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A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models

Year 2021, Volume: 34 Issue: 2, 370 - 379, 01.06.2021
https://doi.org/10.35378/gujs.752042

Abstract

In this study, the NIR and UV-Vis spectroscopy methods, which are frequently used in pharmaceutical industry, were applied to the environments where Paracetamol, Propyphenazone and Caffeine active substances are present, and the spectroscopic data obtained were evaluated comparatively with ICA-ANN and PLS-1, which are powerful chemometric methods. When using solid agents in NIR method, liquid solutions equivalent to them were used in UV-Vis method. Following the application of both methods, spectral data were evaluated as chemometrics and in both spectroscopic methods ICA-ANN method yielded more accurate results than PLS-1. High recovery rates and relatively low standard deviations were found in the applied methods and recommended for use in the pharmaceutical industry.

Supporting Institution

Süleyman Demirel Üniversitesi, BAP

Project Number

4626-YL1-16.

Thanks

The authors would like to thanks Süleyman Demirel University Scientific Research Project 4626-YL1-16.

References

  • [1] The Indian Pharmacopoeia, Controller of Publications, New Delhi; 953, (2010).
  • [2] Dominguez, V. A., Barrales, P. O., Diaz, A. M., “Simultaneous determination of paracetamol, caffeine and propyphenazone in pharmaceuticals by means of single flow-through UV multiparameter”, Micro Chimica Acta, 141: 157-163, (2003).
  • [3] Dinç, E., Kökdil, G., Onur, F., “Derivative ratio spectra-zero crossing spectrophotometry and LC method applied and quantitative determination of paracetamol, propyphenazone and caffeine in ternary mixtures”, Journal of Pharmaceutical and Biomedical Analysis, 26: 769-778, (2001).
  • [4] Avramova, J., “Simultaneous determination of propyphenazone, paracetamol and caffeine in blood by high-performance liquid chromatography”, Acta Chromatographica, 8: 1221-1227, (2008).
  • [5] Gopinath, R., Rajan, S., Meyyanathan, S. N., Krishnadevi, N., Suresh, B., “A RP-HPLC method for simultaneous determination of paracetamol and aceclofenac in tablets”, Indian Journal of Pharmaceutical Sciences, 69: 137-140, (2007).
  • [6] Artem, U. K., Aleksey, G. V., “Simultaneous determination of paracetamol, caffeine and guaifenesin and preservatives in syrups by micellar LC”, Chromatographia, 67: 347- 355, (2008).
  • [7] Blanco, M., Coello, J., Iturriaga, H., Maspoch, S., Pag`es, J., “Calibration of non-linear near infrared reflectance spectroscopy: a comparison of several methods”, Analytica Chimica Acta, 384: 207-214, (1999).
  • [8] Li, Q., Yao, X., Chen, X., Liu, M., Zhang, R., Zhang, X., Hu, Z., “Application of artificial neural networks for the simultaneous determination of a mixture of fluorescent dyes by synchronous fluorescence”, Analyst, 125: 2049-2053, (2000).
  • [9] Safavi, A., Abdollahi, H., Hormozi Nezhad, M. R., “Artificial neural networks for simultaneous spectrophotometric differential kinetic determination of Co (II) and V(IV)”, Talanta, 59: 515-523, (2003).
  • [10] Ruiz Medina, A., Fernandezde Cordova, M. L., Molina-Diaz, A., “Simultaneous determination of paracetamol and acetylsalicylic acid by means of a FI ultraviolet pls multi opto sensing device”, Journal of Pharmaceutical and Biomedical Analysis, 408: 983-992, (2000).
  • [11] Ni, Y., Liu, C., Kokot, S., “Simultaneous kinetic spectrophotometric determination of acetaminophen and phenobarbitat by artificial neural network and partial least squares”, Analytica Chimica Acta, 419: 185-196, (2000).
  • [12] Agatonovic-kustrin, S., Beresford, R., “Basic concept of artificial neural network (ANN) modeling and its application in pharmaceutical research”, Journal of Pharmaceutical and Biomedical Analysis, 22: 717-727, (2000).
  • [13] Petritis, D., Dangas, L. J., Ferguson, P. L., Anderson, G. A., Paˇsa- Toli´c, L., Lipton, M. S., Auberry, K.J., Strittmatter, E. F., Shen, Y., Zhao, R., Smith, R. D., “Use of artificial neural networks for the accurate prediction of peptid liquid chromatography elution times in protome analysis”, Analytical Chemistry, 75: 1039-48, (2003).
  • [14] Valinger, D., Jurina, T., Sain, A., Matesic, N., Panic, M., Benkovic, M., Kljusuric, J.G., Tusek, A.J., “Development of ANN model based on combined UV-vis-NIR spectra for rapid quantification of physical and chemical properties of industrial hemp extracts”, Phytochemical Analysis, 1-13, (2020).
  • [15] Debska, B., Guzowska, S. B., “Application of artificial neural network in food classification”, Analytica Chimica Acta, 705: 283-291, (2011). [16] Dankowska, A., Kowalewski, W., “Tea types classification with data fusion of UV-Vis, synchronous fluorescence and NIR spectroscopies and chemometric analysis”, Spectro Chimica Acta A Molecular and Biomolecular Spectroscopy, 103: 79-83, (2019). [17] Smilde, A., Bro, R., Geladi, G., “Multi-way Analysis: Applications in the Chemical Sciences”. Chichester, UK: Wiley Inter Science; (2005).
  • [18] Hyvarinen, A., Karhunen, J., Oja, E., “Independent Component Analysis”, New York, NY: A John Wiley & Sons, Inc. Publication; (2002).
  • [19] Thomas, E. V., Haaland, D. M., “Comparison of multivariate calibration method for quantitative spectral analysis”, Analytical Chemistry, 62: 1091-1099, (1990).
  • [20] Aktaş, A. H., Kitiş, F., “Spectrophotometric simultaneous determination of caffeine and paracetamol in commercial pharmaceutical by principal component regression, partial least squares and artificial neural network chemometric methods”, Croatica Chimica Acta, 87: 69-74, (2014).
Year 2021, Volume: 34 Issue: 2, 370 - 379, 01.06.2021
https://doi.org/10.35378/gujs.752042

Abstract


Project Number

4626-YL1-16.

References

  • [1] The Indian Pharmacopoeia, Controller of Publications, New Delhi; 953, (2010).
  • [2] Dominguez, V. A., Barrales, P. O., Diaz, A. M., “Simultaneous determination of paracetamol, caffeine and propyphenazone in pharmaceuticals by means of single flow-through UV multiparameter”, Micro Chimica Acta, 141: 157-163, (2003).
  • [3] Dinç, E., Kökdil, G., Onur, F., “Derivative ratio spectra-zero crossing spectrophotometry and LC method applied and quantitative determination of paracetamol, propyphenazone and caffeine in ternary mixtures”, Journal of Pharmaceutical and Biomedical Analysis, 26: 769-778, (2001).
  • [4] Avramova, J., “Simultaneous determination of propyphenazone, paracetamol and caffeine in blood by high-performance liquid chromatography”, Acta Chromatographica, 8: 1221-1227, (2008).
  • [5] Gopinath, R., Rajan, S., Meyyanathan, S. N., Krishnadevi, N., Suresh, B., “A RP-HPLC method for simultaneous determination of paracetamol and aceclofenac in tablets”, Indian Journal of Pharmaceutical Sciences, 69: 137-140, (2007).
  • [6] Artem, U. K., Aleksey, G. V., “Simultaneous determination of paracetamol, caffeine and guaifenesin and preservatives in syrups by micellar LC”, Chromatographia, 67: 347- 355, (2008).
  • [7] Blanco, M., Coello, J., Iturriaga, H., Maspoch, S., Pag`es, J., “Calibration of non-linear near infrared reflectance spectroscopy: a comparison of several methods”, Analytica Chimica Acta, 384: 207-214, (1999).
  • [8] Li, Q., Yao, X., Chen, X., Liu, M., Zhang, R., Zhang, X., Hu, Z., “Application of artificial neural networks for the simultaneous determination of a mixture of fluorescent dyes by synchronous fluorescence”, Analyst, 125: 2049-2053, (2000).
  • [9] Safavi, A., Abdollahi, H., Hormozi Nezhad, M. R., “Artificial neural networks for simultaneous spectrophotometric differential kinetic determination of Co (II) and V(IV)”, Talanta, 59: 515-523, (2003).
  • [10] Ruiz Medina, A., Fernandezde Cordova, M. L., Molina-Diaz, A., “Simultaneous determination of paracetamol and acetylsalicylic acid by means of a FI ultraviolet pls multi opto sensing device”, Journal of Pharmaceutical and Biomedical Analysis, 408: 983-992, (2000).
  • [11] Ni, Y., Liu, C., Kokot, S., “Simultaneous kinetic spectrophotometric determination of acetaminophen and phenobarbitat by artificial neural network and partial least squares”, Analytica Chimica Acta, 419: 185-196, (2000).
  • [12] Agatonovic-kustrin, S., Beresford, R., “Basic concept of artificial neural network (ANN) modeling and its application in pharmaceutical research”, Journal of Pharmaceutical and Biomedical Analysis, 22: 717-727, (2000).
  • [13] Petritis, D., Dangas, L. J., Ferguson, P. L., Anderson, G. A., Paˇsa- Toli´c, L., Lipton, M. S., Auberry, K.J., Strittmatter, E. F., Shen, Y., Zhao, R., Smith, R. D., “Use of artificial neural networks for the accurate prediction of peptid liquid chromatography elution times in protome analysis”, Analytical Chemistry, 75: 1039-48, (2003).
  • [14] Valinger, D., Jurina, T., Sain, A., Matesic, N., Panic, M., Benkovic, M., Kljusuric, J.G., Tusek, A.J., “Development of ANN model based on combined UV-vis-NIR spectra for rapid quantification of physical and chemical properties of industrial hemp extracts”, Phytochemical Analysis, 1-13, (2020).
  • [15] Debska, B., Guzowska, S. B., “Application of artificial neural network in food classification”, Analytica Chimica Acta, 705: 283-291, (2011). [16] Dankowska, A., Kowalewski, W., “Tea types classification with data fusion of UV-Vis, synchronous fluorescence and NIR spectroscopies and chemometric analysis”, Spectro Chimica Acta A Molecular and Biomolecular Spectroscopy, 103: 79-83, (2019). [17] Smilde, A., Bro, R., Geladi, G., “Multi-way Analysis: Applications in the Chemical Sciences”. Chichester, UK: Wiley Inter Science; (2005).
  • [18] Hyvarinen, A., Karhunen, J., Oja, E., “Independent Component Analysis”, New York, NY: A John Wiley & Sons, Inc. Publication; (2002).
  • [19] Thomas, E. V., Haaland, D. M., “Comparison of multivariate calibration method for quantitative spectral analysis”, Analytical Chemistry, 62: 1091-1099, (1990).
  • [20] Aktaş, A. H., Kitiş, F., “Spectrophotometric simultaneous determination of caffeine and paracetamol in commercial pharmaceutical by principal component regression, partial least squares and artificial neural network chemometric methods”, Croatica Chimica Acta, 87: 69-74, (2014).
There are 18 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Chemistry
Authors

Ahmet Hakan Aktaş 0000-0003-2327-4031

Halil Orhun Şahin This is me 0000-0002-4651-4096

Project Number 4626-YL1-16.
Publication Date June 1, 2021
Published in Issue Year 2021 Volume: 34 Issue: 2

Cite

APA Aktaş, A. H., & Şahin, H. O. (2021). A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models. Gazi University Journal of Science, 34(2), 370-379. https://doi.org/10.35378/gujs.752042
AMA Aktaş AH, Şahin HO. A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models. Gazi University Journal of Science. June 2021;34(2):370-379. doi:10.35378/gujs.752042
Chicago Aktaş, Ahmet Hakan, and Halil Orhun Şahin. “A Speedy Method for Simultaneous Determination in Tablet Active Content by NIR and UV-Vis Spectrophotometry: Comparison of PLS-1 and ICA-ANN Models”. Gazi University Journal of Science 34, no. 2 (June 2021): 370-79. https://doi.org/10.35378/gujs.752042.
EndNote Aktaş AH, Şahin HO (June 1, 2021) A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models. Gazi University Journal of Science 34 2 370–379.
IEEE A. H. Aktaş and H. O. Şahin, “A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models”, Gazi University Journal of Science, vol. 34, no. 2, pp. 370–379, 2021, doi: 10.35378/gujs.752042.
ISNAD Aktaş, Ahmet Hakan - Şahin, Halil Orhun. “A Speedy Method for Simultaneous Determination in Tablet Active Content by NIR and UV-Vis Spectrophotometry: Comparison of PLS-1 and ICA-ANN Models”. Gazi University Journal of Science 34/2 (June 2021), 370-379. https://doi.org/10.35378/gujs.752042.
JAMA Aktaş AH, Şahin HO. A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models. Gazi University Journal of Science. 2021;34:370–379.
MLA Aktaş, Ahmet Hakan and Halil Orhun Şahin. “A Speedy Method for Simultaneous Determination in Tablet Active Content by NIR and UV-Vis Spectrophotometry: Comparison of PLS-1 and ICA-ANN Models”. Gazi University Journal of Science, vol. 34, no. 2, 2021, pp. 370-9, doi:10.35378/gujs.752042.
Vancouver Aktaş AH, Şahin HO. A speedy method for simultaneous determination in tablet active content by NIR and UV-Vis spectrophotometry: Comparison of PLS-1 and ICA-ANN models. Gazi University Journal of Science. 2021;34(2):370-9.