Free-standing and Flexible MnO2/Graphene Paper Electrode: A Novel Amperometric Sensor for Dopamine Detection

Year 2020, Volume: 10 Issue: 1, 22 - 34, 15.01.2020

Ezgi Topçu

https://doi.org/10.17714/gumusfenbil.562555

Abstract

In this study, free-standing
MnO₂ coated reduced graphene oxide (MnO₂/rGO) paper with
high flexibility and durability was prepared. As-prepared MnO₂/rGO
paper was characterized by scanning electron microscopy-energy-dispersive X-ray
spectroscopy (SEM-EDS), X-ray diffraction spectroscopy (XRD), X-ray
photoelectron spectroscopy (XPS) and Raman spectroscopy. The electrochemical
behavior of dopamine (DA) was investigated on flexible MnO₂/rGO
paper with cyclic voltammetry and amperometry methods. Electrochemical results
have shown that the flexible MnO₂/rGO paper electrode exhibits
excellent electrocatalytic activity to DA due to its high specific surface
area. In addition, the obtained flexible electrochemical sensor showed a wide
linear range, a low detection limit and a very sensitive response for the amperometric
determination of DA.

Keywords

Amperometric sensor, Dopamine, Graphene paper, MnO2

Serbest Duran ve Esnek MnO2/Grafen Kağıt Elektrot: Dopamin Tayini İçin Yeni Tip Amperometrik Sensör

Abstract

Bu
çalışmada, serbest duran, yüksek esneklik ve dayanıklılık özelliğine sahip, yüzeyi
MnO₂ kaplı indirgenmiş grafen oksit (MnO₂/rGO) kağıt
hazırlanmıştır. Elde edilen MnO₂/rGO kağıt, taramalı elektron
mikroskobu-enerji dağılımlı X-ışını spektroskopisi (SEM-EDS), X-ışını kırınım
spektroskopisi (XRD), X-ışını foto elektron spektroskopisi (XPS) ve Raman
spektroskopisi gibi teknikler ile karakterize edilmiştir. Dopaminin (DA)
elektrokimyasal davranışı, esnek MnO₂/rGO kağıt üzerinde, dönüşümlü
voltametri ve amperometri metotları ile incelenmiştir. Elektrokimyasal sonuçlar,
esnek MnO₂/rGO kağıt elektrotun yüksek spesifik yüzey alanına sahip
olmasından dolayı, DA'ya karşı mükemmel elektrokatalitik aktivite sergilediğini
göstermiştir. Ayrıca, elde edilen esnek elektrokimyasal sensör, DA'nın amperometrik
tayininde; geniş bir doğrusal aralık, düşük tayin sınırı ve oldukça hassas tepki
göstermiştir.

Keywords

Amperometrik sensör, Dopamin, Grafen kağıt, MnO2

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