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Polianilin/Aljinat Kompozit Malzemesinin Asit Violet 90 Boyar Maddesinin Gideriminde Kullanılması: Kinetik Ve İzoterm Değerlendirmesi

Year 2018, Volume: 6 Issue: 4, 729 - 740, 30.12.2018
https://doi.org/10.29109/gujsc.383614

Abstract

Bu çalışmada Polianilin/Aljinat
(PANİ/SA) kompozit malzemesi Asit Violet 90 (AV 90) boyar maddesinin adsorpsiyonunda
kullanılmıştır. PANİ/SA’nın karakterizasyonu
Fourier Dönüşüm Kızılötesi Spektroskopisi (FTIR ile analiz edilmiştir. pH
(2-6), PANİ/SA küre miktarı (10-50 adet) ve AV 90 derişiminin (25-200 mg/L)
boyar madde giderimine etkisi incelenmiştir. En yüksek boyar madde giderimi pH
2’de elde edilmiştir. AV 90 adsorpsiyon izotermlerini belirlemek için Langmuir,
Freundlich ve Temkim izoterm modelleri kullanılmıştır. 25-200 mg/L boyar madde
derişimi aralığında Langmuir modelinden elde edilen maksimum adsorpsiyon kapasitesi
(qm) değeri 138,9 mg/g olarak bulunmuştur. Adsorpsiyon kinetiğinin
belirlenmesi için yalancı birinci derece ve ikinci derece kinetik modelleri
kullanılmış ve en Yalancı ikinci derece kinetik modelin deney verileri ile daha
uyumlu olduğu görülmüştür.
Deney
sonuçları PANİ/SA adsorbentinin AV 90 boyar maddesinin adsorpsiyonu için
oldukça iyi bir alternatif olduğunu göstermiştir. 

References

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Year 2018, Volume: 6 Issue: 4, 729 - 740, 30.12.2018
https://doi.org/10.29109/gujsc.383614

Abstract

References

  • 1. Yang, L., Ma, X., Guo, N., Sodium alginate/Na+-rectorite composite microspheres: preparation, characterization, and dye adsorption, Carbohydrate Polymers, 90, 853-858, 2012. 2. Mohammadi, A., Daemi, H., Barikani, M., Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles, International Journal of Biological Macromolecules, 69, 447-455, 2014. 3. Laabd, M., Ahsaine, H. A., Jaouhari, A., Bakiz, B., Bazzaoui, M., Ezahri, M., Albourine, A., Benlhachemi A., Congo red removal by PANi/Bi2WO6 nanocomposites: Kinetic, equilibrium and thermodynamic studies, Journal of Environmental Chemical Engineering 4, 3096–3105, 2016. 4. Patil, M.R., Shrivastava, V.S., Adsorption removal of carcinogenic acid violet19 dye from aqueous solution by polyaniline-Fe2O3 magnetic nano-composite, J.Mater.Environ.Sci. 6 (1), 11-21, 2015. 5. Hassani, A., Soltani, R. D. C., Karaca, S., Khataee, A., “Preparation of montmorillonite–alginate nanobiocomposite for adsorption of a textile dye in aqueous phase: Isotherm, kinetic and experimental design approaches”, Journal of Industrial and Engineering Chemistry 21, 1197–1207, 2015. 6. Sarıoğlu, Ö.F., Keskin, N.O., Çelebioğlu, A., Tekinay, T., Uyar, T., Bacteria encapsulated electrospun nanofibrous webs for remediation of methylene blue dye in water, Colloids and Surfaces B: Biointerfaces, 152, 245-251, 2017. 7. Kocaer, F.O., Alkan, U., “Boyar madde içeren tekstil atık sularının arıtım alternatifleri” , Uludağ Üniv. Müh.Mim.Fak.Dergisi, Cilt 7, No 1, 47-55, 2002. 8. Jain, R., Gupta, V.K., Sikarwa, S., “Adsorption and desorption studies on hazardous dye Naphthol Yellow S”, Journal of Hazardous Materials, Cilt 182, 749-756, 2010. 9. Gengec, E., Color removal from anaerobic/aerobic treatment effluent of bakery yeast wastewater by polyaniline/beidellite composite materials, Journal of Environmental Chemical Engineering, 3, 2484–2491, 2015. 10. Pandiselvi, K., Thambidurai, S., “Synthesis of porous chitosan–polyaniline/ZnO hybrid composite and application for removal of reactive orange 16 dye”, Colloids and Surfaces B: Biointerfaces 108, 229– 238, 2013. 11. Wang, J., Han, X., Ma, H., Ji, Y., Bi, L., Adsorptive removal of humic acid from aqueous solution on polyaniline/attapulgite composite, Chemical Engineering Journal 173, 171– 177, 2011. 12. Salem, M.A., Elsharkawy, R., Hablas, M.F., ‘Adsorption of Brilliant Green dye by polyaniline/silver nanocomposite: Kinetic, equilibrium, and thermodynamic studies’, European Polymer Journal, 75, 577-590, 2016. 13. Mu,B., Tang, J., Zhang, L., Wang, A., Preparation, characterization and application on dye adsorption of a well-defined two-dimensional superparamagnetic clay/polyaniline/Fe3O4 nanocomposite, Applied Clay Science, 132–133, 7-16, 2016. 14. Olad, A., Naseri, B., Preparation, characterization and anticorrosive properties of a novel polyaniline/clinoptilolite nanocomposite, Progress in Organic Coatings, 67, 233–238, 2010. 15. Jiang, N., Xu, Y., Dai, Y., Lou, W., Dai, L., ‘Polyaniline nanofibers assembled on alginate microsphere for Cu2+ and Pb2+ uptake’, Journal of Hazardous Materials,215-216,17-24, 2012. 16. Ayazi,Z., Khoshhesab, Z.M., Azhar, F.F., Mohajeri, Z., “Modeling and Optimization of Adsorption Removal of Reactive Orange 13 on the Alginate–Montmorillonite–Polyaniline Nanocomposite via Response Surface Methodology”, Journal of the Chinese Chemical Society, 64, 627-639, 2017. 17. Zhuang, Y., Yu, F., Chen, J., Ma, J., Batch and column adsorption of methylene blue by graphene/alginate nanocomposite: Comparison of single-network and double-network hydrogels, Journal of Environmental Chemical Engineering, 4(1), 147-156, 2016. 18. Karthik, R., Meenakshi, S., ‘Removal of Cr(VI) ions by adsorption onto sodiumalginate-polyaniline nanofibers’, International Journal of Biological Macromolecules, 72, 711–717, 2015. 19. Sharma, V., Rekha, P., Mohanty, P., Nanoporous hypercrosslinked polyaniline: An efficient adsorbent for the adsorptive removal of cationic and anionic dyes, 222, 1091-1100, 2016. 20. Lu, T., Xiang, T., Huang, X.L., Li,C., Zhao, W.F., Zhang, Q., Zhao, C.S., “Post-crosslinking towards stimuli-responsive sodium alginate beads fort he removal of dye and heavy metals”, Carbohydrate Polymers, 133, 587-595, 2015. 21. Kaykıoğlu, G., “Kolemanit ve Üleksit Atığı ile Sulu Çözeltilerden Metilen Mavisi Giderimi: Kinetik ve İzoterm Değerlendirmesi”, CBÜ Fen Bil. Dergi., 12(3), 499-509, 2016. 22. Okur, M., “Tekstil Atıksularındaki Metal Kompleks Boyarmaddelerin Yumurta Kabukları İle Giderimi”, Journal of the Faculty of Engineering and Architecture of Gazi University, 28 (4), 777-785, 2013. 23. Rafiqi, F.A., Majid, K., ‘Removal of copper from aqueous solution using polyaniline and polyaniline/ferricyanide composite, Journal of Environmental Chemical Engineering, 3,2492-2501,2015.
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Details

Primary Language Turkish
Subjects Chemical Engineering
Journal Section Original Articles
Authors

Müjgan Okur

Filiz Aktı

Ayşenur Çetintaş This is me

Publication Date December 30, 2018
Submission Date January 25, 2018
Published in Issue Year 2018 Volume: 6 Issue: 4

Cite

APA Okur, M., Aktı, F., & Çetintaş, A. (2018). Polianilin/Aljinat Kompozit Malzemesinin Asit Violet 90 Boyar Maddesinin Gideriminde Kullanılması: Kinetik Ve İzoterm Değerlendirmesi. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım Ve Teknoloji, 6(4), 729-740. https://doi.org/10.29109/gujsc.383614

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