New Mixed Ni(II), Cu(II), and Co(II) Complexes derived from 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-Phenanthroline: Synthesis and Characterization

Year 2023, Volume: 13 Issue: 2, 350 - 358, 15.04.2023

Hatice Gamze Soğukömeroğulları , Ahmet Oral Sarıoğlu

https://doi.org/10.17714/gumusfenbil.1179269

Cited By: 1

Abstract

Three new mixed Ni(II), Co(II) and Cu(II) complexes have been created using 2-((2-mercaptophenylimino)methyl)-4-methoxyphenol and 1,10-phenanthroline. FT-IR, Elemental analysis, magnetic susceptibility, UV-Vis and molar conductivity technique have all been used to explore the structural characterisation of these compounds. Magnetic susceptibility readings for the L-Cu, L-Ni, and L-Co complexes were 1.97 BM, 2.92 BM, and 2.84 BM, respectively. The L-Co complex is thought to be antiferromagnetic. The structures of the mixed ligand metal complexes are thought to be octahedral geometry. There are no conductivity properties in the complexes; however, they exhibit molar conductivities that range from 2.46 to 9.04 µS/cm.

Keywords

Schiff base, Mixed Ligand Metal complex, 1,10-phenantroline, characterization

Thanks

The authors would like to thank Mehmet Sönmez for his kind technical assistance.

2-((2-merkaptofenilimino)metil)-4-metoksifenol ve 1,10-fenantrolinden Türetilen Yeni Karışık Ni(II), Cu(II) ve Co(II) Kompleksleri: Sentez ve Karakterizasyon

Abstract

2-((2-merkaptofenilimino)metil)-4-metoksifenol ve 1,10-fenantrolinden üç yeni karışık Ni(II), Co(II) ve Cu(II) kompleksi sentezlenmiştir. Bu bileşiklerin yapısal karakterizasyonu, FT-IR, elementel analiz, manyetik duyarlılık, UV-Vis ve molar iletkenlik teknikleri kullanılarak araştırılmıştır. Manyetik duyarlılık ölçümleri L-Cu, L-Ni ve L-Co kompleksleri için sırasıyla 1.97 BM, 2.92 BM, ve 2.84 BM olarak kaydedilmiştir. L-Co kompleksinin antiferromanyetik özellikte olduğu düşünülmektedir. Karışık ligand metal komplekslerinin yapılarının oktahedral geometriye sahip olduğu düşünülmektedir. Komplekslerin molar iletkenlik değerleri 2.46-9.04 μS/cm arasında olduğundan dolayı iletkenlik göstermemektedir.

Keywords

Karışık Ligand Metal kompleksi, Schiff baz, 1,10-fenantrolin, karakterizasyon

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