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Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents

Year 2012, Volume: 25 Issue: 2, 371 - 375, 17.04.2012

Abstract

The majority of questioned documents to be examined consist of handwritten, typed or printed information on paper, and therefore, a sizeable part of the document examiner’s work should be the examination of the paper itself. There are two types of paper examination, destructive and non-destructive. The purpose of the non-destructive examination should be to find out as much as possible about the paper characteristics, which will enable the examiner to make a decision about its authenticity, or relationship with other documents, without affecting the document for any other type of examinations to follow. All Raman and infrared analysis is non-destructive. Raman and infrared spectroscopy are two complementary spectroscopic techniques that can produce fast and efficient analysis of paper of questioned documents. In this study the use of FTIR and Raman spectroscopy to differentiate paper samples was investigated.

 

Keywords: Forensic analysis, questioned documents, Raman spectroscopy and infrared spectroscopy.

 

References

  • [1] Calvini P, Gorassini A., ”FTIR - deconvolution spectra of paper documents”, Restaurator, 23 : 48- 66 (2002).
  • [2] Calvini P. ,Vassallo S., ” Computer-assisted infrared analysis of hetrogenous work of art.”, EPreservation Science, 4 : 13-17 (2007).
  • [3] Biermann CJ., ”Handbook of Pulping and Papermaking”, Academic Press., New York, 2 nd Edition, 40-42 (1996).
  • [4] Conners TE.; Banerjee S., ”Surface Analysis of Paper”, CRC Press, New York, 25-32 (1995).
  • [5] Jixing P.,”Ten Kinds of Modified Paper of Ancient China: A Summary”, Institute of Paper Historians Information, 17 : 151-155(1983).
  • [6] Baker M , von Endt D, Hopwood W , Erhardt D. “FTIR-microspectrometry: A Powerful Conservation Analysis Tool, American Institute for Conservation of Historic and Artistic Works”, The Sixteenth Annual Meeting, New Orleans, LA,June 1-5, 1-13, (1988).
  • [7] Tsang, J.-S., and R. H. Cunningham, "Some Improvements in the Study of Cross-Sections," The American Institute for Conservation of Historic and Artistic Works, the Seventeenth Annual Meeting, Cincinnati OH, May 31-June 4, 20- 21(1989).
  • [8] Pandey KK, ”A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy”, J. Appl. Polym. Sci., 71 : 1969- 1975 (1999).
  • [9] Tănase I.Gh., “Techniques and methods in spectrometric analysis”, Ed. Ars Docendi Bucharest, 125-127 (2001).
  • [10] Causin V, Marega C, Marigo A , Casamassima R,Peluso G, Ripani L., ”Forensic differentiation of paper by X-ray diffraction and infrared spectroscop”, Forensic Science International 197 : 70–74 (2010).
  • [11] Doncea SM , Ion RM , Fierascui RC, Bacalum E, Bunaciu AA., Aboul-Enein H Y., ”Spectral methods for historical paper analysis: composition and age approximation”, Instrumentation Science & Technology; 38: 96-106 (2010).
  • [12] Schmitt M , Popp J. Raman ”Spectroscopy at the Beginning of the Twenty-First Century”, J. Raman Spectrosc.; 37: 20–28 (2006).
  • [13] Ferraro JR ,Nakamoto K , Ferraro J. ”Introductory Raman Spectroscopy”, 2nd Edition; Academic Press, New York, (2003).
  • [14] Long DA, ”Raman Spectroscopy”; McGraw Hill, New York, , Chapter 7(1977).
  • [15] Campion, A.; Kambhampti, P., ”Surface-Enhanced Raman Scattering”, Chem. Soc. Rev.; 27 : 241–250 (1998).
  • [16] Moskovits, M., ”Surface-Enhanced Raman Spectroscopy: A Brief Retrospective”, J. Raman Spectrosc. 36: 485–496 (2005).
  • [17] Lewis IR , Edwards HG. ”Handbook of Raman Spectroscopy”, Marcel Dekker Inc, New York,11– 40 (2002).
  • [18] Vikman, K, Sipi K. ”Applicability of FTIR and Raman spectroscopic methods to the study of paper-ink interactions in digital prints”, Journal of Imaging Science and Technology, 47: 139-141 (2003).
  • [19] Agarwal UP , Reiner RS; Ralph SA. ”Dependable Cellulose I Crystallinity Determination using NearIR FT-Raman”, CELL Division, Abstract 95, 233rd ACS National Meeting; Chicago,IL, March 25–29, (2007).

Analysis of Questioned Documents

Year 2012, Volume: 25 Issue: 2, 371 - 375, 17.04.2012

Abstract

References

  • [1] Calvini P, Gorassini A., ”FTIR - deconvolution spectra of paper documents”, Restaurator, 23 : 48- 66 (2002).
  • [2] Calvini P. ,Vassallo S., ” Computer-assisted infrared analysis of hetrogenous work of art.”, EPreservation Science, 4 : 13-17 (2007).
  • [3] Biermann CJ., ”Handbook of Pulping and Papermaking”, Academic Press., New York, 2 nd Edition, 40-42 (1996).
  • [4] Conners TE.; Banerjee S., ”Surface Analysis of Paper”, CRC Press, New York, 25-32 (1995).
  • [5] Jixing P.,”Ten Kinds of Modified Paper of Ancient China: A Summary”, Institute of Paper Historians Information, 17 : 151-155(1983).
  • [6] Baker M , von Endt D, Hopwood W , Erhardt D. “FTIR-microspectrometry: A Powerful Conservation Analysis Tool, American Institute for Conservation of Historic and Artistic Works”, The Sixteenth Annual Meeting, New Orleans, LA,June 1-5, 1-13, (1988).
  • [7] Tsang, J.-S., and R. H. Cunningham, "Some Improvements in the Study of Cross-Sections," The American Institute for Conservation of Historic and Artistic Works, the Seventeenth Annual Meeting, Cincinnati OH, May 31-June 4, 20- 21(1989).
  • [8] Pandey KK, ”A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy”, J. Appl. Polym. Sci., 71 : 1969- 1975 (1999).
  • [9] Tănase I.Gh., “Techniques and methods in spectrometric analysis”, Ed. Ars Docendi Bucharest, 125-127 (2001).
  • [10] Causin V, Marega C, Marigo A , Casamassima R,Peluso G, Ripani L., ”Forensic differentiation of paper by X-ray diffraction and infrared spectroscop”, Forensic Science International 197 : 70–74 (2010).
  • [11] Doncea SM , Ion RM , Fierascui RC, Bacalum E, Bunaciu AA., Aboul-Enein H Y., ”Spectral methods for historical paper analysis: composition and age approximation”, Instrumentation Science & Technology; 38: 96-106 (2010).
  • [12] Schmitt M , Popp J. Raman ”Spectroscopy at the Beginning of the Twenty-First Century”, J. Raman Spectrosc.; 37: 20–28 (2006).
  • [13] Ferraro JR ,Nakamoto K , Ferraro J. ”Introductory Raman Spectroscopy”, 2nd Edition; Academic Press, New York, (2003).
  • [14] Long DA, ”Raman Spectroscopy”; McGraw Hill, New York, , Chapter 7(1977).
  • [15] Campion, A.; Kambhampti, P., ”Surface-Enhanced Raman Scattering”, Chem. Soc. Rev.; 27 : 241–250 (1998).
  • [16] Moskovits, M., ”Surface-Enhanced Raman Spectroscopy: A Brief Retrospective”, J. Raman Spectrosc. 36: 485–496 (2005).
  • [17] Lewis IR , Edwards HG. ”Handbook of Raman Spectroscopy”, Marcel Dekker Inc, New York,11– 40 (2002).
  • [18] Vikman, K, Sipi K. ”Applicability of FTIR and Raman spectroscopic methods to the study of paper-ink interactions in digital prints”, Journal of Imaging Science and Technology, 47: 139-141 (2003).
  • [19] Agarwal UP , Reiner RS; Ralph SA. ”Dependable Cellulose I Crystallinity Determination using NearIR FT-Raman”, CELL Division, Abstract 95, 233rd ACS National Meeting; Chicago,IL, March 25–29, (2007).
There are 19 citations in total.

Details

Primary Language English
Journal Section Chemistry
Authors

Y Aboul-eneın

Andrei Bunacıu This is me

Florin Udrıştıoıu This is me

İ Tanase This is me

Publication Date April 17, 2012
Published in Issue Year 2012 Volume: 25 Issue: 2

Cite

APA Aboul-eneın, Y., Bunacıu, A., Udrıştıoıu, F., Tanase, İ. (2012). Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents. Gazi University Journal of Science, 25(2), 371-375.
AMA Aboul-eneın Y, Bunacıu A, Udrıştıoıu F, Tanase İ. Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents. Gazi University Journal of Science. April 2012;25(2):371-375.
Chicago Aboul-eneın, Y, Andrei Bunacıu, Florin Udrıştıoıu, and İ Tanase. “Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents”. Gazi University Journal of Science 25, no. 2 (April 2012): 371-75.
EndNote Aboul-eneın Y, Bunacıu A, Udrıştıoıu F, Tanase İ (April 1, 2012) Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents. Gazi University Journal of Science 25 2 371–375.
IEEE Y. Aboul-eneın, A. Bunacıu, F. Udrıştıoıu, and İ. Tanase, “Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents”, Gazi University Journal of Science, vol. 25, no. 2, pp. 371–375, 2012.
ISNAD Aboul-eneın, Y et al. “Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents”. Gazi University Journal of Science 25/2 (April 2012), 371-375.
JAMA Aboul-eneın Y, Bunacıu A, Udrıştıoıu F, Tanase İ. Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents. Gazi University Journal of Science. 2012;25:371–375.
MLA Aboul-eneın, Y et al. “Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents”. Gazi University Journal of Science, vol. 25, no. 2, 2012, pp. 371-5.
Vancouver Aboul-eneın Y, Bunacıu A, Udrıştıoıu F, Tanase İ. Application of Micro-Raman and FT - IR Spectroscopy in Forensic Analysis of Questioned Documents. Gazi University Journal of Science. 2012;25(2):371-5.