The investigation of fuel properties of mixtures obtained by adding waste sunflower biodiesel and ethanol to euro diesel fuel

Year 2021, Volume: 10 Issue: 2, 91 - 99, 14.10.2021

Fatih Aydın

https://doi.org/10.18245/ijaet.874772

Abstract

Energy production from waste in the world will be an indispensable factor for the future of countries. Countries that can produce their own energy in the world will be superior to other countries. In this study, waste sunflower oil was converted to methyl ester by transesterification method and biodiesel was produced. A Ternary mixture was made from biodiesel, ethanol and euro diesel fuel obtained from waste sunflower oil and test fuels were produced in the forms of D90B5E5, D80B10E10, D70B15E15 and D60B20E20. The kinematic viscosities of the test fuels at 40 0C, density, water contents, pH values, color specifications, calorific values, cloud points, yield points, freezing, copper strip corrosion tests, CFPP tests and cetane index tests were carried out and fuel properties were determined. As a result of the tests, it was found out that the most suitable engine fuel mixture was D90B5E5. It can be used for internal combustion engines by adding ethanol to the Biodiesel – Euro diesel fuel mixture and in this way, an environmentally friendly fuel mixture is obtained and energy conversion is achieved from waste.

Keywords

Biodiesel, Ethanol, Euro diesel, Fuel mixtures, Waste sunflower oil

References

• Rodrigues, J.S., Valle, C.P., Uchoa, A.F.J., Ramos, D.M., Ponte, F.A.F., Rios, M.A.S., Malveria, J.Q. and Ricardo, N.M.P., (2020), Comparative Study of Synthetic and Natural Antioxidants on Theoxidative Stability of Biodiesel from Tilapia Oil, Renewable Energy, Volume 156, Pages 1100-1106.
• Ryan L., Convery F. and Ferreira S., (2006), Stimulating the Use of Biofuels in the European Union: Implications for Climate Change Policy, Energy Policy, Volume 34, Issue 17, Pages 3184–3194.
• Madheshiya, A. K. and Vedrtnam, A., (2018), Energy Exergy Analysis of Biodiesel Fuels Produced from Waste Cooking Oil and Mustard Oil, Fuel, 214, 386–408.
• Carraretto, C., Macor. A., Mirandola, A., Stoppato, A. and Tonon, S., (2004), Biodiesel as alternative fuel: Experimental analysis and energetic evaluations, Energy, Volume 29, Issues 12–15, Pages 2195-2211.
• Granados, M.L., Poves, M.,D., Z., Alonso, D., M., Mariscal, R., Galisteo, F., C., Tost, R.M., Santamarı, J. and Fierro, J.L.G., (2007), Biodiesel from sunflower oil by using activated calcium oxide, Applied Catalysis B: Environmental, Volume 73, Pages 317–326.
• Ray, S. K., and Prakash, O. (2019). Biodiesel Extracted from Waste Vegetable Oil as an Alternative Fuel for Diesel Engine: Performance Evaluation of Kirlosker 5 kW Engine. Singapore: Springer.
• Kirubakaran, M., and Selvan, V. A. M. (2018). A comprehensive review of low cost biodiesel production from waste chicken fat. Renew. Sus. Ener. Rev. 82, 390–401. Doi: 10.1016/j.rser.2017.09.039.
• Hosseini, S. E., and Wahid, M. A. (2012). Necessity of biodiesel utilization as a source of renewable energy in Malaysia. Renew. Sustain. Energy Rev. 16, 5732–5740. Doi: 10.1016/j.rser.2012.05.025.
• Palani, S., Srinivasan, G. R., and Ranjitha, J. (2017). Biodiesel production from the seeds of Mimusops elengi using potassium aluminium silicate as novel catalyst. Inno. Ener. Res. 6:165. doi: 10.4172/2576-1463.1000165.
• Tran, N. N., Tišma, M., Budžaki, S., McMurchie, E. J., Gonzalez, O. M. M., Hessel, V., et al. (2018). Scale-up and economic analysis of biodiesel production from recycled grease trap waste. App. Energ. 229, 142–150. doi: 10.1016/j.apenergy.2018.07.106.
• Jambulingam R., Shankar V., Palani S. and Srinivasan G.R., (2019), Effect of Dominant Fatty Acid Esters on Emission Characteristics of Waste Animal Fat Biodiesel in CI Engine, Front. Energy Res. https://doi.org/10.3389/fenrg.2019.00063.
• Graboski, M.S. and McCormick, R., L., (1998), Combustion of fat and vegetable oil derived fuels in diesel engines, Progress in Energy and Combustion Science, Volume 24, Issue 2, Pages 125-164.
• Nystrom, R., Sadiktsis, I., Ahmed, T. M., Westerholm, R., Koegler, J.H., Blomberg, A., Sandstrom, T. and Boman, C., (2016), Physical and Chemical Properties of RME Biodiesel Exhaust Particles without Engine Modifications, Fuel, 186, 261-269.
• Otchere, P., Pan, J., Fan, B., Chen, W. and Lu, Y., (2021), Recent Studies of Fuels Used in Wankel Rotary Engines, Journal of Energy Resources Technology, 143(3): 030801.
• Karaosmanoglu F., Kurt G. and Ozaktas T., (2000), Direct Use of Sunflower Oil as a Compression Ignition Engine Fuel, Energy Sources, 22, 659–672.
• Canakci M. and Van Gerpen J. H., (2001), Biodiesel Production from Oils and Fats With High Free Fatty Acids, Transaction of the ASAE, Vol,44 (6), 1429–1436.
• Hajjari, M., Tabatabaei, M., Aghbashlo, M. and Ghanavati, H., (2017), A Review on the Prospects of Sustainable Biodiesel Production: A Global Scenario with an Emphasis on Waste-Oil Biodiesel Utilization, Renewable and Sustainable Energy Reviews, Volume 72, Pages 445–464.
• Yesilyurt, M.K. and Arslan, M., (2019), Analysis of the fuel injection pressure effects on energy and exergy efficiencies of a diesel engine operating with biodiesel, Biofuels, Volume 10, Number 5, Pages 643–655.
• Babazadeh, R., (2017), Optimal Design and Planning of Biodiesel Supply Chain Considering Non-Edible Feedstock, Renewable and Sustainable Energy Reviews, Volume 75, Pages 1089–1100.
• Mahmudul H.M., Hagos F.Y., Mamat, R., Abdul Adam, A., Ishak, W.F.W. and Alenezi, R., (2017), Production, Characterization and Performance of Biodiesel as an Alternative Fuel in Diesel Engines–A Review, Renewable and Sustainable Energy Reviews, Volume 72, Pages 497–509.
• Speight J.G., (2019), Handbook of Industrial Hydrocarbon Processes, Second Edition, Gulf Professional Publishing, Elsevier, Oxford, United Kingdom, Hydrocarbons from Crude Oil, Chapter 3, Page 125.
• Bertoli C., Del Giacomo N. and Beatrice C., (1997), Diesel Combustion Improvements by the Use of Oxygenated Synthetic Fuels, Society of Automotive Engineers, 972972.
• Miyamoto N., Ogawa H., Nurun N.A., Obata K. and Arima T., (1998), Smokeless, Low NOx, High Thermal Efficiency, and Low Noise Diesel Combustion with Oxygenated Agents as Main Fuel, Society of Automotive Engineers 980506.
• Nabi N., Shahadat M., Z., Rahman S. and Beg R., A.. (2004), Behavior of Diesel Combustion and Exhaust Emission with Neat Diesel Fuel and Diesel Biodiesel Blends, Society of Automotive Engineers 01-3034.
• Dorado M., P., Ballesteros E., Arnal J., Gomez J. and Gimenez F., J., L., (2003 a), Testing Waste Olive Oil Methyl Ester as a Fuel in a Diesel Engine, Energy Fuel, 17(6):1560–1565.
• Dorado M.P., Ballesteros E., Arnal J., Gomez J. and Lopez F., (2003 b), Exhaust Emissions from a Diesel Engine Fueled With Transesterified Waste Olive Oil, Fuel, 82(11): 1311–1315.
• Goyal P., Sharma M.P. and Jain S., (2013), Optimization of Transesterification of Jatropha Curcas Oil to Biodiesel using Response Surface Methodology and its Adulteration with Kerosene, Journal of Materials and Environmental Science, Volume 4, Number 2, Pages 277–284.
• Jeyalakshmi P. and Subramanian R., (2013), The Application of Response Surface 28ethodology for the Optimization of Pretreatment Process Parameters of Paradise Seed (Simarouba Glauca) Oil, Energy Source Part A: Recovery, Utilization, and Environmental Effects, Volume 35, Issue 22, Pages 2087–2095.
• Bayindirli, C. and Celik, M., (2019), Investigation of combustion and emission characteristics of n-hexane and n-hexadecane additives in diesel fuel, Journal of Mechanical Science and Technology, Volume 33, Issue 4, Pages 1937-1946.
• Çelik, M., Örs, İ., Bayindirli, C. and Demiralp, M., (2017), Experimental investigation of impact of addition of bioethanol in different biodiesels, on performance, combustion and emission characteristics, Journal of Mechanical Science and Technology, Volume 31, Issue 11, Pages 5581-5592.
• Teoh, Y.H., Yu, K.H., How, H.G. and Nyugen, H.T., (2019), Experimental Investigation of Performance, Emission and Combustion Characteristics of a Common-Rail Diesel Engine Fuelled with Bioethanol as a Fuel Additive in Coconut Oil Biodiesel Blends, Energies Volume 12, Issue 10, 1954, Pages 1-17.