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CO Methanation Over SAPO-34 Supported Ni Catalysts

Year 2023, Volume: 36 Issue: 4, 1480 - 1494, 01.12.2023
https://doi.org/10.35378/gujs.1125710

Abstract

This study investigated carbon monoxide methanation with 15 %NiO doped SAPO-34 zeolite-supported catalysts. The SAPO-34 support was produced by hydrothermal synthesis, and nickel oxide was added to the support by impregnation and surfactant-assisted impregnation method, dissolved in different solvents (water, ethanol, acetone, and 1-propanol). Various characterization techniques, N2 physisorption, XRD, SEM, TEM, and FTIR, were used to determine the physical properties of catalysts. XRD analysis showed that synthesizing the catalysts with surfactant reduced the crystallite size. The average crystal sizes of the catalysts synthesized using the impregnation and surfactant-assisted impregnation methods are between 11.3-7.1 nm and 8.9-7.1 nm, respectively. The N2 physisorption analysis showed that the catalysts with the surfactant assisted impregnation method had higher surface areas among the catalysts produced by the two different preparation methods. It was observed that the surface area of the catalyst increased as the boiling point of the solvent increased. Scanning electron microscopy (SEM) analysis exhibited that the particle size of the catalysts with 1-propanol prepared by impregnation and surfactant-assisted impregnation methods are 118 nm and 86 nm, respectively. According to the results, surfactants cause to produce smaller particles. The CO methanation studies showed that the highest CO conversion values were reached with Ni/SAPO-34 catalyst using 1- propanol prepared by impregnation and other method, which gave 19.2% and 21.1% CO conversion to methane at 375C, respectively. The low methane formation rates showed that most of the CO component was adsorbed on the surface, and some were converted to methane.

Supporting Institution

Gazi Üniversitesi

Project Number

BAP 06/2019-01.

Thanks

As the project team, we would like to thank Gazi University Scientific Research Unit for their financial support with the project numbered BAP 18/2016-03.

References

  • [1] Guler, A., “Preparation, characterization and application of bentonite-supported hpa catalysts to esterification reactions”, Ph.D. Thesis, Dicle University, Institute of Science and Technology, 21-22, (2002).
  • [2] Kuznecova, I., Gusca, J., “Property based ranking of CO and CO2 methanation catalysts, Energy Procedia”, 128: 255–260, (2017).
  • [3] İsmail, U. Y., “Synthesis and application areas of zeolites”, Ph.D. Thesis, Yıldız Technical University, Faculty of Chemistry and Metallurgy, Department of Chemical Engineering, 24-25, (2011).
  • [4] Bursalı, T., “Catalytic pyrolysis of plastic wastes over SAPO-34 catalyst”, Ph.D. Thesis, A Thesis Submitted To The Graduate School Of Natural And Applied Scıences Of Middle East Technical, 12-13, (2014).
  • [5] Tan, J., Liu, Z., Bao, X., Xianchun L., Hav. X., “Crystallization and Si incorporation mechanisms of SAPO-34”, Microporous and Mesoporous Materials, 53: 97–108, (2002).
  • [6] Li, J., Pan X., Bao, X., “Direct conversion of syngas into hydrocarbons over a core–shell Cr-Zn@SiO2@SAPO-34 catalyst”, Chinese Journal Of Catalysis, 36: 1131–1135, (2015).
  • [7] Westermann, A., Azambre, B., Bacariza, M.C., Graça, I., Ribeiro, M.F., Lopes, J.M., Henriques, C., “Insight into, CO2 methanation mechanism over NiUSY zeolites: An operando IR study”, Applied Catalysis B: Environmental, 283: 120–125, (2015).
  • [8] Bacariza M.C, Graca I., Westermann A., Ribeiro M.F., Lopes J.M., Henriques C. “CO2 hydrogenation over Ni-based zeolites: effect of catalysts preparation and pre-reduction conditions on methanation performance”, Topics in Catalysis, 59: 314-325, (2015).
  • [9] Italianoa, C., Llorcab, J., Pinoa, L., Ferraroa., Vitaa, M. V. A., “CO and CO2 methanation over Ni catalysts supported on CeO2, Al2O3 and Y2O3 oxides”, Applied Catalysis B: Environmental 264: 118494, (2020).
  • [10] Abdel-Mageed, A.M., Eckle, S., Anfang, H.G., Behm, R.J., “Selective CO methanation in CO2-rich H2 atmospheres over a Ru/zeolite catalyst: The influence of catalyst calcination”, Journal of Catalysis 298: 148-160, (2013).
  • [11] Upasen, S., Sarunchot, G., Srira-ngam, N., Poo-arporn, Y., Wattanachai, P., Praserthdam, P., Ngaotrakanwiwat, P., Panpranot, J., Soisuwan, S., “What if zeolite LTA4A and zeolite LTA5A used as Nickel catalyst supports for recycling carbon dioxide to green fuel methane”, Journal of CO2 Utilization 55: 101803, (2022).
  • [12] Cao, H.X., Zhang, J., Guo, C.L., Chen, J.G., Ren, X.K., “Modifying surface properties of KIT-6 zeolite with Ni and V for enhancing catalytic CO methanation”, Applied Surface Science, 426: 40-49, (2017).
  • [13] Demir, H., “Dimethyl ether (dme) synthesis using mesoporous SAPO-34 like catalytıc materials”, Msc. Thesis, A Thesıs Submitted To The Graduate School Of Natural And Applıed Sciences Of Middle East Technical Unıversity., By In Partial fulfıllment of the requırements. For The degree of master of science In Chemıcal Engineering, (2011).
  • [14] Zhihong, L., Bozhao, C., Xuli, Z., Yong, J., Yi, C., “Total methanation of syngas to synthetic natural gas over Ni catalyst in a micro-channel reactor”, Fuel, 95: 599–605, (2012).
  • [15] Neuberg, S., Pennemann, H., Shanmugam, V., Thiermann, R. Zapf, R., “CO2 methanation in microstructured reactors–catalyst development and process design”, Chemical Engineering Technology, 10: 2076–2084, (2019).
  • [16] Ngassaa, S., Oraáa, A., Álvareza, M.I., Domíngueza, F., Romero-Sarriaa, G. Arzamendib, L.M. Gandíab, M.A. Centenoa, J.A. Odriozolaa, “Preferential oxidation of CO (CO-prox) over CUOX/CEO2 coated microchannel reactor”, Catalysis Today, 180: 105–110, (2012).
  • [17] Akhoundzadeh, H., Majid T., Hassan S. P., “Synthesis of highly selective and stable mesoporous Ni–Ce/SAPO-34 nanocatalyst for methanol-to-olefin reaction: role of polar aprotic N, N-dimethylformamide solvent”, Particuology, 40: 113–122, (2018).
  • [18] Ji, H.Y., Hong D., Xiaoxin C., “Revealing inherent factors of SAPO-34 zeolites etching towards the fabrication of hierarchical structure”, Microporous and Mesoporous Materials, 319: 111067, (2021).
  • [19] Wei, L., Grenmann, H., Haije, W., Kumar, N., Aho, A., Eränen, K., Wei, L., de Jong, W., “Sub-Nanometer ceria-promoted Ni 13X zeolite catalyst for CO2 methanation”, Applied Catalysis A, 612: 118012, (2021).
  • [20] Xi, S., Wang, X., Caren Tome, K., Zang, T., Han, Z., Gao, M., Zhou, S., Yu, H., “Effect of Ni and SAPO-34 Co-additive on enhancing hydrogen storage performance of MgH2”, International Journal of Hydrogen Energy, 46: 23748-23756, (2021).
  • [21] Yu, L., Zhang, R., Cao, C., Liu L., Fang, J., Jin, H., “Hydrogen production from supercritical water gasification of lignin catalyzed by ni supported on various zeolites”, Fuel, 319: 123744, (2022).
  • [22] Hossein-Nejad, Z., “An adaptive image registration method based on SIFT features and RANSAC transform”, Computers and Electrical Engineering, 62: 524–537, (2017).
  • [23] Jwa, E., Lee S., Lee, H., Mok, Y., “Plasma-assisted catalytic methanation of CO and CO2 over Ni–zeolite catalysts”, Fuel Processing Technology, 108: 89-93, (2013).
  • [24] Gao, W., Meng, X., Jim, D., Xu W., Dai, W., Zaho, R., Xin, Z., “Polyol-Pretreated SBA-16 supported Ni-Fe bimetallic catalyst applied ın CO methanation at low temperature”, Molecular Catalysis, 512: 111769, (2021).
  • [25] Jiangwei L., Panpan L., Jiangbing Li., Zhiqun T., Feng Y., “Highly-dispersed Nİ-NiO nanoparticles anchored on an SiO2 support for an enhanced comethanation performance”, Catalytsts, 9: 506, (2019).
Year 2023, Volume: 36 Issue: 4, 1480 - 1494, 01.12.2023
https://doi.org/10.35378/gujs.1125710

Abstract

Project Number

BAP 06/2019-01.

References

  • [1] Guler, A., “Preparation, characterization and application of bentonite-supported hpa catalysts to esterification reactions”, Ph.D. Thesis, Dicle University, Institute of Science and Technology, 21-22, (2002).
  • [2] Kuznecova, I., Gusca, J., “Property based ranking of CO and CO2 methanation catalysts, Energy Procedia”, 128: 255–260, (2017).
  • [3] İsmail, U. Y., “Synthesis and application areas of zeolites”, Ph.D. Thesis, Yıldız Technical University, Faculty of Chemistry and Metallurgy, Department of Chemical Engineering, 24-25, (2011).
  • [4] Bursalı, T., “Catalytic pyrolysis of plastic wastes over SAPO-34 catalyst”, Ph.D. Thesis, A Thesis Submitted To The Graduate School Of Natural And Applied Scıences Of Middle East Technical, 12-13, (2014).
  • [5] Tan, J., Liu, Z., Bao, X., Xianchun L., Hav. X., “Crystallization and Si incorporation mechanisms of SAPO-34”, Microporous and Mesoporous Materials, 53: 97–108, (2002).
  • [6] Li, J., Pan X., Bao, X., “Direct conversion of syngas into hydrocarbons over a core–shell Cr-Zn@SiO2@SAPO-34 catalyst”, Chinese Journal Of Catalysis, 36: 1131–1135, (2015).
  • [7] Westermann, A., Azambre, B., Bacariza, M.C., Graça, I., Ribeiro, M.F., Lopes, J.M., Henriques, C., “Insight into, CO2 methanation mechanism over NiUSY zeolites: An operando IR study”, Applied Catalysis B: Environmental, 283: 120–125, (2015).
  • [8] Bacariza M.C, Graca I., Westermann A., Ribeiro M.F., Lopes J.M., Henriques C. “CO2 hydrogenation over Ni-based zeolites: effect of catalysts preparation and pre-reduction conditions on methanation performance”, Topics in Catalysis, 59: 314-325, (2015).
  • [9] Italianoa, C., Llorcab, J., Pinoa, L., Ferraroa., Vitaa, M. V. A., “CO and CO2 methanation over Ni catalysts supported on CeO2, Al2O3 and Y2O3 oxides”, Applied Catalysis B: Environmental 264: 118494, (2020).
  • [10] Abdel-Mageed, A.M., Eckle, S., Anfang, H.G., Behm, R.J., “Selective CO methanation in CO2-rich H2 atmospheres over a Ru/zeolite catalyst: The influence of catalyst calcination”, Journal of Catalysis 298: 148-160, (2013).
  • [11] Upasen, S., Sarunchot, G., Srira-ngam, N., Poo-arporn, Y., Wattanachai, P., Praserthdam, P., Ngaotrakanwiwat, P., Panpranot, J., Soisuwan, S., “What if zeolite LTA4A and zeolite LTA5A used as Nickel catalyst supports for recycling carbon dioxide to green fuel methane”, Journal of CO2 Utilization 55: 101803, (2022).
  • [12] Cao, H.X., Zhang, J., Guo, C.L., Chen, J.G., Ren, X.K., “Modifying surface properties of KIT-6 zeolite with Ni and V for enhancing catalytic CO methanation”, Applied Surface Science, 426: 40-49, (2017).
  • [13] Demir, H., “Dimethyl ether (dme) synthesis using mesoporous SAPO-34 like catalytıc materials”, Msc. Thesis, A Thesıs Submitted To The Graduate School Of Natural And Applıed Sciences Of Middle East Technical Unıversity., By In Partial fulfıllment of the requırements. For The degree of master of science In Chemıcal Engineering, (2011).
  • [14] Zhihong, L., Bozhao, C., Xuli, Z., Yong, J., Yi, C., “Total methanation of syngas to synthetic natural gas over Ni catalyst in a micro-channel reactor”, Fuel, 95: 599–605, (2012).
  • [15] Neuberg, S., Pennemann, H., Shanmugam, V., Thiermann, R. Zapf, R., “CO2 methanation in microstructured reactors–catalyst development and process design”, Chemical Engineering Technology, 10: 2076–2084, (2019).
  • [16] Ngassaa, S., Oraáa, A., Álvareza, M.I., Domíngueza, F., Romero-Sarriaa, G. Arzamendib, L.M. Gandíab, M.A. Centenoa, J.A. Odriozolaa, “Preferential oxidation of CO (CO-prox) over CUOX/CEO2 coated microchannel reactor”, Catalysis Today, 180: 105–110, (2012).
  • [17] Akhoundzadeh, H., Majid T., Hassan S. P., “Synthesis of highly selective and stable mesoporous Ni–Ce/SAPO-34 nanocatalyst for methanol-to-olefin reaction: role of polar aprotic N, N-dimethylformamide solvent”, Particuology, 40: 113–122, (2018).
  • [18] Ji, H.Y., Hong D., Xiaoxin C., “Revealing inherent factors of SAPO-34 zeolites etching towards the fabrication of hierarchical structure”, Microporous and Mesoporous Materials, 319: 111067, (2021).
  • [19] Wei, L., Grenmann, H., Haije, W., Kumar, N., Aho, A., Eränen, K., Wei, L., de Jong, W., “Sub-Nanometer ceria-promoted Ni 13X zeolite catalyst for CO2 methanation”, Applied Catalysis A, 612: 118012, (2021).
  • [20] Xi, S., Wang, X., Caren Tome, K., Zang, T., Han, Z., Gao, M., Zhou, S., Yu, H., “Effect of Ni and SAPO-34 Co-additive on enhancing hydrogen storage performance of MgH2”, International Journal of Hydrogen Energy, 46: 23748-23756, (2021).
  • [21] Yu, L., Zhang, R., Cao, C., Liu L., Fang, J., Jin, H., “Hydrogen production from supercritical water gasification of lignin catalyzed by ni supported on various zeolites”, Fuel, 319: 123744, (2022).
  • [22] Hossein-Nejad, Z., “An adaptive image registration method based on SIFT features and RANSAC transform”, Computers and Electrical Engineering, 62: 524–537, (2017).
  • [23] Jwa, E., Lee S., Lee, H., Mok, Y., “Plasma-assisted catalytic methanation of CO and CO2 over Ni–zeolite catalysts”, Fuel Processing Technology, 108: 89-93, (2013).
  • [24] Gao, W., Meng, X., Jim, D., Xu W., Dai, W., Zaho, R., Xin, Z., “Polyol-Pretreated SBA-16 supported Ni-Fe bimetallic catalyst applied ın CO methanation at low temperature”, Molecular Catalysis, 512: 111769, (2021).
  • [25] Jiangwei L., Panpan L., Jiangbing Li., Zhiqun T., Feng Y., “Highly-dispersed Nİ-NiO nanoparticles anchored on an SiO2 support for an enhanced comethanation performance”, Catalytsts, 9: 506, (2019).
There are 25 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Chemical Engineering
Authors

Filiz Balıkçı Derekaya 0000-0001-5985-6872

Yusuf Serkan Kılınç 0000-0002-7470-6888

Project Number BAP 06/2019-01.
Early Pub Date May 15, 2023
Publication Date December 1, 2023
Published in Issue Year 2023 Volume: 36 Issue: 4

Cite

APA Balıkçı Derekaya, F., & Kılınç, Y. S. (2023). CO Methanation Over SAPO-34 Supported Ni Catalysts. Gazi University Journal of Science, 36(4), 1480-1494. https://doi.org/10.35378/gujs.1125710
AMA Balıkçı Derekaya F, Kılınç YS. CO Methanation Over SAPO-34 Supported Ni Catalysts. Gazi University Journal of Science. December 2023;36(4):1480-1494. doi:10.35378/gujs.1125710
Chicago Balıkçı Derekaya, Filiz, and Yusuf Serkan Kılınç. “CO Methanation Over SAPO-34 Supported Ni Catalysts”. Gazi University Journal of Science 36, no. 4 (December 2023): 1480-94. https://doi.org/10.35378/gujs.1125710.
EndNote Balıkçı Derekaya F, Kılınç YS (December 1, 2023) CO Methanation Over SAPO-34 Supported Ni Catalysts. Gazi University Journal of Science 36 4 1480–1494.
IEEE F. Balıkçı Derekaya and Y. S. Kılınç, “CO Methanation Over SAPO-34 Supported Ni Catalysts”, Gazi University Journal of Science, vol. 36, no. 4, pp. 1480–1494, 2023, doi: 10.35378/gujs.1125710.
ISNAD Balıkçı Derekaya, Filiz - Kılınç, Yusuf Serkan. “CO Methanation Over SAPO-34 Supported Ni Catalysts”. Gazi University Journal of Science 36/4 (December 2023), 1480-1494. https://doi.org/10.35378/gujs.1125710.
JAMA Balıkçı Derekaya F, Kılınç YS. CO Methanation Over SAPO-34 Supported Ni Catalysts. Gazi University Journal of Science. 2023;36:1480–1494.
MLA Balıkçı Derekaya, Filiz and Yusuf Serkan Kılınç. “CO Methanation Over SAPO-34 Supported Ni Catalysts”. Gazi University Journal of Science, vol. 36, no. 4, 2023, pp. 1480-94, doi:10.35378/gujs.1125710.
Vancouver Balıkçı Derekaya F, Kılınç YS. CO Methanation Over SAPO-34 Supported Ni Catalysts. Gazi University Journal of Science. 2023;36(4):1480-94.