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Synthesis and characterization of boron nitride nanotubes (BNNTs) with a new method and precursor materials

Year 2021, , 1217 - 1224, 15.10.2021
https://doi.org/10.17714/gumusfenbil.887340

Abstract

Boron nitride nanotubes (BNNTs) have many application areas thanks to their superior properties such as thermal and electrical insulation, resistance to oxidation, high hydrophobicity, and high hydrogen storage capacity, as well as biocompatible properties. Therefore, new synthesis methods are being searched for BNNT with increasing interest in recent years. In this study, high purity and yield BNNTs were synthesized using precursor materials and methods that were not previously tried in the literature. A chemical vapor storage (CVD) furnace was used for the synthesis, and various parameters were changed to achieve optimum conditions. The structure of the obtained BNNTs was characterized by Fourier conversion infrared spectroscopy (FTIR), Raman spectroscopy, and a UV-visible spectrophotometer. In addition, surface morphologies were illuminated using transmission electron microscopy (TEM) and scanning electron microscopy (SEM). However, it has been observed that BNNTs obtained as a result of HR-TEM (high-resolution transmission electron microscope) analysis have a single-walled structure that is difficult to synthesize. This increases the importance and quality of synthesized BNNTs.

References

  • Ahmad, P., Khandaker, M.U., Amin, Y.M. and Khan, Z.R. (2015). Synthesis of boron nitride microtubes and formation of boron nitride nanosheets. Materials and Manufacturing Processes, 30, 184-188. https://doi.org/10.1080/10426914.2014.952041
  • Ansaloni, L.M.S. and Sousa, E.M.B. (2013). Boron nitride nanostructured: synthesis, characterization and potential use in cosmetics. Materials Sciences and Applications, 4, 22-28. https://doi.org/10.4236/msa.2013.41004
  • Arenal, R., Ferrari, A.C., Reich, S., Wirtz, L., Mevellec, J.-Y., Lefrant, S., Rubio, A. and Loiseau, A. (2006). Raman spectroscopy of single-wall boron nitride nanotubes. Nano Letters, 6(8), 1812-1816. https://doi.org/10.1021/nl0602544
  • Bai, X.D., Golberg, D., Bando, Y., Zhi, C., Tang, C., Mitome, M. and Kurashima, K. (2007). Deformation-driven electrical transport of individual boron nitride nanotubes. Nano Letters, 7(3), 632-637. https://doi.org/10.1021/nl062540l
  • Berber, S., Kwon, Y.-K. and Tomanek, D. (2000). Unusually high thermal conductivity of carbon nanotubes. Physical Review Letters, 84(29), 4613-4616. https://doi.org/10.1103/PhysRevLett.84.4613
  • Cao, F., Ren, W., Ji, Y.-M. and Zhao, C. (2009). The structural and electronic properties of amine-functionalized boron nitride nanotubes via ammonia plasmas: a density functional theory study. Nanotechnology, 20(19, 145703. https://doi.org/10.1088/0957-4484/20/14/145703
  • Chang, C.W.A., Fennimore, M., Afanasiev, A., Okawa, D., Ikuno, T., Garcia, H., Li, D., Majumdar, A. and Zettl, A. (2006). Isotope efect on the thermal conductivity of boron nitride nanotubes. Physical Review Letters, 97(8), 085901. https://doi.org/10.1103/PhysRevLett.97.085901 Chang, C.W., Han, W.-Q. and Zettl, A. (2005). Termal conductivity of B-C-N and BN nanotubes. Journal of Vacuum Science & Technology B, 23(5), 1-3. https://doi.org/10.1116/1.2008266
  • Chen, X., Wu, P., Rousseas, M., Okawa, D., Gartner, Z., Zettl, A. and Bertozzi, C.R. (2009). Boron nitride nanotubes are noncytotoxic and can be functionalized for interaction with proteins and cells. Journal of the American Chemical Society, 131(3), 890-891. https://doi.org/10.1021/ja807334b
  • Ciofani, G. (2010). Potential applications of boron nitride nanotubes as drug delivery systems. Expert Opinion on Drug Delivery, 7(8), 889-893. https://doi.org/10.1517/17425247.2010.499897
  • Ciofani, G., Raffa, V., Menciassi, A. and Cuschieri, A. (2009). Boron nitride nanotubes: an innovative tool for nanomedicine. Nano Today, 4(1), 8-10. https://doi.org/10.1016/j.nantod.2008.09.001
  • Eti Maden for life. (2021). Boron in the world.
  • Ferreira, T.H., Silva, P.R.O. and Santos, R.G. (2011). A novel synthesis route to produce boron nitride nanotubes for bioapplications. Journal of Biomaterials and Nanobiotechnology, 2, 426-434. https://doi.org/10.4236/jbnb.2011.24052
  • Fu, L., Wang, T., Yu, J., Dai, W., Sun, H., Liu, Z., Sun, R., Jiang, N., Yu, A. and Lin, C.-T. (2017). An ultrathin high-performance heat spreader fabricated with hydroxylated boron nitride nanosheets. 2D Materials, 4(2), 025047. https://doi.org/10.1088/2053-1583/aa636e
  • Gao, Z., Zhi, C., Bando, Y., Golberg, D. and Serizawa, T. (2011). Noncovalent functionalization of disentangled boron nitride nanotubes with favin mononucleotides for strong and stable visiblelight emission in aqueous solution. ACS Applied Materials & Interfaces, 3(3), 627-632. https://doi.org/10.1021/am1010699
  • Gao, Z., Zhi, C., Bando, Y., Golberg, D., Komiyama, M. and Serizawa, T. (2012). Efficient disentanglement of boron nitride nanotubes using water-soluble polysaccharides for protein immobilization. RSC Advances, 2(15), 6200-6208. https://doi.org/10.1039/C2RA20765F
  • Iijima, S. (1991). Helical microtubules of graphitic carbon, Nature, 354(6348), 56-58. https://doi.org/10.1038/354056a0
  • Kalay, S., Yilmaz, Z. and Çulha, M. (2013). Synthesis of boron nitride nanotubes from unprocessed colemanite. Beilstein Journal of Nanotechnology, 4, 843-851. https://doi.org/10.3762/bjnano.4.95
  • Kumar, V., Lahiri, D. and Lahiri, I. (2018). Synthesis of boron nitride nanotubes and boron nitride nanoflakes with potential application in bioimaging. Materials Today: Proceedings, 5(8), 16756-16762. https://doi.org/10.1016/j.matpr.2018.06.037
  • Lauret, J.S., Arenal, R., Ducastelle, F., Loiseau, A., Cau, M., Tretout, B.A., Rosencher, E. and Capes, L.G. (2005). Optical transitions in single-wall boron nitride nanotubes. Physical Review Letters, 94(3), 037405. https://doi.org/10.1103/PhysRevLett.94.037405
  • Lee, C.H., Wang, J., Kayatsha, V.K., Huang, J.Y. and Yap, Y.K. (2008). Effective growth of boron nitride nanotubes by thermal chemical vapor deposition. Nanotechnology, 19, 455605. https://doi.org/10.1088/0957-4484/19/45/455605
  • Lee, C.H., Xie, M., Kayastha, V., Wang, J. And Yap, Y.K. (2010). Patterned growth of boron nitride nanotubes by catalytic chemical vapor deposition. Chemistry of Materials, 22(5), 1782-1787. https://doi.org/10.1021/cm903287u
  • Nithya, J.S.M. and Pandurangan, A. (2014). Efficient mixed metal oxide routed synthesis of boron nitride nanotubes. RSC Advances, 4, 26697. https://doi.org/10.1039/c4ra01204f
  • Pakdel, A., Zhi, C., Bando, Y., Nakayama, T. and Golberg, D. (2012). A comprehensive analysis of the CVD growth of boron nitride nanotubes. Nanotechnology, 23, 215601. https://doi.org/10.1088/0957-4484/23/21/215601
  • Pan, A. and Chen, Y. (2014). Large-scale fabrication of boron nitride nanotubes with high purity via solid-state reaction Method. Nanoscale Research Letters, 9, 555. https://doi.org/10.1186/1556-276X-9-555
  • Roy, A.K., Park, B., Lee, K.S., Park, S.Y. and In, I. (2014). Boron nitride nanosheets decorated with silver nanoparticles through mussel-inspired chemistry of dopamine. Nanotechnology, 25(44), 445603. https://doi.org/10.1088/0957-4484/25/44/445603
  • Salvetti, A., Rossi, L., Iacopetti, P., Li, X., Nitti, S., Pellegrino, T., Mattoli, V., Golberg, D. and Ciofani, G. (2015). In vivo biocompatibility of boron nitride nanotubes: effects on stem cell biology and tissue regeneration in planarians. Nanomedicine (London), 10(12), 1911-1922. https://doi.org/10.2217/nnm.15.46
  • Şen, Ö., Çobandede, Z., Emanet, M., Bayrak, Ö.F. and Çulha, M. (2017). Boron nitride nanotubes for gene silencing. Biochimica et Biophysica Acta - General Subjects, 1861(9), 2391-2397. https://doi.org/10.1016/j.bbagen.2017.05.026
  • Tang, C., Bando, Y., Sato, T. and Kurashima, K. (2002). A novel precursor for synthesis of pure boron nitride nanotubes. Chemical Communications, 12, 1290-1291. https://doi.org/10.1039/B202177C
  • Wang, H., Wang, W., Wang, H., Zhang, F., Li, Y. and Fu, Z. (2018). Synthesis of boron nitride nanotubes by combining citrate nitrate combustion reaction and catalytic chemical vapor deposition. Ceramics International, 44(12), 13959- 13966. https://doi.org/10.1016/j.ceramint.2018.04.245
  • Wu, J., Chen, H., Zhao, L., He, X., Fang, W., Li, W. and Du, X. (2017). Synthesis of boron nitride nanotubes by catalytic pyrolysis of organi-inorganic hybrid precursor. Ceramics International, 43(6), 5145-5149. https://doi.org/10.1016/j.ceramint.2017.01.029
  • Xu, S., Fan, Y., Luo, J., Zhang, L., Wang, W., Yao, B. and An, L. (2007). Phonon characteristics and photoluminescence of bamboo structured silicon-doped boron nitride multiwall nanotubes. Applied Physics Letters, 90, 013115. https://doi.org/10.1063/1.2429904
  • Zhi, C., Bando, Y., Wang, W., Tang, C., Kuwahara, H. and Golberg, D. (2007). DNA-mediated assembly of boron nitride nanotubes. Chemistry: An Asian Journal, 2(12), 1581-1585. https://doi.org/10.1002/asia.2007002

Yeni bir yöntem ve öncü maddeler ile bor nitrür nanotüplerin (BNNT'lerin) sentezi ve karakterizasyonu

Year 2021, , 1217 - 1224, 15.10.2021
https://doi.org/10.17714/gumusfenbil.887340

Abstract

Bor nitrür nanotüpler (BNNT’ler) ısıl ve elektriksel yalıtkanlıkları, oksidasyona karşı dayanıklılıkları, yüksek hidrofobiteleri ve yüksek hidrojen depolama kapasiteleri gibi üstün özelliklerinin yanı sıra biyouyumlu özellikleri sayesinde birçok uygulama alanına sahiptir. Dolayısıyla BNNT için son yıllarda gittikçe artan bir ilgiyle yeni sentez yöntemleri araştırılmaktadır. Bu çalışmada, literatürde daha önce denenmemiş öncü maddeler ve yöntemle yüksek saflıkta ve verimde BNNT’ler sentezledi. Sentez için bir kimyasal buhar depolama (CVD) fırını kullanıldı ve çeşitli parametreler değiştirilerek optimum koşullar elde edildi. Elde edilen BNNT’lerin yapısı fourier dönüşümlü kızılötesi spektroskopisi (FTIR), Raman spektroskopisi ve bir UV-visible spektrofotometresi kullanılarak karakterize edildi. Ayrıca yüzey morfolojileri geçirimli elektron mikroskobu (TEM) ve taramalı elektron mikroskobu (SEM) kullanılarak aydınlatıldı. Bunla birlikte HR-TEM (yüksek çözünürlüklü geçirimli elektron mikroskobu) analiz sonuçlarına göre elde edilen BNNT’lerin, sentezlenmesi zor olan tek duvarlı (single-walled) bir yapıya sahip olduğu görülmüştür. Buda sentezlenen BNNT’lerin önemini ve kalitesini arttırmaktadır.

References

  • Ahmad, P., Khandaker, M.U., Amin, Y.M. and Khan, Z.R. (2015). Synthesis of boron nitride microtubes and formation of boron nitride nanosheets. Materials and Manufacturing Processes, 30, 184-188. https://doi.org/10.1080/10426914.2014.952041
  • Ansaloni, L.M.S. and Sousa, E.M.B. (2013). Boron nitride nanostructured: synthesis, characterization and potential use in cosmetics. Materials Sciences and Applications, 4, 22-28. https://doi.org/10.4236/msa.2013.41004
  • Arenal, R., Ferrari, A.C., Reich, S., Wirtz, L., Mevellec, J.-Y., Lefrant, S., Rubio, A. and Loiseau, A. (2006). Raman spectroscopy of single-wall boron nitride nanotubes. Nano Letters, 6(8), 1812-1816. https://doi.org/10.1021/nl0602544
  • Bai, X.D., Golberg, D., Bando, Y., Zhi, C., Tang, C., Mitome, M. and Kurashima, K. (2007). Deformation-driven electrical transport of individual boron nitride nanotubes. Nano Letters, 7(3), 632-637. https://doi.org/10.1021/nl062540l
  • Berber, S., Kwon, Y.-K. and Tomanek, D. (2000). Unusually high thermal conductivity of carbon nanotubes. Physical Review Letters, 84(29), 4613-4616. https://doi.org/10.1103/PhysRevLett.84.4613
  • Cao, F., Ren, W., Ji, Y.-M. and Zhao, C. (2009). The structural and electronic properties of amine-functionalized boron nitride nanotubes via ammonia plasmas: a density functional theory study. Nanotechnology, 20(19, 145703. https://doi.org/10.1088/0957-4484/20/14/145703
  • Chang, C.W.A., Fennimore, M., Afanasiev, A., Okawa, D., Ikuno, T., Garcia, H., Li, D., Majumdar, A. and Zettl, A. (2006). Isotope efect on the thermal conductivity of boron nitride nanotubes. Physical Review Letters, 97(8), 085901. https://doi.org/10.1103/PhysRevLett.97.085901 Chang, C.W., Han, W.-Q. and Zettl, A. (2005). Termal conductivity of B-C-N and BN nanotubes. Journal of Vacuum Science & Technology B, 23(5), 1-3. https://doi.org/10.1116/1.2008266
  • Chen, X., Wu, P., Rousseas, M., Okawa, D., Gartner, Z., Zettl, A. and Bertozzi, C.R. (2009). Boron nitride nanotubes are noncytotoxic and can be functionalized for interaction with proteins and cells. Journal of the American Chemical Society, 131(3), 890-891. https://doi.org/10.1021/ja807334b
  • Ciofani, G. (2010). Potential applications of boron nitride nanotubes as drug delivery systems. Expert Opinion on Drug Delivery, 7(8), 889-893. https://doi.org/10.1517/17425247.2010.499897
  • Ciofani, G., Raffa, V., Menciassi, A. and Cuschieri, A. (2009). Boron nitride nanotubes: an innovative tool for nanomedicine. Nano Today, 4(1), 8-10. https://doi.org/10.1016/j.nantod.2008.09.001
  • Eti Maden for life. (2021). Boron in the world.
  • Ferreira, T.H., Silva, P.R.O. and Santos, R.G. (2011). A novel synthesis route to produce boron nitride nanotubes for bioapplications. Journal of Biomaterials and Nanobiotechnology, 2, 426-434. https://doi.org/10.4236/jbnb.2011.24052
  • Fu, L., Wang, T., Yu, J., Dai, W., Sun, H., Liu, Z., Sun, R., Jiang, N., Yu, A. and Lin, C.-T. (2017). An ultrathin high-performance heat spreader fabricated with hydroxylated boron nitride nanosheets. 2D Materials, 4(2), 025047. https://doi.org/10.1088/2053-1583/aa636e
  • Gao, Z., Zhi, C., Bando, Y., Golberg, D. and Serizawa, T. (2011). Noncovalent functionalization of disentangled boron nitride nanotubes with favin mononucleotides for strong and stable visiblelight emission in aqueous solution. ACS Applied Materials & Interfaces, 3(3), 627-632. https://doi.org/10.1021/am1010699
  • Gao, Z., Zhi, C., Bando, Y., Golberg, D., Komiyama, M. and Serizawa, T. (2012). Efficient disentanglement of boron nitride nanotubes using water-soluble polysaccharides for protein immobilization. RSC Advances, 2(15), 6200-6208. https://doi.org/10.1039/C2RA20765F
  • Iijima, S. (1991). Helical microtubules of graphitic carbon, Nature, 354(6348), 56-58. https://doi.org/10.1038/354056a0
  • Kalay, S., Yilmaz, Z. and Çulha, M. (2013). Synthesis of boron nitride nanotubes from unprocessed colemanite. Beilstein Journal of Nanotechnology, 4, 843-851. https://doi.org/10.3762/bjnano.4.95
  • Kumar, V., Lahiri, D. and Lahiri, I. (2018). Synthesis of boron nitride nanotubes and boron nitride nanoflakes with potential application in bioimaging. Materials Today: Proceedings, 5(8), 16756-16762. https://doi.org/10.1016/j.matpr.2018.06.037
  • Lauret, J.S., Arenal, R., Ducastelle, F., Loiseau, A., Cau, M., Tretout, B.A., Rosencher, E. and Capes, L.G. (2005). Optical transitions in single-wall boron nitride nanotubes. Physical Review Letters, 94(3), 037405. https://doi.org/10.1103/PhysRevLett.94.037405
  • Lee, C.H., Wang, J., Kayatsha, V.K., Huang, J.Y. and Yap, Y.K. (2008). Effective growth of boron nitride nanotubes by thermal chemical vapor deposition. Nanotechnology, 19, 455605. https://doi.org/10.1088/0957-4484/19/45/455605
  • Lee, C.H., Xie, M., Kayastha, V., Wang, J. And Yap, Y.K. (2010). Patterned growth of boron nitride nanotubes by catalytic chemical vapor deposition. Chemistry of Materials, 22(5), 1782-1787. https://doi.org/10.1021/cm903287u
  • Nithya, J.S.M. and Pandurangan, A. (2014). Efficient mixed metal oxide routed synthesis of boron nitride nanotubes. RSC Advances, 4, 26697. https://doi.org/10.1039/c4ra01204f
  • Pakdel, A., Zhi, C., Bando, Y., Nakayama, T. and Golberg, D. (2012). A comprehensive analysis of the CVD growth of boron nitride nanotubes. Nanotechnology, 23, 215601. https://doi.org/10.1088/0957-4484/23/21/215601
  • Pan, A. and Chen, Y. (2014). Large-scale fabrication of boron nitride nanotubes with high purity via solid-state reaction Method. Nanoscale Research Letters, 9, 555. https://doi.org/10.1186/1556-276X-9-555
  • Roy, A.K., Park, B., Lee, K.S., Park, S.Y. and In, I. (2014). Boron nitride nanosheets decorated with silver nanoparticles through mussel-inspired chemistry of dopamine. Nanotechnology, 25(44), 445603. https://doi.org/10.1088/0957-4484/25/44/445603
  • Salvetti, A., Rossi, L., Iacopetti, P., Li, X., Nitti, S., Pellegrino, T., Mattoli, V., Golberg, D. and Ciofani, G. (2015). In vivo biocompatibility of boron nitride nanotubes: effects on stem cell biology and tissue regeneration in planarians. Nanomedicine (London), 10(12), 1911-1922. https://doi.org/10.2217/nnm.15.46
  • Şen, Ö., Çobandede, Z., Emanet, M., Bayrak, Ö.F. and Çulha, M. (2017). Boron nitride nanotubes for gene silencing. Biochimica et Biophysica Acta - General Subjects, 1861(9), 2391-2397. https://doi.org/10.1016/j.bbagen.2017.05.026
  • Tang, C., Bando, Y., Sato, T. and Kurashima, K. (2002). A novel precursor for synthesis of pure boron nitride nanotubes. Chemical Communications, 12, 1290-1291. https://doi.org/10.1039/B202177C
  • Wang, H., Wang, W., Wang, H., Zhang, F., Li, Y. and Fu, Z. (2018). Synthesis of boron nitride nanotubes by combining citrate nitrate combustion reaction and catalytic chemical vapor deposition. Ceramics International, 44(12), 13959- 13966. https://doi.org/10.1016/j.ceramint.2018.04.245
  • Wu, J., Chen, H., Zhao, L., He, X., Fang, W., Li, W. and Du, X. (2017). Synthesis of boron nitride nanotubes by catalytic pyrolysis of organi-inorganic hybrid precursor. Ceramics International, 43(6), 5145-5149. https://doi.org/10.1016/j.ceramint.2017.01.029
  • Xu, S., Fan, Y., Luo, J., Zhang, L., Wang, W., Yao, B. and An, L. (2007). Phonon characteristics and photoluminescence of bamboo structured silicon-doped boron nitride multiwall nanotubes. Applied Physics Letters, 90, 013115. https://doi.org/10.1063/1.2429904
  • Zhi, C., Bando, Y., Wang, W., Tang, C., Kuwahara, H. and Golberg, D. (2007). DNA-mediated assembly of boron nitride nanotubes. Chemistry: An Asian Journal, 2(12), 1581-1585. https://doi.org/10.1002/asia.2007002
There are 32 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Tuba Tarhan 0000-0003-2656-4464

Publication Date October 15, 2021
Submission Date February 26, 2021
Acceptance Date August 23, 2021
Published in Issue Year 2021

Cite

APA Tarhan, T. (2021). Synthesis and characterization of boron nitride nanotubes (BNNTs) with a new method and precursor materials. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 11(4), 1217-1224. https://doi.org/10.17714/gumusfenbil.887340