rao, P.S.P., Safai, P.D., Ali, K., “Chemical composition of rainwater around an industrial region in Mumbai”, Curr. Sci., 82(9): 1131-1137, (2002).
[10] Fornaro, A., Gutz, I.G.R., “Wet deposition and related atmospheric chemistry in the São Paulo metropolis, Brazil: Part 2-Contribution of formic and acetic acids”, Atmos. Environ., 37(1): 117-128, (2003).
[11] Migliavacca, D., Teixeira, E.C., Pires, M., Fachel, J., “Study of chemical elements in atmospheric precipitation in South Brazil”, Atmos. Environ., 38 (11): 1641-1656, (2004).
[12] Coelho, C.H., Allen, A.G., Fornaro, A., Orlando, E.A., Grigoletto, T.L.B., Campos, M.L.A.M., “Wet deposition of major ions in a rural area impacted by biomass burning emissions”, Atmos. Environ., 45(30): 5260-5265, (2011).
[13] Rodrigues, R.A.R., Mello, W.Z., Souza, P.A., “Atmospheric deposition of ammonium, nitrate ans sulfate on the montane dense ombrophilous forest in Serra dos Órgãos, RJ”, Quím. Nova, 30(8): 1842-1848, (2007).
[14] Moreda-Piñeiro, J., Alonso-Rodríguez, E., Moscoso-Pérez, C., Blanco-Heras, G., Turnes-Carou, I., López-Mahía, P., Muniategui-Lorenzo, S., Prada-Rodríguez, D., “Influence of marine, terrestrial and anthropogenic sources on ionic and metallic composition of rainwater at a suburban site (northwest coast of Spain)”. Atmos. Environ., 88: 30-38, (2014).
[15] Lee, B.K., Hong, S.H., Lee, D.S., “Chemical composition of precipitation and wet deposition of major ions on the Korean peninsula”, Atmos. Environ., 34: 563- 575, (2000).
[16] Baron, J., Denning, A.S., “The influence of mountain meteorology on precipitation chemistry at low and high elevations of the Colorado Front Range, USA”, Atmos. Environ. Part A-General Topics, 27: 2337-2349, (1993).
[17] Cerqueira, M.R.F., Pinto, M.F., Derossi, I.N., Esteves, W.T., Santos, M.D.R., Matos, M.A.C., Lowinsohn, D., Matos, R.C., “Chemical characteristics of rainwater at a southeastern site of Brazil”, Atmos. Pollut. Res., 5: 253-261, (2014).
[18] Zunckel, M., Saizar, C., Zarauz, J., “Rainwater composition in Northeast Uruguay”, Atmos. Res., 37: 1601-1611, (2003).
[19] Bahattin, C., İbrahim, K., “The Relation between Meteorological Factors and Pollutants Concentrations in Karabük City”, Gazi Uni. J. Sci., 20(4): 87-95 (2007).
[20] Herrera, J., Rodríguez, S., Baéz, A., “Chemical composition of bulk precipitation in the metropolitan area of Costa Rica, Central America”, Atmos. Res., 94: 151-160, (2009).
[21] Hoinaski, L., Franco, D., Haas, R., Martins, R.F., Lisboa, H.M., “Investigation of rainwater contamination sources in the southern part of Brazil”, Environ. Technol., 35(7):868-881, (2014).
[22] Wang, L., Chen, Z., Shang, H., Wang, J., Zhang, P.Y., “Impact of simulated acid rain on soil microbial community function in Masson pine seedlings”, Electr. J. Biotechnol., 17(5): 199-203, (2014).
[23] Alcolea, A., Fernández-López, C., Vázquez, M., Caparrós, A., Ibarra, I., García, C., Zarroca, M., Rodríguez, R., “An assessment of the influence of sulfidic mine wastes on rainwater quality in a semiarid climate (SE Spain)”, Atmos. Res., 107: 85-94, (2015).
[24] Al-Khashman, O.A., “Chemical characteristics of rainwater collected at a western site of Jordan”, Atmos. Res., 91: 53-61, (2009).
[25] Huang, X.F., Li, X., He, L.Y., Feng, N., Hu, M., Niu, Y.W., Zeng, L.W., “5-Year study of rainwater chemistry in a coastal mega-city in South China”, Atmos. Res., 97: 185-193, (2010).
[26] Laouali, D., Galy-Lacaux, C., Diop, B., Delon, C., Orange, D., Lacaux, J.P., Akpo, A., Lavenu, F., Gardrat, E., Castera, P., “Long term monitoring of the chemical composition of precipitation and wet deposition fluxes over three Sahelian savannas”, Atmos. Environ., 50: 314-327, (2012).
[27] Abdus-Salam, N., Adekola, F.A., Otuyo-Ibrahim, M., “Chemical composition of wet precipitation in ambient environment of Ilorin, north central Nigeria”, J. Saudi Chem. Soc., 18: 528-534, (2014).
[28] Sánchez, A.S., Cohim, E., Kalid, R.A., “A review on physicochemical and microbiological contamination of roof-harvested rainwater in urban areas”, Sustain. Water Qual. Ecol., 6: 119-137, (2015).
[29] Roy, A., Chatterjee A., Tiwari, S., Sarkar, C., Das, S.K., Ghosh, S.K., Raha, S., “Precipitation chemistry over urban, rural and high altitude Himalayan stations in eastern India”, Atmos. Res., 18: 44-53, (2016).
[30] Mimura, A.M.S., Almeida, J.M., Vaz, F.A.S., de Oliveira, M.A.L., Ferreira, C.C.M., Silva, J.C.J., “Chemical composition monitoring of tropical rainwater during a typical dry year”, Atmos. Res., 169: 391-399, (2016).
[31] Mehr, M.R., Keshavarzi, B., Sorooshian, A., “Influence of natural and urban emissions on rainwater chemistry at a southwestern Iran coastal site”, Sci. Total Environ., 668: 1213-1221, (2019).
[32] Vlastos, D., Antonopoulou, M., Lavranou, A., Efthimiou, I., Dailianis, S., Hela, D., Lambropoulou, D., Paschalidou, A.K., Kassomenos, P., “Assessment of the toxic potential of rainwater precipitation: First evidence from a case study in three Greek cities”, Sci. Total Environ., 648: 1323-1332, (2019).
[33] Garaga, R., Chakraborty, S., Zhang, H., Gokhale, S., Xue, Q., Kota, S.H., “Influence of anthropogenic emissions on wet deposition of pollutants and rainwater acidity in Guwahati, a UNESCO heritage city in Northeast India”, Atmos. Res., 232: 104683, (2020).
[34] GDM, “General Statistics data of our provinces”, General Directorate of Meteorology, (2020). https://www.mgm.gov.tr/tahmin/il-ve-ilceler.aspx?il=Kocaeli&ilce=Gebze. (In Turkish).
[35] APHA, AWWA and WEF, “Standard Methods for the Examination of Water and Wastewater”, American Public Health Association, Washington, DC, (2012).
[36] Charlson, R., Rodhe, H., “Factors controlling the acidity of natural rainwater”, Nature, 295: 683-685, (1982).
[37] Zhao, M., Li, L., Liu, Z., Chen, B., Huang, J., Cai, J., Deng, S., “Chemical composition and sources of rainwater collected at a semi-rural site in Ya'an, southwestern China”, Atmos. and Clim. Sci., 3: 486-496, (2013).
[38] Demirak, A., Balci, A., Karaoğlu, H., Tosmur, B., “Chemical characteristics of rain water at an urban site of south western Turkey”, Environ. Monit. Assess., 123: 271-283, (2006).
[39] Örnektekin, S., Cakmakli, S., “Chemical composition and acidity of rain at the gulf of Iskenderun, North-East Mediterranean”, Water, Air, & Soil Pollut.: Focus, 3: 151-166, (2003).
[40] Gülsoy, G., Tayanç, M., Ertürk, F., “Chemical analyses of the major ions in the precipitation of İstanbul, Turkey”, Environ. Pollut., 105: 273-280, (1999).
[41] Demir, F.T., Kılıçer, Y.Ç., Yenisoy-Karakaş, S., “Yarı şehirsel istasyonda toplanan yağmur suyunun iyon kompozisyonunun belirlenmesi ve asitlik”, VII. Ulusal Hava Kirliliği ve Kontrolü Sempozyumu, Antalya, Turkey, 873-882, (2017).
[42] Kaya, G., Tuncel, G., “Trace element and major ion composition of wet and dry deposition in Ankara, Turkey”, Atmos. Environ., 31: 3985-3998, (1997).
[43] Özsoy, T., Türker, P., Örnektekin, S, “Precipitation chemistry as an indicator of urban air quality in Mersin, North-Eastern Mediterranean region”, Water Air & Soil Pollut., 189: 69-83, (2008).
[44] Al-Momani, I.F., Ataman, O.Y., Anwari, M.A., Tuncel, S., Köse, C., Tuncel, G., “Chemical composition of precipitation near an industrial area at İzmir, Turkey”, Atmos. Environ., 29: 1131-1143, (1995).
[45] Akkoyunlu, B.O., Tayanç, M., Karaca, M., “Analysis of bulk and sub-event wet deposition in Gebze”, 2nd International Symposium on Air Quality Management at Urban, Regional and Global Scales, Istanbul, Turkey, 509-516, (2001).
[46] Tang, J., Xue, H., Yu, X., Cheng, H., Xu, X., Zhang, X., Ji, J., “The preliminary study on chemical characteristics of precipitation at Mt. Waliguan”, Acta Sci. Circum., 20(4): 420-425, (2000). (in Chinese).
[47] Zhang, M., Wang, S., Wu, F., Yuan, X., Zhang, Y., “Chemical compositions of wet precipitation and anthropogenic influences at a developing urban site in southeastern China”. Atmos. Res., 84(4): 311-322, (2007).
[48] Lu, X., Li, L. Y., Li, N., Yang, G., Luo, D., Chen, J., “Chemical characteristics of spring rainwater of Xi’an city", NW China”, Atmos. Environ., 45: 5058-5063, (2011).
[49] Souza, P.A., Mello, W.Z., Maldonado, J., “Composição química da chuva e aporte atmosférico na Ilha Grande, RJ”, Quím. Nova, 29(3): 471-476, (2006).
[50] Vieira-Filho, M.S., Pedrotti, J.J., Fornaro, A., “Contribution of long and mid-range transport on the sodium and potassium concentrations in rainwater samples, São Paulo megacity, Brazil”, Atmos. Environ., 79: 299-307, (2013).
[51] Tuncer, B., Bayar, B., Yeşilyurt, C., Tuncel, G. “Ionic composition of precipitation at the Central Anatolia (Turkey)”, Atmos. Environ., 35: 5989-6002, (2001).
[52] Calvo, A.I., Olmo, F.J., Lyamani, H., Alados-Arboledas, L., Castro, A., Fernández-Raga, M., Fraile, R., “Chemical composition of wet precipitation at the background EMEP station in Víznar (Granada, Spain) (2002–2006)”, Atmos. Res., 96, 408-420, (2010).
[53] Shakya, K.M., Peltier, R.E., Shrestha, H., Byanju, R.M., “Measurements of TSP, PM10, PM2.5, BC, and PM chemical composition from an urban residential location in Nepal”, Atmos. Pollut. Res., 8: 1123-1131, (2017).
[54] Tsai, Y.I., Hsieh, L.Y., Kuo, S.C., Chen, C.H., Wu, P.W., “Seasonal and rainfall-type variations in inorganic ions and dicarboxylic acids and acidity of wet deposition samples collected from subtropical East Asia”. Atmos. Environ., 45(21): 3535-3547, (2011).
[55] Dordevic, D., Mihajlidi-Zelic, A., Relic, D., “Differentiation of the contribution of local resuspension from that of regional and remote sources on trace elements content in the atmospheric aerosol in the Mediterranean area”, Atmos. Environ., 39(34): 6271-6281, (2005).
[56] Reimann, C., Caritat, P., “Chemical Elements in the Environment, Factsheets for the Geochemist and Environmental Scientist”, 398, (1998).
[57] Lin, X., He, L., Zhang, R., Guo, X., Li, H., “Rainwater in Guangzhou, China: Oxidizing properties and physicochemical characteristics”, Atmos. Pollut. Res., 10: 303-312, (2019).
[58] Song, F., Gao, Y., “Chemical characteristics of precipitation at metropolitan Newark in the US East Coast”, Atmos. Environ., 43: 4903-4913, (2009).
[59] Senevirathna, S., Ramzan, S., Morgan, J., “A sustainable and fully automated process to treat stored rainwater to meet drinking water quality guidelines”, Process Saf. Environ. Prot., 130: 190-196, (2019).
[60] Samara, C., Tsitouridou, R., Balafoutis, C.H., “Chemical composition of rain in Thessaloniki, Greece, in relation to meteorological conditions”, Atmos. Environ., 26(3): 359-367, (1992).
[61] Topcu, S., Incecik, S., Atimtay, A., “Chemical composition of rainwater at EMEP station in Ankara, Turkey”, Atmos. Res., 65:77-92, (2002).
[62] Al-Momani, I.F., Aygun, S., Tuncel, G., “Wet deposition of major ions and trace elements in the Eastern Mediterranean basin”, J. Geophys. Res., 103: 8287-8299, (1998).
[63] Al-Momani, I.F., “Trace elements in atmospheric precipitation at Northern Jordan measured by ICP-MS: acidity and possible sources”, Atmos. Environ., 37: 4507-4515, (2003).
[64] Kulshrestha, U.C., Kulshrestha, M.J., Sekar R., Sastry, G.S.R., Vairamani, M., “Chemical characteristics of rainwater at an urban site of south-central India”, Atmos. Res., 37: 3019-3026, (2003).
[65] Cao, Y., Wang, S., Zhang, G., Luo, J., Lu, S., “Chemical characteristics of wet precipitation at an urban site of Guangzhou, South China”, Atmos. Res., 94: 462-469, (2009).
[66] Taylor, S.R., “Abundance of chemical elements in the continental crust: a new table”, Geochim. Cosmochim. Acta, 28(8): 1273-1285, (1964).
[67] Poissant, L., Schmit, J.-P., Béron, P., “Trace inorganic elements in rainfall in the Montreal Island”, Atmos. Environ., 28(2): 339–346, (1994).
[68] Singh, K.P., Singh, V.K., Malik, A., Sharma, N., Murthy, R.C., Kumar, R., “Hydrochemistry of wet atmospheric precipitation over an urban area in Northern Indo-Gangetic Plains”, Environ. Monit. Assess., 131(1), 237-254, (2007).