Askorbik Asit’in Amperometrik Tayini için Esnek, Serbest Duran Nikel Sülfür Temelli Grafen Kağıt Elektrotun Geliştirilmesi

Year 2020, , 60 - 75, 15.01.2020

Kader Dağcı Kıranşan

https://doi.org/10.17714/gumusfenbil.562556

Abstract

Esnek, serbest duran ve dayanıklı nikel
sülfür/indirgenmiş grafen oksit (NiS/rGO) kompozit kağıt elektrot, rGO kağıt
elektrot yüzeyinde NiS yapılarının basit bir elektrokimyasal depozisyonuyla
hazırlanmıştır. NiS/rGO kompozit kağıt elektrot taramalı elektron mikroskopisi
(SEM), X-ışınları fotoelektron spektroskopisi (XPS), X-ışınları kırınım
difraksiyonu (XRD) , Raman spektroskopisi ve elektrokimyasal empedans
spektroskopisi (EIS) gibi teknikler kullanılarak karakterize edilmiştir.
Hazırlanan NiS/rGO kompozit kağıt, askorbik asitin (AA) elektrokimyasal tayininde
kullanılmıştır. NiS/rGO kompozit kağıt elektrot
yüzeyinde bulunan top benzeri NiS nano yapılarının, oldukça büyük aktif yüzey
alanı sağladığı için kağıt elektrotun katalitik performansını büyük ölçüde artırdığı
belirlenmiştir. AA, NiS/rGO kompozit kağıt üzerinde geniş lineer aralıkta (1.0-800
µM), düşük tayin limitinde (0.7 µM) ve yüksek seçicilikle tayin edilmiştir.
Bunun yanı sıra yapılan elektrokimyasal testler sonucu kompozit kağıt elektrodun
oldukça kararlı, esnek ve atmosfer koşullarına dayanıklı olduğu ortaya
konmuştur.

Keywords

Askorbik asit, Amperometrik sensör, Grafen kağıt elektrot, Nikel sülfür

Development of Flexible, Free-Standing Nickel Sulfide Based Graphene Paper Electrode for Amperometric Determination of Ascorbic Acid

Abstract

The flexible, free-standing and durable highly rough
NiS/rGO composite paper electrode was prepared with a simple electrochemical
deposition of NiS structures on the surface of the rGO paper electrode.  NiS/rGO composite paper electrode was
characterized by using scanning electron microscopy (SEM), X-ray photoelectron
spectroscopy (XPS), X-ray diffraction (XRD), Raman spectroscopy and
electrochemical impedance spectroscopy (EIS) techniques. As-prepared NiS/rGO
composite paper was used for the electrochemical detection of ascorbic acid
(AA). The rough and the ball-like NiS nanostructures on the rGO paper electrode surface
greatly increased the catalytic performance of the paper electrode by providing
a large active surface area. AA was detected on NiS/rGO composite paper with a
wide linear range from 1.0 to 800 µM, a low detection limit of 0.7 µM (S/N=3) and
a high sensitivity. Besides, the electrochemical tests showed that the
composite paper electrode is very stable, flexible and durable at the
atmospheric conditions.

Keywords

Ascorbic acid, Amperometric sensor, Graphene paper electrode, Nickel sulfur

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