Metilen Mavisinin Doğal Kil Üzerine Adsorpsiyonu

Year 2018, Volume: 8 Issue: 2, 264 - 272, 31.07.2018

Serkan Bayar

https://doi.org/10.17714/gumusfenbil.344748

Cited By: 2

Abstract

Bu çalışmada,
kesikli sistem adsorpsiyon prosesi ile sentetik olarak hazırlanan sulu
çözeltilerden metilen mavisi (MM) boyar maddesinin uzaklaştırılmasında Erzurum
ili Narman ilçesinden temin edilen doğal kilin kullanılabilirliği
araştırılmıştır. Deneysel parametreler olarak; pH (3.0 – 8.0 aralığı),
karıştırma hızı (100 devir/dakika - 400 devir/dakika aralığı), başlangıç boyar
madde konsantrasyonu (25 mg.L^-1- 500 mgL^-1 aralığı), adsorban dozajı (0.025 g 100 mL^-1
– 0.100 g.100 mL^-1 aralığı) ve NaCl konsantrasyonu (0 mM – 0.001 mM
aralığı) seçilmiştir. Çalışmalarda adsorpsiyon veriminin artan başlangıç MM
konsantrasyonu, pH ve karıştırma hızı ile arttığı, NaCl konsantrasyonu ve
adsorban dozajı ile azaldığı tespit edilmiştir. Çalışmalar sonucunda doğal
kilin en yüksek adsorpsiyon kapasitesinin 25 ºC’de, 300 devir/dakika karıştırma
hızında, çözelti doğal pH değerinde ve 500 mg.L^-1 MM
konsantrasyonunda 338.15 mg.g^-1olduğu tespit edilmiştir. 

Keywords

Adsorpsiyon, Kil, Kimyasal Oksijen İhtiyacı, Metilen Mavisi

Adsorption of Methylene Blue onto Natural Clay

Abstract

In this study,
the utilization of natural clay obtained from the Narman district of Erzurum
province was investigated in the removal of methylene blue (MB) from
synthetically prepared aqueous solutions by batch adsorption process. As
experimental parameters; the influences of initial pH of solution (from 3.0 to
8.0), stirring speed (from 100 to 400 rpm), initial dyestuff concentration  (from 25 mg.L^-1 to 500 mg.L^-1),
adsorbent dosage (from 0.025 g.100mL^-1 to 0.100 g.100mL^-1)
and NaCl concentration (from 0 to 0.001 mM) were selected. It was established that adsorption amount
increased with increasing pH, dye concentration and stirring speed, but
decreased with increased ionic strength and adsorbent dosage. As a result of working, the highest
adsorption capacity of natural clay was observed as 338.15 mg.g ^-1at
25 °C, at a stirring speed of 300 rpm, at a solution of natural pH and at a initial
MB concentration of 500 mg.L^-1.

Keywords

Adsorption, Clay, Chemical Oxygen Demand, Methylene Blue

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