Research Article

Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation

Volume: 4 Number: 1 June 30, 2020
EN

Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation

Abstract

Copper oxide nanoparticles (CuO NPs) were produced using green synthesis method with Cimin grape extract (Vitis vinifera cv.). The produced CuO NPs were used to remove methylene blue (MB) from water by degradation with Fenton-like reactions. The surface properties of the CuO NPs were determined by FT-IR, SEM and XRD techniques. Experimental parameters for MB removal were selected as: pH: 3 – 11; Temp: 20 - 80°C; initial MB concentration (15 - 50 ml-1), and CuO NPs concentrations (25 - 800 mg ml-1). The best reaction conditions were found to be pH: 7 - 11, temperature: 40 - 45C, interaction time: 120 min, initial MB concentration: 3.125 mg ml-1 and CuO NPs concentration: 25 mg ml-1. Under these conditions, CuO NPs showed a 97.80% efficacy for the removal of MB from wastewater with Fenton-like process. Moreover, this study showed that reagents were reusable, inexpensive, biocompatible, easy to prepare, harmless (CuO NPs, H2O2), and Fenton-like reaction conditions were created. 

Keywords

References

  1. 1. Sen, T. Int. J. Environ. Pollut. Control Manage. 2011, 3 (1), 1-10.
  2. 2. Bombardelli, E.; Morazzoni, P. Fitoterapia (Milano). 1995, 66 (4), 291-317.
  3. 3. Fan, P.; Lou, H.; Yu, W.; Ren, D.; Ma, B.; Ji, M. Tetrahedron Lett. 2004, 45 (15), 3163-3166.
  4. 4. Królikowska, A.; Kudelski, A.; Michota, A.; Bukowska. J. Surf. Sci. 2003, 532, 227-232.
  5. 5. Catauro, M.; Raucci, M. G.; De Gaetano, F.; Marotta, A. J. Mater. Sci-Mater. M. 2004, 15 (7), 831-837.
  6. 6. Crabtree, J. H.; Burchette, R. J.; Siddiqi, R. A.; Huen I. T.; Hadnott, L. L.; Fishman, A. Periton. Dialysis Int. 2003, 23 (4), 368-374.
  7. 7. Sharma, V. K.; Yngard, R. A.; Lin, Y. Adv. Colloid Interfac. 2009, 145 (1-2), 83-96.
  8. 8. Balantrapu, K.; Goia, D. V. J. Mater. Res. 2009, 24 (9), 2828-2836.

Details

Primary Language

English

Subjects

Chemical Engineering

Journal Section

Research Article

Publication Date

June 30, 2020

Submission Date

April 20, 2020

Acceptance Date

May 20, 2020

Published in Issue

Year 2020 Volume: 4 Number: 1

APA
Gültekin, D. D., Alaylı, A., & Nadaroglu, H. (2020). Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. International Journal of Chemistry and Technology, 4(1), 71-78. https://doi.org/10.32571/ijct.724056
AMA
1.Gültekin DD, Alaylı A, Nadaroglu H. Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. Int. J. Chem. Technol. 2020;4(1):71-78. doi:10.32571/ijct.724056
Chicago
Gültekin, Demet Demirci, Azize Alaylı, and Hayrunnisa Nadaroglu. 2020. “Eco-Friendly Synthesis of Nano Copper and Its Use in Fenton-Like Reactions for Methylene Blue Degradation”. International Journal of Chemistry and Technology 4 (1): 71-78. https://doi.org/10.32571/ijct.724056.
EndNote
Gültekin DD, Alaylı A, Nadaroglu H (June 1, 2020) Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. International Journal of Chemistry and Technology 4 1 71–78.
IEEE
[1]D. D. Gültekin, A. Alaylı, and H. Nadaroglu, “Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation”, Int. J. Chem. Technol., vol. 4, no. 1, pp. 71–78, June 2020, doi: 10.32571/ijct.724056.
ISNAD
Gültekin, Demet Demirci - Alaylı, Azize - Nadaroglu, Hayrunnisa. “Eco-Friendly Synthesis of Nano Copper and Its Use in Fenton-Like Reactions for Methylene Blue Degradation”. International Journal of Chemistry and Technology 4/1 (June 1, 2020): 71-78. https://doi.org/10.32571/ijct.724056.
JAMA
1.Gültekin DD, Alaylı A, Nadaroglu H. Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. Int. J. Chem. Technol. 2020;4:71–78.
MLA
Gültekin, Demet Demirci, et al. “Eco-Friendly Synthesis of Nano Copper and Its Use in Fenton-Like Reactions for Methylene Blue Degradation”. International Journal of Chemistry and Technology, vol. 4, no. 1, June 2020, pp. 71-78, doi:10.32571/ijct.724056.
Vancouver
1.Demet Demirci Gültekin, Azize Alaylı, Hayrunnisa Nadaroglu. Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. Int. J. Chem. Technol. 2020 Jun. 1;4(1):71-8. doi:10.32571/ijct.724056

Cited By