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Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması

Year 2013, Volume: 2 Issue: 3, 85 - 91, 20.04.2013

Hülya Karabaş

Abstract

The production of biodiesel fuel from crude canola oil was evaluated in this study. The process of alkali-catalyzed transesterification with methanol was carried out to examine the effects of reaction variables on the formation of methyl ester: variables which included alcohol:oil molar ratios of 3:1, 6:1, 8:1,10:1, catalyst concentrations of 0.5, 1, 1.5, 2% w/w of oil, reaction temperatures of 30, 40, 50, 60oC, and reaction times of 10, 20, 40, 60 min. The methyl ester yield from each reaction condition is calculated. The optimum conditions for transesterification of canola oil with methanol and KOH as catalyst were found to be 50oC reaction temperature, 1 h reaction time, 8:1 molar ratio of canola oil to methanol and 1% catalyst (w/w). The resultant methyl ester content of 98%, plus all of the other measured properties of the canola biodiesel, met the international standards EN 14214.

Özet: Bu çalışmada ham kanola yağından biyodizel yakıt üretimi değerlendirilmiştir. Metanol ile, alkali katalizörlü transesterifikasyon işlemi reaksiyon değişkenlerin etkisini incelemek için gerçekleştirildi: metil ester oluşumu: alkol dahil değişkenler: : yağ mol oranları: 3: 1, 6: 1, 8: 1,10: 1, katalizör konsantrasyonu, % 0.5, 1, 1.5, 2 ağırlık / yağın ağırlığı, reaksiyon sıcaklıkları, 30, 40, 50, 60 oC ve reaksiyon süreleri 10, 20, 40, 60 dakika. Her bir reaksiyon koşulundan metil ester verimi hesaplanır. Katalizör olarak metanol ve KOH ile kanola yağı transesterifikasyonu için optimum koşullar 50 ° C reaksiyon sıcaklığı, 1 saat reaksiyon süresi, 8:1 metanole kanolanın mol oranı ve % 1 (ağırlık / ağırlık) katalizörüdür. Sonuçta % 98 metil ester içeriği ve kanola biyodizelinin diğer ölçülen tüm özellikleri, EN 14214 uluslararası standartlara uygundur.

Keywords

Canola oil methyl ester transesterification optimum condition / Kanola yağı metil ester transesterifikasyon en iyi koşul

References

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  • Rashid, U, F. Anwar, B.R. Moser, S. Ashraf. Production of sunflower oil methyl esters by optimized alkali- catalyzed Bioenergy, 32: 1202–1205, 2008. Biomass
  • Anwar, F, U. Rashid, M. Ashraf, M. Nadeem. Okra (Hibiscus esculentus) seed oil for biodiesel production. Applied Energy, 87: 779-785, 2010.
  • Dorado, M.P, E. Ballesteros, F.J. Lopez, M. Mittelbach. Optimization of alkalicatalyzed transesterification of Brassica carinata oil for biodiesel production. Energy Fuels, 18: 77–83, 2004.
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Year 2013, Volume: 2 Issue: 3, 85 - 91, 20.04.2013

Hülya Karabaş

Abstract

References

  • Srivastava, A. and R. Diesel fuels. Energy Renewable Review, 4: 111–133, 2000.
  • Usta, N. Use of tobacco seed oil methyl ester in a turbocharged indirect injection Bioenergy, 28: 77–86, 2005. engine. Biomass N. and S. Wootthikanokkhan. Roselle (Hibiscus sabdariffa L.) oil as an alternative feedstock for biodiesel production in Thailand. Fuel, 89: 1806–1811, 2010.
  • Meher, L.C, V.S.S. Dharmagadda, S.N. Naik. Optimization of alkali-catalyzed transesterification of Pongamia pinnata oil Bioresour Technology, 97: 1392–1397, 2006. of biodiesel.
  • Canakci, M, G.and Van Gerpen. Biodiesel production via acid catalysis. Trans ASAE, 42:1203–1210, 1999.
  • Freedman, B, E.H. Pryde, T.L. Mounts. Variables affecting the yields of fatty esters from transesterified vegetable oils. J Am Chem Soc, 61(10): 1638– 1643, 1984.
  • Shailendra, S, A.K. Agarwal, S. Garg. Biodiesel development from rice bran oil: optimization and fuel characterization. Energy Conversion and Management, 49: 1248–1257, 2008. process
  • Peterson, C.L, G.L. Wagner, D.L. Auld. Vegetable oil substitution for Diesel fuel. Trans ASAE, 26: 322–327, 1983.
  • Ma, F. and M.A. Hanna. Biodiesel production: A review. Bioresource Technology, 70: 1–15, 1999.
  • Van Gerpen, J. Biodiesel processing and Technology, 86: 1097–1107, 2005.
  • Cantrell, D.G, L.J. Gillie, A.F. Lee, K. Wilson. correlations in MgAl hydrotalcite catalysts for biodiesel synthesis. Appl Catal A, 287: 183–190, 2005.
  • Ghadge, S.V. and H. Raheman. Biodiesel production from mahua (Madhuca indica) oil having high free fatty acids. Biomass Bioenergy, 28: 601–605, 2005.
  • Rashid, U, F. Anwar, B.R. Moser, S. Ashraf. Production of sunflower oil methyl esters by optimized alkali- catalyzed Bioenergy, 32: 1202–1205, 2008. Biomass
  • Anwar, F, U. Rashid, M. Ashraf, M. Nadeem. Okra (Hibiscus esculentus) seed oil for biodiesel production. Applied Energy, 87: 779-785, 2010.
  • Dorado, M.P, E. Ballesteros, F.J. Lopez, M. Mittelbach. Optimization of alkalicatalyzed transesterification of Brassica carinata oil for biodiesel production. Energy Fuels, 18: 77–83, 2004.
  • Marchetti, J.M, V.U. Miguel, A.F. Errazu. Possible methods for biodiesel production. Energy Review, 11: 1300–1311, 2007. Sustainable
There are 15 citations in total.

Details

Primary Language English
Journal Section Article
Authors

Hülya Karabaş

Publication Date April 20, 2013
Submission Date April 20, 2013
Published in Issue Year 2013 Volume: 2 Issue: 3

Cite

APA Karabaş, H. (2013). Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması. International Journal of Automotive Engineering and Technologies, 2(3), 85-91.
AMA Karabaş H. Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması. International Journal of Automotive Engineering and Technologies. October 2013;2(3):85-91.
Chicago Karabaş, Hülya. “Investigation of Biodiesel Fuel from Canola Oil Using Various Reaction Parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması”. International Journal of Automotive Engineering and Technologies 2, no. 3 (October 2013): 85-91.
EndNote Karabaş H (October 1, 2013) Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması. International Journal of Automotive Engineering and Technologies 2 3 85–91.
IEEE H. Karabaş, “Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması”, International Journal of Automotive Engineering and Technologies, vol. 2, no. 3, pp. 85–91, 2013.
ISNAD Karabaş, Hülya. “Investigation of Biodiesel Fuel from Canola Oil Using Various Reaction Parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması”. International Journal of Automotive Engineering and Technologies 2/3 (October 2013), 85-91.
JAMA Karabaş H. Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması. International Journal of Automotive Engineering and Technologies. 2013;2:85–91.
MLA Karabaş, Hülya. “Investigation of Biodiesel Fuel from Canola Oil Using Various Reaction Parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması”. International Journal of Automotive Engineering and Technologies, vol. 2, no. 3, 2013, pp. 85-91.
Vancouver Karabaş H. Investigation of biodiesel fuel from canola oil using various reaction parameters / Farklı Reaksiyon Parametreleri Kullanılarak Kanola Yağından Biyodizelin Araştırılması. International Journal of Automotive Engineering and Technologies. 2013;2(3):85-91.