Hakan ÇİFTÇİ1, H. Nur TESTERECİ1, Zeki ÖKTEM1

Year 2011, Volume: 24 Issue: 1, 11 - 16, 14.01.2011

Hakan Çiftçi Hasan Testereci Zeki Öktem

Abstract

Preconcentration and electroanalysis of copper at glassy carbon electrode modified with poly(2-aminothiazole)

Abstract

Conducting poly(2-aminothiazole), PAT, was synthesized in acetonitrile with tetrabutylammonium tetrafluoroborate, TBAFB, as supporting electrolyte via constant potential electrolysis, CPE. Glassy carbon, GC, electrode was modified by immersing the electrode in a DMSO solution of PAT. Preconcentration of copper on polymer matrix was carried out at -0.7 V. The effects of preconcentration time and pH and Cu(II) concentration of the preconcentration solution on the stripping peak current of copper were studied.

Keywords

Poly(2-aminothiazole), conducting polymer, modified electrode, copper determination, stripping voltammetry

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