Yabani kuşburnu ağacı talaşının sodyum hidroksit impregnasyonuyla elde edilen aktif karbon kullanılarak kinolin sarısı boyar maddesinin sulu çözeltilerden giderimi

Year 2022, Volume: 12 Issue: 1, 101 - 118, 15.01.2022

İlyas Genel , Yaşar Genel

https://doi.org/10.17714/gumusfenbil.979439

Abstract

Bu çalışmada Van ili ve çevrelerinde yetişen yabani kuşburnu ağacından elde edilen talaşlar aktif karbon üretiminde kullanılmıştır. Aktif karbon üretiminde yabani kuşburnu ağaç talaşına (hammadde) NaOH (sodyum hidroksit) ile 1:1 oranında impregnasyon işlemi uygulanmış ve de azot gazı ortamında 800 ℃ piroliz edilmiştir. Üretilen aktif karbonun Langmuir yüzey alanı 1564.3621 m2/g olarak bulunmuştur. Elde edilen bu aktif karbonun gıda üretimde de kullanımı olan ve katyonik bir boyarmadde olan kinolin sarısının sıcaklık, konsantrasyon ve doğal pH’sında (pH:6.02) adsorpsiyonu incelenmiştir. Üretilen aktif karbon tarafından maksimum kinolin sarısı adsorpsiyonu belirlenerek, Langmuir, Freundlich, temkin ve D-R adsorpsiyon izoterm modellerine göre uyumu gözlenmiştir. R2=0.996 değerine sahip Langmuir adsorpsiyon izotermiyle uyumlu olduğu görülmüştür. Kinetik model olarak; yalancı birinci derece kinetik modeli, yalancı ikini derece kinetik modeli, elovich ve interpartiküler kinetik modellerinin uyumluluğuna bakılmış ve adsorpsiyonun yalancı ikinci dereceden kinetik modeline uyumlu olduğu belirlenmiştir. Çalışmada konsantrasyon ölçümleri UV spektrofotometre ile yapılmıştır. Adsorpsiyon denge verilerinde adsorplanan en yüksek değer 245.6885 mg/g bulunmuştur. Üretilen aktif karbonun sulu çözeltilerden kinolin boyarmaddesinde gideriminde kullanılabilir niteliktedir.

Keywords

Adsorpsiyon, Aktif karbon, İmpregnasyon, Yabani kuşburnu ağacı

Removal of quinoline yellow dyestuff from aqueous solutions using activated carbon obtained by sodium hydroxide ımpregnation of wild rosehip wood sawdust

Abstract

In this study, wild rosehip tree shavings that can be grown in Van and its region were used in the production of activated carbon. In the production of activated carbon, wild rosehip wood sawdust (raw material) was impregnated with NaOH (sodium hydroxide) at a ratio of 1:1 and pyrolyzed at 800 ℃ in a nitrogen gas environment. The Langmuir surface area of the produced activated carbon was found to be 1564.3621 m2/g. The adsorption of quinoline yellow, a cationic dyestuff, which is also used in food production as an adsorbed substance, at temperature, concentration and natural pH (pH:6.02) was investigated. Maximum quinoline yellow adsorption was determined by the produced activated carbon and its compatibility was observed according to Langmuir, Freundlich, Temkin and D-R adsorption isotherm models. It was found to be compatible with the Langmuir adsorption isotherm with R2=0.996. As a kinetic model; The compatibility of the pseudo-first-order kinetic model, pseudo-second-order kinetic model, elovich and interparticular kinetic models was examined and it was determined that adsorption was compatible with the pseudo-second-order kinetic model. In the study, concentration measurements were made with UV spectrophotometer. The highest adsorbed value in the adsorption equilibrium data was found to be 245.6885 mg/g. It is thought that the produced activated carbon can be used for dye removal from aqueous solutions.

Keywords

Adsorption, Activated carbon, Impregnation, Wild rosehip tree

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