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İyonotropik Jelleşme Yöntemi ile Hazırlanan Kitosan Nanopartiküllerde Hapsetme (Enkapsülasyon) ile Anyonik Boyaların Uzaklaştırılma ve Hapsedilen Boyanın Nanopartikülde Depolanma Etkinliğinin Araştırılması

Year 2018, Volume: 8 Issue: 1, 26 - 37, 31.01.2018
https://doi.org/10.17714/gumusfenbil.307356

Abstract

İyonotropik etkileşim ile kitosan nanopartiküller
anyonik boya (Fast Green FCF) içeren çözelti ortamında hazırlandı. Boya
hapsedilmiş kitosan nanopartiküller SEM ve Zeta-sizer ile karekterize edildi.
Kitosan nanopartikül içerisine hapsedilen boyanın sulu ortamdan uzaklaşmasında
etkili parametreler ve nanopartiküller içerisinde hapsolma kararlılığı farklı
pH çözeltilerinde araştırıldı. Fast Green FCF’nin sulu ortamdan % 90’nın
üzerinde bir etkinlikle uzaklaştırılması sağlandı. Kitosan nanopartikül
içerisine hapsedilen boya miktarı ise 1140 mg/g kitosan olarak belirlendi.

References

  • Abbasi, M., 2017. Synthesis and characterization of magnetic nanocomposite of chitosan/SiO2/carbon nanotubes and its application for dyes removal, Journal of Cleaner Production, 145, 105-113.
  • Agarwal, S., Gupta, V.K., Ghasemi. ve M., Azimi-Amin, J., 2017. Peganum harmala-L Seeds adsorbent for the rapid removal of noxious brilliant green dyes from aqueous phase, Journal of Molecular Liquids, 231, 296-305.
  • Agarwal, S., Tyagi, I., Gupta, V.K., Mashhadi, S. ve Ghasemi, M., 2016. Kinetics and thermodynamics of Malachite Green dye removal from aqueous phase using iron nanoparticles loaded on ash, Journal of Molecular Liquids, 223, 1340-1347.
  • Al Nafiey, A., Addad, A., Sieber, B., Chastanet, G., Barras, A., Szunerits, S. ve Boukherroub, R., 2017. Reduced graphene oxide decorated with Co3O4 nanoparticles (rGO-Co3O4) nanocomposite: A reusable catalyst for highly efficient reduction of 4-nitrophenol, and Cr (VI) and dye removal from aqueous solutions, Chemical Engineering Journal, 322, 375-384.
  • Aldana, A.A., González, A., Strumia, M.C. ve Martinelli, M., 2012. Preparation and characterization of chitosan/genipin/poly (N-vinyl-2-pyrrolidone) films for controlled release drugs, Materials Chemistry and Physics, 134(1), 317-324.
  • Alver, E. ve Metin, A.Ü., 2012. Anionic dye removal from aqueous solutions using modified zeolite: Adsorption kinetics and isotherm studies, Chemical Engineering Journal, 200, 59-67.
  • Alver, E., Bulut, M., Metin, A.Ü. ve Çiftçi, H., 2017. One step effective removal of Congo Red in chitosan nanoparticles by encapsulation, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 171, 132-138.
  • Alver, E., Metin, A.Ü. ve Çiftçi, H., 2014. Synthesis and characterization of chitosan/polyvinylpyrrolidone/zeolite composite by solution blending method, Journal of Inorganic and Organometallic Polymers and Materials, 24(6), 1048-1054.
  • Antoniou, J., Liu, F., Majeed, H., Qi, J., Yokoyama, W. ve Zhong, F., 2015. Physicochemical and morphological properties of size-controlled chitosan–tripolyphosphate nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 465, 137-146.
  • Bhati, I., Punjabi, P.B. ve Ameta, S.C., 2010. Photocatalytic degradation of fast green using nanosized CeCrO3, Macedonian Journal of Chemistry and Chemical Engineering, 29(2), 195-202.
  • Chen, C.Y., Chang, J.C. ve Chen, A.H., 2011. Competitive biosorption of azo dyes from aqueous solution on the templated crosslinkedchitosan nanoparticles, Journal of Hazardous Materials, 185, 430−441.
  • Chiou, M.S. ve Li, H.Y., 2003. Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads, Chemosphere, 50(8), 1095-1105.
  • Crini, G., 2006. Non-conventional low-cost adsorbents for dye removal: a review, Bioresource Technology, 97, 1061−1085.
  • De Moura, M.R., Aouada, F.A., Avena-Bustillos, R.J., McHugh, T.H., Krochta, J.M. ve Mattoso, L.H., 2009. Improved barrier and mechanical properties of novel hydroxypropylmethylcellulose edible films with chitosan/tripolyphosphate nanoparticles, Journal of Food Engineering, 92, 448–453.
  • Demir, A. ve Seventekin, N., 2009. Kitin, kitosan ve genel kullanım alanları, Tekstil Teknolojileri Elektronik Dergisi, 3(2), 92-103.
  • Geçer, A., Yıldız, N., Kavak, D. ve Çalımlı, A., 2009. Comparison of chitosan apatite composites synthesized by different methods, Polymer Composites, 30(3), 288-295.
  • George, M. ve Abraham, T.E., 2006. Polyionic hydrocolloids for the intestinal delivery ofprotein drugs: alginate and chitosan—a review, Journal of Controlled Release, 114, 1–14.
  • Gonçalves, J.O., Santos, J.P., Rios, E.C., Crispim, M.M., Dotto, G.L. ve Pinto, L.A.A., 2017. Development of chitosan based hybrid hydrogels for dyes removal from aqueous binary system, Journal of Molecular Liquids, 225, 265-270.
  • Gong, R., Ding, Y., Li, M., Yang, C., Liu, H. ve Sun, Y., 2005. Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution, Dyes and Pigments, 64(3), 187-192.
  • Gupta, V.K., Ali, I. ve Saini, V.K., 2004. Removal of rhodamine B, fast green, and methylene blue from wastewater using red mud, an aluminum industry waste, Industrial & Engineering Chemistry Research, 43(7), 1740-1747.
  • Gupta, V.K., Ali, I., Saini, V.K., Van Gerven, T., Van der Bruggen, B. ve Vandecasteele, C., 2005. Removal of dyes from wastewater using bottom ash. Industrial & Engineering Chemistry Research, 44(10), 3655-3664.
  • Hashemian, S. ve Foroghimoqhadam, A., 2014. Effect of copper doping on CoTiO 3 ilmenite type nanoparticles for removal of congo red from aqueous solution, Chemical Engineering Journal, 235, 299-306.
  • Huang, R., Liu, Q., Huo, J. ve Yang, B., 2017. Adsorption of methyl orange onto protonated cross-linked chitosan, Arabian Journal of Chemistry, 10(1), 24-32.
  • Kumar, A., Paliwal, M., Ameta, R. ve Ameta, S.C., 2008. Oxidation of fast green FCF by the solar photo-Fenton process, Journal of the Iranian Chemical Society, 5(2), 346-351.
  • Kumari, H.J., Krishnamoorthy, P., Arumugam, T.K., Radhakrishnan, S. ve Vasudevan, D., 2017. An efficient removal of crystal violet dye from waste water by adsorption onto TLAC/Chitosan composite: A novel low cost adsorbent, International Journal of Biological Macromolecules, 96, 324-333.
  • Marrakchi, F., Ahmed, M.J., Khanday, W.A., Asif, M. ve Hameed, B.H., 2017. Mesoporous-activated carbon prepared from chitosan flakes via single-step sodium hydroxide activation for the adsorption of methylene blue, International Journal of Biological Macromolecules, 98, 233-239.
  • Metin, A.Ü. ve Alver, E., 2016. Fibrous polymer-grafted chitosan/clay composite beads as a carrier for immobilization of papain and its usability for mercury elimination, Bioprocess and Biosystems Engineering, 39(7), 1137-1149.
  • Metin, A.Ü., Çiftçi, H. ve Alver, E., 2013. Efficient removal of acidic dye using low-cost biocomposite beads, Industrial & Engineering Chemistry Research, 52(31), 10569-10581.
  • Mittal, A., Kaur, D. ve Mittal, J., 2009. Batch and bulk removal of a triarylmethane dye, Fast Green FCF, from wastewater by adsorption over waste materials, Journal of Hazardous Materials, 163(2), 568-577.
  • Mohammadi, A., Daemi, H. ve Barikani, M., 2014. Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles, International Journal of Biological Macromolecules, 69, 447-455.
  • Mudhakir, D., Wibisono, C. ve Rachmawati, H., 2014. Encapsulation of risperidone into chitosan-based nanocarrier via ionic binding interaction, Procedia Chemistry, 13, 92-100.
  • Pooralhossini, J., Ghaedi, M., Zanjanchi, M.A. ve Asfaram, A., 2017. Ultrasonically assisted removal of Congo red, Phloxine B and Fast green FCF in ternary mixture using novel nanocomposite following their simultaneous analysis by derivative spectrophotometry, Ultrasonics Sonochemistry, 37, 452-463.
  • Ramalakshmi, S., Muthuchelian, K. ve Swaminathan, K., 2012. Comparative Studies on Removal of Fast Green Dye from Aqueous Solutions by Activated Carbon Prepared from Gloriosa superba Waste and Altemaria raphani Fungal Biomass, Journal of Environmental Science and Technology, 5(4), 222-231.
  • Sirés, I., Guivarch, E., Oturan, N. ve Oturan, M.A., 2008. Efficient removal of triphenylmethane dyes from aqueous medium by in situ electrogenerated Fenton’s reagent at carbon-felt cathode, Chemosphere, 72(4), 592-600.
  • Subramani, S.E. ve Thinakaran, N., 2017. Isotherm, kinetic and thermodynamic studies on the adsorption behaviour of textile dyes onto chitosan, Process Safety and Environmental Protection, 106, 1-10.
  • Tahir, H., Hammed, U., Jahanzeb, Q. ve Sultan, M., 2008. Removal of fast green dye (CI 42053) from an aqueous solution using Azadirachta indica leaf powder as a lowcost adsorbent, African Journal of Biotechnology, 7(21), 3906-3911.
  • Tahir, H., Hammed, U., Sultan, M. ve Jahanzeb, Q., 2010. Batch adsorption technique for the removal of malachite green and fast green dyes by using montmorillonite clay as adsorbent, African Journal of Biotechnology, 9(48), 8206-8214.
  • Tirtom, V.N., Dinçer, A., Becerik, S., Aydemir, T. ve Çelik, A., 2012. Comparative adsorption of Ni (II) and Cd (II) ions on epichlorohydrin crosslinked chitosan–clay composite beads in aqueous solution, Chemical Engineering Journal, 197, 379-386.
  • Tsuji, S., Yoshii, K. ve Tonogai, Y., 2006. Identification of isomers and subsidiary colors in commercial Fast Green FCF (FD&C Green No. 3, Food Green No. 3) by liquid chromatography–mass spectrometry and comparison between amounts of the subsidiary colors by high-performance liquid chromatography and thin-layer chromatography-spectrophotometry, Journal of Chromatography A, 1101(1), 214-221.
  • Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z. ve Amouzgar, P., 2014. Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review, Carbohydrate Polymers, 113, 115-130.
  • Yu, F.Y., Li, C.W. ve Kang, S.F. 2005. Color, dye and DOC removal, and acid generation during Fenton oxidation of dyes, Environmental Technology, 26(5), 537-544.

Investigation Removal Effectiveness of Anionic Dyes via Encapsulation in Chitosan Nanoparticles Prepared by Ionotropic Gelation Method and the Dye Storage Performance in Nanoparticles

Year 2018, Volume: 8 Issue: 1, 26 - 37, 31.01.2018
https://doi.org/10.17714/gumusfenbil.307356

Abstract

The chitosan nanoparticles were prepared in solution medium containing
anionic dye (Fast Green FCF) with ionotropic interaction. The dye encapsulated
chitosan nanoparticles were characterized by SEM and Zeta-sizer. The effective
parameters for the removal of dye from aqueous medium and stability of trapping
in nanoparticles were investigated in different pH solutions. Fast Green FCF
was removed from the aqueous medium with an efficiency of over 90%. The amount
of trapped dye was determined as 1140 mg / g chitosan.

References

  • Abbasi, M., 2017. Synthesis and characterization of magnetic nanocomposite of chitosan/SiO2/carbon nanotubes and its application for dyes removal, Journal of Cleaner Production, 145, 105-113.
  • Agarwal, S., Gupta, V.K., Ghasemi. ve M., Azimi-Amin, J., 2017. Peganum harmala-L Seeds adsorbent for the rapid removal of noxious brilliant green dyes from aqueous phase, Journal of Molecular Liquids, 231, 296-305.
  • Agarwal, S., Tyagi, I., Gupta, V.K., Mashhadi, S. ve Ghasemi, M., 2016. Kinetics and thermodynamics of Malachite Green dye removal from aqueous phase using iron nanoparticles loaded on ash, Journal of Molecular Liquids, 223, 1340-1347.
  • Al Nafiey, A., Addad, A., Sieber, B., Chastanet, G., Barras, A., Szunerits, S. ve Boukherroub, R., 2017. Reduced graphene oxide decorated with Co3O4 nanoparticles (rGO-Co3O4) nanocomposite: A reusable catalyst for highly efficient reduction of 4-nitrophenol, and Cr (VI) and dye removal from aqueous solutions, Chemical Engineering Journal, 322, 375-384.
  • Aldana, A.A., González, A., Strumia, M.C. ve Martinelli, M., 2012. Preparation and characterization of chitosan/genipin/poly (N-vinyl-2-pyrrolidone) films for controlled release drugs, Materials Chemistry and Physics, 134(1), 317-324.
  • Alver, E. ve Metin, A.Ü., 2012. Anionic dye removal from aqueous solutions using modified zeolite: Adsorption kinetics and isotherm studies, Chemical Engineering Journal, 200, 59-67.
  • Alver, E., Bulut, M., Metin, A.Ü. ve Çiftçi, H., 2017. One step effective removal of Congo Red in chitosan nanoparticles by encapsulation, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 171, 132-138.
  • Alver, E., Metin, A.Ü. ve Çiftçi, H., 2014. Synthesis and characterization of chitosan/polyvinylpyrrolidone/zeolite composite by solution blending method, Journal of Inorganic and Organometallic Polymers and Materials, 24(6), 1048-1054.
  • Antoniou, J., Liu, F., Majeed, H., Qi, J., Yokoyama, W. ve Zhong, F., 2015. Physicochemical and morphological properties of size-controlled chitosan–tripolyphosphate nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 465, 137-146.
  • Bhati, I., Punjabi, P.B. ve Ameta, S.C., 2010. Photocatalytic degradation of fast green using nanosized CeCrO3, Macedonian Journal of Chemistry and Chemical Engineering, 29(2), 195-202.
  • Chen, C.Y., Chang, J.C. ve Chen, A.H., 2011. Competitive biosorption of azo dyes from aqueous solution on the templated crosslinkedchitosan nanoparticles, Journal of Hazardous Materials, 185, 430−441.
  • Chiou, M.S. ve Li, H.Y., 2003. Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads, Chemosphere, 50(8), 1095-1105.
  • Crini, G., 2006. Non-conventional low-cost adsorbents for dye removal: a review, Bioresource Technology, 97, 1061−1085.
  • De Moura, M.R., Aouada, F.A., Avena-Bustillos, R.J., McHugh, T.H., Krochta, J.M. ve Mattoso, L.H., 2009. Improved barrier and mechanical properties of novel hydroxypropylmethylcellulose edible films with chitosan/tripolyphosphate nanoparticles, Journal of Food Engineering, 92, 448–453.
  • Demir, A. ve Seventekin, N., 2009. Kitin, kitosan ve genel kullanım alanları, Tekstil Teknolojileri Elektronik Dergisi, 3(2), 92-103.
  • Geçer, A., Yıldız, N., Kavak, D. ve Çalımlı, A., 2009. Comparison of chitosan apatite composites synthesized by different methods, Polymer Composites, 30(3), 288-295.
  • George, M. ve Abraham, T.E., 2006. Polyionic hydrocolloids for the intestinal delivery ofprotein drugs: alginate and chitosan—a review, Journal of Controlled Release, 114, 1–14.
  • Gonçalves, J.O., Santos, J.P., Rios, E.C., Crispim, M.M., Dotto, G.L. ve Pinto, L.A.A., 2017. Development of chitosan based hybrid hydrogels for dyes removal from aqueous binary system, Journal of Molecular Liquids, 225, 265-270.
  • Gong, R., Ding, Y., Li, M., Yang, C., Liu, H. ve Sun, Y., 2005. Utilization of powdered peanut hull as biosorbent for removal of anionic dyes from aqueous solution, Dyes and Pigments, 64(3), 187-192.
  • Gupta, V.K., Ali, I. ve Saini, V.K., 2004. Removal of rhodamine B, fast green, and methylene blue from wastewater using red mud, an aluminum industry waste, Industrial & Engineering Chemistry Research, 43(7), 1740-1747.
  • Gupta, V.K., Ali, I., Saini, V.K., Van Gerven, T., Van der Bruggen, B. ve Vandecasteele, C., 2005. Removal of dyes from wastewater using bottom ash. Industrial & Engineering Chemistry Research, 44(10), 3655-3664.
  • Hashemian, S. ve Foroghimoqhadam, A., 2014. Effect of copper doping on CoTiO 3 ilmenite type nanoparticles for removal of congo red from aqueous solution, Chemical Engineering Journal, 235, 299-306.
  • Huang, R., Liu, Q., Huo, J. ve Yang, B., 2017. Adsorption of methyl orange onto protonated cross-linked chitosan, Arabian Journal of Chemistry, 10(1), 24-32.
  • Kumar, A., Paliwal, M., Ameta, R. ve Ameta, S.C., 2008. Oxidation of fast green FCF by the solar photo-Fenton process, Journal of the Iranian Chemical Society, 5(2), 346-351.
  • Kumari, H.J., Krishnamoorthy, P., Arumugam, T.K., Radhakrishnan, S. ve Vasudevan, D., 2017. An efficient removal of crystal violet dye from waste water by adsorption onto TLAC/Chitosan composite: A novel low cost adsorbent, International Journal of Biological Macromolecules, 96, 324-333.
  • Marrakchi, F., Ahmed, M.J., Khanday, W.A., Asif, M. ve Hameed, B.H., 2017. Mesoporous-activated carbon prepared from chitosan flakes via single-step sodium hydroxide activation for the adsorption of methylene blue, International Journal of Biological Macromolecules, 98, 233-239.
  • Metin, A.Ü. ve Alver, E., 2016. Fibrous polymer-grafted chitosan/clay composite beads as a carrier for immobilization of papain and its usability for mercury elimination, Bioprocess and Biosystems Engineering, 39(7), 1137-1149.
  • Metin, A.Ü., Çiftçi, H. ve Alver, E., 2013. Efficient removal of acidic dye using low-cost biocomposite beads, Industrial & Engineering Chemistry Research, 52(31), 10569-10581.
  • Mittal, A., Kaur, D. ve Mittal, J., 2009. Batch and bulk removal of a triarylmethane dye, Fast Green FCF, from wastewater by adsorption over waste materials, Journal of Hazardous Materials, 163(2), 568-577.
  • Mohammadi, A., Daemi, H. ve Barikani, M., 2014. Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles, International Journal of Biological Macromolecules, 69, 447-455.
  • Mudhakir, D., Wibisono, C. ve Rachmawati, H., 2014. Encapsulation of risperidone into chitosan-based nanocarrier via ionic binding interaction, Procedia Chemistry, 13, 92-100.
  • Pooralhossini, J., Ghaedi, M., Zanjanchi, M.A. ve Asfaram, A., 2017. Ultrasonically assisted removal of Congo red, Phloxine B and Fast green FCF in ternary mixture using novel nanocomposite following their simultaneous analysis by derivative spectrophotometry, Ultrasonics Sonochemistry, 37, 452-463.
  • Ramalakshmi, S., Muthuchelian, K. ve Swaminathan, K., 2012. Comparative Studies on Removal of Fast Green Dye from Aqueous Solutions by Activated Carbon Prepared from Gloriosa superba Waste and Altemaria raphani Fungal Biomass, Journal of Environmental Science and Technology, 5(4), 222-231.
  • Sirés, I., Guivarch, E., Oturan, N. ve Oturan, M.A., 2008. Efficient removal of triphenylmethane dyes from aqueous medium by in situ electrogenerated Fenton’s reagent at carbon-felt cathode, Chemosphere, 72(4), 592-600.
  • Subramani, S.E. ve Thinakaran, N., 2017. Isotherm, kinetic and thermodynamic studies on the adsorption behaviour of textile dyes onto chitosan, Process Safety and Environmental Protection, 106, 1-10.
  • Tahir, H., Hammed, U., Jahanzeb, Q. ve Sultan, M., 2008. Removal of fast green dye (CI 42053) from an aqueous solution using Azadirachta indica leaf powder as a lowcost adsorbent, African Journal of Biotechnology, 7(21), 3906-3911.
  • Tahir, H., Hammed, U., Sultan, M. ve Jahanzeb, Q., 2010. Batch adsorption technique for the removal of malachite green and fast green dyes by using montmorillonite clay as adsorbent, African Journal of Biotechnology, 9(48), 8206-8214.
  • Tirtom, V.N., Dinçer, A., Becerik, S., Aydemir, T. ve Çelik, A., 2012. Comparative adsorption of Ni (II) and Cd (II) ions on epichlorohydrin crosslinked chitosan–clay composite beads in aqueous solution, Chemical Engineering Journal, 197, 379-386.
  • Tsuji, S., Yoshii, K. ve Tonogai, Y., 2006. Identification of isomers and subsidiary colors in commercial Fast Green FCF (FD&C Green No. 3, Food Green No. 3) by liquid chromatography–mass spectrometry and comparison between amounts of the subsidiary colors by high-performance liquid chromatography and thin-layer chromatography-spectrophotometry, Journal of Chromatography A, 1101(1), 214-221.
  • Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z. ve Amouzgar, P., 2014. Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review, Carbohydrate Polymers, 113, 115-130.
  • Yu, F.Y., Li, C.W. ve Kang, S.F. 2005. Color, dye and DOC removal, and acid generation during Fenton oxidation of dyes, Environmental Technology, 26(5), 537-544.
There are 41 citations in total.

Details

Subjects Engineering
Journal Section Articles
Authors

Erol Alver

Publication Date January 31, 2018
Submission Date April 20, 2017
Acceptance Date September 27, 2017
Published in Issue Year 2018 Volume: 8 Issue: 1

Cite

APA Alver, E. (2018). İyonotropik Jelleşme Yöntemi ile Hazırlanan Kitosan Nanopartiküllerde Hapsetme (Enkapsülasyon) ile Anyonik Boyaların Uzaklaştırılma ve Hapsedilen Boyanın Nanopartikülde Depolanma Etkinliğinin Araştırılması. Gümüşhane Üniversitesi Fen Bilimleri Dergisi, 8(1), 26-37. https://doi.org/10.17714/gumusfenbil.307356