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Kendiliğinden organize olan tek tabaka molekülleri kullanarak organik ışık yayan diyotların veriminin iyileştirilmesi

Year 2021, , 1235 - 1241, 15.10.2021

Eyyup Yalçın , Burak Gültekin , Hakan Bilgili , Mustafa Can

https://doi.org/10.17714/gumusfenbil.853760

Abstract

Ara yüzey iyileştirmeleri optoelektronik cihazların performansı üzerine önemli bir role sahiptir. Kendiliğinden organize olan tek tabaka molekülleri indiyum kalay oksit (ITO) ile organik katman arasında kullanılarak organik ışık yayan diyotlardan (OLEDs) daha yüksek performans elde edilmesi sağlanır. Bu çalışmada ITO’yu modifiye etmek için 4-metoksifenil boronik asit ile 3,5-dimetoksifenil boronik asit molekülleri bir ara yüzey katmanı olarak kullanılmıştır. Kendiliğinden organize olan moleküllerinin cihaz performansı üzerine etkisi elektriksel ve optiksel olarak analiz edilmiştir. Buna ek olarak, modifiye edilmiş ITO’nun yüzey morfolojisi atomik kuvvet mikroskopu (AFM), yüzey ıslanabilirliği ise temas açısı yöntemi ile ölçülmüştür. Elde edilen sonuçlara göre, ITO yüzeyi kendiliğinden organize olan moleküller ile modifiye edilen cihazların modifiye edilmemiş cihazlara göre daha iyi performans sergilediği görülmüştür.

Keywords

Enerji verimliliği Kendiliğinden organize tek tabaka moleküller OLED

Supporting Institution

Yok

Project Number

Yok

Thanks

Yok

References

  • An, D., Liu, H., Wang, S. and Li, X. (2019). Modification of ITO anodes with self-assembled monolayers for enhancing hole injection in OLEDs. Applied Physics Letters, 114(15), 153301. https://doi.org/10.1063/1.5086800
  • Can, M., Havare, A. K., Aydın, H., Yagmurcukardes, N., Demic, S., Icli, S. and Okur, S. (2014). Electrical properties of SAM-modified ITO surface using aromatic small molecules with double bond carboxylic acid groups for OLED applications. Applied Surface Science, 314, 1082-1086. https://doi.org/10.1016/j.apsusc.2014.05.181
  • Chong, L.-W., Lee, Y.L. and Wen, T.C. (2007). Surface modification of indium tin oxide anodes by self-assembly monolayers: Effects on interfacial morphology and charge injection in organic light-emitting diodes. Thin Solid Films, 515(5), 2833-2841. https://doi.org/10.1016/j.tsf.2006.05.010
  • Elschner, A., Bruder, F., Heuer, H.-W., Jonas, F., Karbach, A., Kirchmeyer, S. and Wehrmann, R. (2000). PEDT/PSS for efficient hole-injection in hybrid organic light-emitting diodes. Synthetic Metals, 111, 139-143. https://doi.org/10.1016/S0379-6779(99)00328-8
  • Forrest, S. R. (2004). The path to ubiquitous and low-cost organic electronic appliances on plastic. Nature, 428(6986), 911.
  • Hotchkiss, P. J., Jones, S. C., Paniagua, S. A., Sharma, A., Kippelen, B., Armstrong, N. R. and Marder, S. R. (2011). The modification of indium tin oxide with phosphonic acids: mechanism of binding, tuning of surface properties, and potential for use in organic electronic applications. Accounts of Chemical Research, 45(3), 337-346. https://doi.org/10.1021/ar200119g
  • Huang, F., Liu, H., Li, X. and Wang, S. (2020). Highly efficient hole injection/transport layer-free OLEDs based on self-assembled monolayer modified ITO by solution-process. Nano Energy, 78, 105399. https://doi.org/10.1016/j.nanoen.2020.105399
  • Huang, Q., Li, J., Evmenenko, G. A., Dutta, P. and Marks, T. J. (2006). Systematic Investigation of Nanoscale Adsorbate Effects at Organic Light-Emitting Diode Interfaces. Interfacial Structure− Charge Injection− Luminance Relationships. Chemistry of Materials, 18(9), 2431-2442. https://doi.org/10.1021/cm0604918
  • Kido, J., Kimura, M. and Nagai, K. (1995). Multilayer white light-emitting organic electroluminescent device. Science, 267(5202), 1332-1334. 10.1126/science.267.5202.1332
  • Kim, H., Horwitz, J., Kim, W., Mäkinen, A., Kafafi, Z. and Chrisey, D. (2002). Doped ZnO thin films as anode materials for organic light-emitting diodes. Thin Solid Films, 420, 539-543. https://doi.org/10.1016/S0040-6090(02)00836-2
  • Kim, H. R., Kim, T. W. and Park, S. G. (2019). Effective hole‐injection characteristics of organic light‐emitting diodes due to fluorinated self assembled monolayer embedded as a buffer layer. Polymer International, 68(8). 1478-1483, https://doi.org/10.1002/pi.5853
  • Kim, J., Cacialli, F., Cola, A., Gigli, G. and Cingolani, R. (1999). Increase of charge carriers density and reduction of Hall mobilities in oxygen-plasma treated indium–tin–oxide anodes. Applied Physics Letters, 75(1). 19-21, https://doi.org/10.1063/1.124263
  • Klauk, H. (2010). Organic thin-film transistors. Chemical Society Reviews, 39(7), 2643-2666. https://doi.org/10.1039/B909902F
  • Li, C., Kwong, C., Djurišić, A., Lai, P., Chui, P., Chan, W. and Liu, S. (2005). Improved performance of OLEDs with ITO surface treatments. Thin Solid Films, 477(1-2), 57-62. https://doi.org/10.1016/j.tsf.2004.08.111
  • Mi, X., Rungo, B. A., Dong, X., Liu, H., Li, X. and Wang, S. (2020). Enhanced efficiency and stability of organic light-emitting diodes via binary self-assembled monolayers of aromatic and aliphatic compounds on indium tin oxide. Organic Electronics, 105752. https://doi.org/10.1016/j.orgel.2020.105752
  • Qiao, X., Tao, Y., Wang, Q., Ma, D., Yang, C., Wang, L. and Wang, F. (2010). Controlling charge balance and exciton recombination by bipolar host in single-layer organic light-emitting diodes. Journal of Applied Physics, 108(3), 034508. https://doi.org/10.1063/1.3457672
  • Shang, Z., Liu, D., Wang, T., Yu, X., Li, B., Li, W., . . . Zhou, X. (2018). Enhanced Hole-Injection Property in an OLED with a Self-assembled Monolayer of Hole-Transporting TPD on Thin Au as the Anode. Transactions of Tianjin University, 1-7. https://doi.org/10.1007/s12209-018-0161-7
  • Tokudome, Y., Fukushima, T., Goto, A. and Kaji, H. (2011). Enhanced hole injection in organic light-emitting diodes by optimized synthesis of self-assembled monolayer. Organic Electronics, 12(10), 1600-1605. https://doi.org/10.1016/j.orgel.2011.06.022
  • Wang, M. and Hill, I. G. (2012). Fluorinated alkyl phosphonic acid SAMs replace PEDOT: PSS in polymer semiconductor devices. Organic Electronics, 13(3), 498-505. https://doi.org/10.1016/j.orgel.2011.12.008
  • Yalcin, E., Can, M., Rodriguez-Seco, C., Aktas, E., Pudi, R., Cambarau, W. and Palomares, E. (2018). Semiconductor self-assembled monolayers as selective contacts for efficient PiN perovskite solar cells. Energy & Environmental Science. 10.1039/C8EE01831F
  • Yalcin, E., Kara, D. A., Karakaya, C., Yigit, M. Z., Havare, A. K., Can, M. and Aboulouard, A. (2017). Functionalized organic semiconductor molecules to enhance charge carrier injection in electroluminescent cell. Optical Materials, 69, 283-290. https://doi.org/10.1016/j.optmat.2017.04.038
  • You, H., Dai, Y., Zhang, Z. and Ma, D. (2007). Improved performances of organic light-emitting diodes with metal oxide as anode buffer, Journal of Applied Physics, 101 (2), 06105, https://doi.org/10.1063/1.2430511
  • Zhao, Y., Duan, L., Zhang, D., Dong, G., Qiao, J., Wang, L. and Qiu, Y. (2014). Systematic Investigation of Surface Modification by Organosiloxane Self-Assembled on Indium–Tin Oxide for Improved Hole Injection in Organic Light-Emitting Diodes. ACS Applied Materials & Interfaces, 6(6), 4570-4577. https://doi.org/10.1021/am500399e
  • Zheng, H., Zhang, F., Zhou, N., Sun, M., Li, X., Xiao, Y. and Wang, S. (2018). Self-assembled monolayer-modified ITO for efficient organic light-emitting diodes: The impact of different self-assemble monolayers on interfacial and electroluminescent properties. Organic Electronics, 56, 89-95. https://doi.org/10.1016/j.orgel.2018.01.038
  • Zhong, Z. and Jiang, Y. (2006). Surface modification and characterization of indium–tin oxide for organic light-emitting devices. Journal of Colloid and İnterface Science, 302(2), 613-619. https://doi.org/10.1016/j.jcis.2006.07.009

Increasing efficiency of organic light emitting diode by using self assembled monolayers

Year 2021, , 1235 - 1241, 15.10.2021

Eyyup Yalçın , Burak Gültekin , Hakan Bilgili , Mustafa Can

https://doi.org/10.17714/gumusfenbil.853760

Abstract

Interface engineering has an important role on performance of optoelectronic devices. Self-assembled monolayers (SAMs) have been used between indium tin oxide (ITO) and organic layer to obtain high performance from organic light-emitting diodes (OLEDs). Herein, 4-Methoxyphenyl Boronic Acid and 3,5-Dimethoxyphenyl Boronic Acid have been used to ITO as an interface layer. The effect of SAMs on device performance was analyzed electrically and optically. Additionally, surfacre topography of modified ITO was characterized by atomic force microscope and surface wetability was analyzed by contact angle. According to results that has obtain, modified devices show better performance than unmodified devices.

Keywords

Energy efficiency Self-assembled monolayers OLED

Project Number

Yok

References

  • An, D., Liu, H., Wang, S. and Li, X. (2019). Modification of ITO anodes with self-assembled monolayers for enhancing hole injection in OLEDs. Applied Physics Letters, 114(15), 153301. https://doi.org/10.1063/1.5086800
  • Can, M., Havare, A. K., Aydın, H., Yagmurcukardes, N., Demic, S., Icli, S. and Okur, S. (2014). Electrical properties of SAM-modified ITO surface using aromatic small molecules with double bond carboxylic acid groups for OLED applications. Applied Surface Science, 314, 1082-1086. https://doi.org/10.1016/j.apsusc.2014.05.181
  • Chong, L.-W., Lee, Y.L. and Wen, T.C. (2007). Surface modification of indium tin oxide anodes by self-assembly monolayers: Effects on interfacial morphology and charge injection in organic light-emitting diodes. Thin Solid Films, 515(5), 2833-2841. https://doi.org/10.1016/j.tsf.2006.05.010
  • Elschner, A., Bruder, F., Heuer, H.-W., Jonas, F., Karbach, A., Kirchmeyer, S. and Wehrmann, R. (2000). PEDT/PSS for efficient hole-injection in hybrid organic light-emitting diodes. Synthetic Metals, 111, 139-143. https://doi.org/10.1016/S0379-6779(99)00328-8
  • Forrest, S. R. (2004). The path to ubiquitous and low-cost organic electronic appliances on plastic. Nature, 428(6986), 911.
  • Hotchkiss, P. J., Jones, S. C., Paniagua, S. A., Sharma, A., Kippelen, B., Armstrong, N. R. and Marder, S. R. (2011). The modification of indium tin oxide with phosphonic acids: mechanism of binding, tuning of surface properties, and potential for use in organic electronic applications. Accounts of Chemical Research, 45(3), 337-346. https://doi.org/10.1021/ar200119g
  • Huang, F., Liu, H., Li, X. and Wang, S. (2020). Highly efficient hole injection/transport layer-free OLEDs based on self-assembled monolayer modified ITO by solution-process. Nano Energy, 78, 105399. https://doi.org/10.1016/j.nanoen.2020.105399
  • Huang, Q., Li, J., Evmenenko, G. A., Dutta, P. and Marks, T. J. (2006). Systematic Investigation of Nanoscale Adsorbate Effects at Organic Light-Emitting Diode Interfaces. Interfacial Structure− Charge Injection− Luminance Relationships. Chemistry of Materials, 18(9), 2431-2442. https://doi.org/10.1021/cm0604918
  • Kido, J., Kimura, M. and Nagai, K. (1995). Multilayer white light-emitting organic electroluminescent device. Science, 267(5202), 1332-1334. 10.1126/science.267.5202.1332
  • Kim, H., Horwitz, J., Kim, W., Mäkinen, A., Kafafi, Z. and Chrisey, D. (2002). Doped ZnO thin films as anode materials for organic light-emitting diodes. Thin Solid Films, 420, 539-543. https://doi.org/10.1016/S0040-6090(02)00836-2
  • Kim, H. R., Kim, T. W. and Park, S. G. (2019). Effective hole‐injection characteristics of organic light‐emitting diodes due to fluorinated self assembled monolayer embedded as a buffer layer. Polymer International, 68(8). 1478-1483, https://doi.org/10.1002/pi.5853
  • Kim, J., Cacialli, F., Cola, A., Gigli, G. and Cingolani, R. (1999). Increase of charge carriers density and reduction of Hall mobilities in oxygen-plasma treated indium–tin–oxide anodes. Applied Physics Letters, 75(1). 19-21, https://doi.org/10.1063/1.124263
  • Klauk, H. (2010). Organic thin-film transistors. Chemical Society Reviews, 39(7), 2643-2666. https://doi.org/10.1039/B909902F
  • Li, C., Kwong, C., Djurišić, A., Lai, P., Chui, P., Chan, W. and Liu, S. (2005). Improved performance of OLEDs with ITO surface treatments. Thin Solid Films, 477(1-2), 57-62. https://doi.org/10.1016/j.tsf.2004.08.111
  • Mi, X., Rungo, B. A., Dong, X., Liu, H., Li, X. and Wang, S. (2020). Enhanced efficiency and stability of organic light-emitting diodes via binary self-assembled monolayers of aromatic and aliphatic compounds on indium tin oxide. Organic Electronics, 105752. https://doi.org/10.1016/j.orgel.2020.105752
  • Qiao, X., Tao, Y., Wang, Q., Ma, D., Yang, C., Wang, L. and Wang, F. (2010). Controlling charge balance and exciton recombination by bipolar host in single-layer organic light-emitting diodes. Journal of Applied Physics, 108(3), 034508. https://doi.org/10.1063/1.3457672
  • Shang, Z., Liu, D., Wang, T., Yu, X., Li, B., Li, W., . . . Zhou, X. (2018). Enhanced Hole-Injection Property in an OLED with a Self-assembled Monolayer of Hole-Transporting TPD on Thin Au as the Anode. Transactions of Tianjin University, 1-7. https://doi.org/10.1007/s12209-018-0161-7
  • Tokudome, Y., Fukushima, T., Goto, A. and Kaji, H. (2011). Enhanced hole injection in organic light-emitting diodes by optimized synthesis of self-assembled monolayer. Organic Electronics, 12(10), 1600-1605. https://doi.org/10.1016/j.orgel.2011.06.022
  • Wang, M. and Hill, I. G. (2012). Fluorinated alkyl phosphonic acid SAMs replace PEDOT: PSS in polymer semiconductor devices. Organic Electronics, 13(3), 498-505. https://doi.org/10.1016/j.orgel.2011.12.008
  • Yalcin, E., Can, M., Rodriguez-Seco, C., Aktas, E., Pudi, R., Cambarau, W. and Palomares, E. (2018). Semiconductor self-assembled monolayers as selective contacts for efficient PiN perovskite solar cells. Energy & Environmental Science. 10.1039/C8EE01831F
  • Yalcin, E., Kara, D. A., Karakaya, C., Yigit, M. Z., Havare, A. K., Can, M. and Aboulouard, A. (2017). Functionalized organic semiconductor molecules to enhance charge carrier injection in electroluminescent cell. Optical Materials, 69, 283-290. https://doi.org/10.1016/j.optmat.2017.04.038
  • You, H., Dai, Y., Zhang, Z. and Ma, D. (2007). Improved performances of organic light-emitting diodes with metal oxide as anode buffer, Journal of Applied Physics, 101 (2), 06105, https://doi.org/10.1063/1.2430511
  • Zhao, Y., Duan, L., Zhang, D., Dong, G., Qiao, J., Wang, L. and Qiu, Y. (2014). Systematic Investigation of Surface Modification by Organosiloxane Self-Assembled on Indium–Tin Oxide for Improved Hole Injection in Organic Light-Emitting Diodes. ACS Applied Materials & Interfaces, 6(6), 4570-4577. https://doi.org/10.1021/am500399e
  • Zheng, H., Zhang, F., Zhou, N., Sun, M., Li, X., Xiao, Y. and Wang, S. (2018). Self-assembled monolayer-modified ITO for efficient organic light-emitting diodes: The impact of different self-assemble monolayers on interfacial and electroluminescent properties. Organic Electronics, 56, 89-95. https://doi.org/10.1016/j.orgel.2018.01.038
  • Zhong, Z. and Jiang, Y. (2006). Surface modification and characterization of indium–tin oxide for organic light-emitting devices. Journal of Colloid and İnterface Science, 302(2), 613-619. https://doi.org/10.1016/j.jcis.2006.07.009
There are 25 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Eyyup Yalçın 0000-0002-7468-2169

Burak Gültekin

Hakan Bilgili 0000-0001-5646-6641

Mustafa Can 0000-0002-1749-8293

Project Number Yok
Publication Date October 15, 2021
Submission Date January 7, 2021
Acceptance Date September 4, 2021
Published in Issue Year 2021

Cite

APA Yalçın, E., Gültekin, B., Bilgili, H., Can, M. (2021). Kendiliğinden organize olan tek tabaka molekülleri kullanarak organik ışık yayan diyotların veriminin iyileştirilmesi. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 11(4), 1235-1241. https://doi.org/10.17714/gumusfenbil.853760