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Nanosilika ile güçlendirilmiş AZ91 alaşimlarinin mikroyapı, sertlik ve yoğunluk araştırması

Year 2025, Volume: 7 Issue: 2, 106 - 112, 23.12.2025

Abstract

Magnezyum ve alaşımları, olağanüstü mukavemet-ağırlık oranı, düşük yoğunluk, mükemmel dökülebilirlik, işlenebilirlik ve bulunabilirlik özellikleri nedeniyle havacılık ve otomotiv endüstrilerinde hafif yapısal uygulamalar için çok değerlidir. Ancak, düşük mukavemet, zayıf süneklik ve sınırlı soğuk işlenebilirlik özellikleri nedeniyle kullanım alanları sınırlıdır. Geleneksel alaşımlama yöntemleri mekanik özellikleri iyileştirir, ancak yine de alüminyum alaşımları ve çeliğe kıyasla yetersiz kalır. Bu durum, mekanik özellikleri iyileştirmek için mikron ve nano boyutlu takviyelere odaklanan magnezyum bazlı metal matris kompozitler (MMC'ler) konusunda önemli araştırmalara yol açmıştır. Bu çalışma, mekanik alaşımlama yaklaşımı kullanılarak nanosilikayla takviye edilmiş AZ91 alaşımının üretimini araştırmakta ve farklı nanosilikal oranlarının (1%, 3% ve 5%) malzeme özellikleri üzerindeki etkilerini incelemektedir. Mekanik alaşımlama işlemi, planet yüksek enerjili bilyalı değirmen kullanılarak gerçekleştirilmiş ve elde edilen tozlar soğuk preslenerek yığın alaşımlara dönüştürülmüştür. Kompozitlerin yoğunlukları Arşimet prensibi kullanılarak ölçülmüş ve nanosilikanın numunelerdeki gözenekliliği doldurma kabiliyeti nedeniyle genel yoğunluğu artırdığı ortaya çıkmıştır. Sertlik ölçümleri, nanosilikanın sertlik değerlerini artırdığını göstermiştir. En yüksek sertlik, %5 nanosilikalı numunede gözlemlenmiştir. Genel olarak, nanosilikalı takviye, AZ91 alaşımlarında hem yoğunluğu hem de sertliği artırmıştır. Bu sonuçlar, yüksek performanslı uygulamalar için gelişmiş magnezyum bazlı MMC'lerin geliştirilmesine yardımcı olmaktadır.

Project Number

MF.YLT.24.15

References

  • Adin, H., Sağlam, Z., Adin, M. Ş., Numerical investigation of fatigue behavior of non-patched and patched aluminum/composite plates, European Mechanical Science, 5(4), 168-176, 2021
  • Alruqi, A. B., Tailoring the Mechanical Properties of X–C–Si (X= Al, Mg) Alloys for Aerospace and Automotive Industries: An ab Initio Study, Science of Advanced Materials, 16(2), 224-230, 2024
  • Ateş, S., Coşman, S., Improvement of the mechanical and wear properties of Al6061 alloys with quartz and SiC hybrid reinforcements by powder metallurgy, Materials Testing, 67(7), 1190-1205, 2025
  • Bai, J., Yang, Y., Wen, C., Chen, J., Zhou, G., Jiang, B., Peng, X., Pan, F., Applications of magnesium alloys for aerospace: A review, Journal of Magnesium and Alloys, 2023
  • Bolat, Ç., Akgün, İ. C., Göksenli, A., On the way to real applications: Aluminum matrix syntactic foams, European Mechanical Science, 4(3), 131-141, 2020
  • Canakci, A., Varol, T., Erdemir, F., The effect of flake powder metallurgy on the microstructure and densification behavior of B4C nanoparticle-reinforced Al–Cu–Mg alloy matrix nanocomposites, Arabian Journal for Science and Engineering, 41(5), 1781-1796, 2016
  • Chaudhary, V., Verma, R., Sharma, V., Effect of nanoparticles adhesion and multipass friction stir processing on metallurgical properties of AZ91D magnesium alloy, Journal of Adhesion Science and Technology, 38(11), 1953-1973, 2024
  • Dwivedi, S. P., Sharma, S., The behaviour of AZ91 magnesium-based alloy with Ni–Al2O3 reinforcement, Materials Science and Technology, 02670836241228967, 2024
  • Edoziuno, F. O., Adediran, A. A., Emereje, P. O., Akaluzia, R. O., Jen, T.-C., Development of lightweight, creep resistant Mg–Zn–Al alloys for automotive applications: Influence of micro-additions of quaternary elements, Results in Engineering, 101632, 2024
  • Ferkel, H., Mordike, B. L., Magnesium strengthened by SiC nanoparticles, Materials Science and Engineering: A, 298(1-2), 193-199, 2001
  • Furuya, H., Kogiso, N., Matunaga, S., Senda, K. (2000). Applications of magnesium alloys for aerospace structure systems.
  • Guo, H., Zhou, X., Liu, Z., Advanced Lightweight Structural Materials for Automobiles: Properties, Manipulation, and Perspective, Science of Advanced Materials, 16(5), 563-580, 2024
  • Hu, X. J., Li, T. Y., Lai, Y. X., Xiang, X. M., Chen, J. H., Hardness reversal in severely deformed automotive Al-Mg-Si alloys, Journal of Alloys and Compounds, 978, 173515, 2024
  • Iqbal, A. A., Ismail, N. B. (2022). Mechanical Properties and Corrosion Behavior of Silica Nanoparticle Reinforced Magnesium Nanocomposite for Bio-Implant Application. Materials, 15(22). doi:10.3390/ma15228164
  • Krishnakumar, S., Ali, M., Prakash, R., Venkatesh, R., Fabrication of nano SiC and BF-bonded magnesium alloy (AZ80) hybrid nanocomposite via liquid state stir casting process: characteristics study, International Journal of Cast Metals Research, 1-12, 2024
  • Kumar, V. N., Kishore Nath, N., Ramesh Babu, P., Effect of reinforcement and fabrication of Al6061 nanosilica composite prepared using single-and two-step methods, Advances in Materials and Processing Technologies, 8(1), 478-497, 2022
  • Li, X., Fang, X., Jiang, X., Duan, Y., Li, Y., Zhang, H., Li, X., Huang, K., Additively manufactured high-performance AZ91D magnesium alloys with excellent strength and ductility via nanoparticles reinforcement, Additive Manufacturing, 69, 103550, 2023
  • Liu, F., Mao, Y., Sun, Z., Cao, J., Chen, H., Effect of TiC nanoparticles on microstructure and corrosion resistance of laser cladding Al-CNTs composite coatings on AZ31 alloy, International Journal of Cast Metals Research, 37(2), 136-147, 2024
  • Liu, Z., Jin, L., Zeng, J., Wang, F., Wang, F., Dong, S., Dong, J., A review on particle reinforced mg matrix composites fabricated by powder metallurgy, Acta Metallurgica Sinica (English Letters), 37(3), 391-400, 2024
  • Malaki, M., Tehrani, A. F., Niroumand, B., Abdullah, A., Ultrasonically stir cast SiO2/A356 metal matrix nanocomposites, Metals, 11(12), 2004, 2021
  • Mohammed, S., Chen, D. L., Liu, Z. Y., Ni, D. R., Wang, Q. Z., Xiao, B. L., Ma, Z. Y., Deformation behavior and strengthening mechanisms in a CNT-reinforced bimodal-grained aluminum matrix nanocomposite, Materials Science and Engineering: A, 817, 141370, 2021
  • Padmavathi, K. R., Venkatesh, R., Devi, G. R., Muthukumar, V., Synthesis and characteristics evaluation of SiCnp and SiCnp/CNT-reinforced AZ91D alloy hybrid nanocomposites via semisolid stir casting technique, International Journal of Metalcasting, 18(2), 1633-1643, 2024
  • Regev, M., Rosen, A., Bamberger, M., Qualitative model for creep of AZ91D magnesium alloy, Metallurgical and Materials Transactions A, 32(6), 1335-1345, 2001
  • Ren, J.-Y., Ji, G.-C., Guo, H.-R., Zhou, Y.-M., Tan, X., Zheng, W.-F., Xing, Q., Zhang, J.-Y., Sun, J.-R., Yang, H.-Y., Nano-enhanced phase reinforced magnesium matrix composites: a review of the matrix, reinforcement, interface design, properties and potential applications, Materials, 17(10), 2454, 2024
  • Rubel, R. I., Ali, M. H., Jafor, M. A., Alam, M. M., Carbon nanotubes agglomeration in reinforced composites: A review, AIMS Materials Science, 6(5), 756-780, 2019
  • Sankar, C., Gangatharan, K., Singh, S. C. E., Sivaraj, M., Influence of AZ91 alloy reinforced with nano B4C particles on microstructural characterization, hardness and tribological properties prepared through powder metallurgy, Materials Research Express, 8(10), 105007, 2021
  • Senthilkumar, S., Revathi, K., Venkatesh, R., Sivaprakash, E., Enhancement of magnesium alloy (AZ31B) nanocomposite by the additions of zirconia nanoparticle via stir casting technique: physical, microstructural, and mechanical behaviour, International Journal of Metalcasting, 18(2), 1465-1474, 2024
  • Siva Sankar, L. V., Ebenezer, K., Thoufiq Mohammed, K., Manisekar, K., Investigation into the mechanical properties of heat-treated magnesium metal matrix composites reinforced with TiO2 and Sn particles, Interactions, 245(1), 142, 2024
  • Suryanarayana, C., Mechanical alloying and milling, Progress in materials science, 46(1-2), 1-184, 2001 Şanlı, A., Ateş, S., Hardness and fatigue behavior of SiC, Al2O3, and blast furnace slag reinforced hybrid composites with Al6061 matrix, Materials Testing, 67(9), 1557-1567, 2025
  • Tang, Y., Ye, L., Zhang, Z., Friedrich, K., Interlaminar fracture toughness and CAI strength of fibre-reinforced composites with nanoparticles–A review, Composites Science and Technology, 86, 26-37, 2013
  • Thanabal, N., Silambarasan, R., Seenuvasaperumal, P., Basha, D. A., Elayaperumal, A., Microstructure and mechanical behavior of AXM Mg alloy systems—A review, Journal of Magnesium and Alloys, 2024
  • Toprak, H., Ateş, S., Investigation of fatigue behaviors of Al6061 matrix marble powder reinforced composite, Sādhanā, 50(4), 252, 2025
  • Turan, M. E., Sun, Y., Akgul, Y., Mechanical, tribological and corrosion properties of fullerene reinforced magnesium matrix composites fabricated by semi powder metallurgy, Journal of Alloys and Compounds, 740, 1149-1158, 2018
  • Wang, H., Luo, X. C., Zhang, D. T., Qiu, C., Chen, D. L., High-strength extruded magnesium alloys: A critical review, Journal of Materials Science & Technology, 2024
  • Wei, S., Wang, X., Li, X., Shi, H., Hu, X., Xu, C., Liu, D., Microstructure refinement and mechanical properties enhancement of MgAl alloys via a novel of MgO nanoparticles modified graphene nanoplates refiner by in-situ synthesis, Materials Characterization, 210, 113824, 2024
  • Zhang, Y.-Z., Dong, B.-X., Wang, C.-G., Yan, B.-C., Yang, H.-Y., Qiu, F., Shu, S.-L., Jiang, Q.-C., Review on manufacturability and strengthening mechanisms of particulate reinforced Mg composites, Journal of Materials Research and Technology, 2024
  • Zhang, Y., Li, J., Han, S., Gao, P., Luo, H., Chen, P., Zheng, K., Chen, X., Pan, F., Analysis of Cu-decorated Ti particles as a reinforcement for AZ91 alloys prepared using the powder metallurgy method, Journal of Materials Research and Technology, 30, 5711-5723, 2024
  • Zhu, Z.-h., Nie, K.-b., Munroe, P., Deng, K.-k., Guo, Y.-c., Han, J.-g., Synergistic effects of hybrid (SiC+ TiC) nanoparticles and dynamic precipitates in the design of a high-strength magnesium matrix nanocomposite, Materials Chemistry and Physics, 259, 124048, 2021

The microstructure, hardness, and density investigation of AZ91 alloys reinforced with nanosilica

Year 2025, Volume: 7 Issue: 2, 106 - 112, 23.12.2025

Abstract

Magnesium and its alloys are highly valued for lightweight structural applications in the aerospace and automotive industries due to their exceptional strength-to-weight ratio, low density, excellent castability, and machinability However, their utility is limited by low strength, poor ductility, and limited cold workability. Traditional alloying methods improve mechanical properties but still fall short compared to aluminum alloys and steel. This has led to significant research in magnesium-based metal matrix composites (MMCs), focusing on micron- and nano-sized reinforcements to enhance mechanical characteristics. This study investigates the fabrication of nanosilica-reinforced AZ91 alloy using a mechanical alloying approach, examining the effects of different nanosilica ratios (1%, 3%, and 5%) on the material properties. The mechanical alloying process was carried out using a planetary high-energy ball mill, and the resulting powders were cold-pressed into bulk alloys. The densities of the composites were measured using the Archimedean principle, revealing that the addition of nanosilica increased the overall density due to its ability to reduce the porosity in the samples. Hardness measurements showed that nanosilica increased hardness values. The highest hardness was observed in the sample with 5% nanosilica. Overall, nanosilica reinforcement improved both density and hardness in AZ91 alloys. These results aid in developing advanced magnesium-based MMCs for high-performance applications.

Project Number

MF.YLT.24.15

References

  • Adin, H., Sağlam, Z., Adin, M. Ş., Numerical investigation of fatigue behavior of non-patched and patched aluminum/composite plates, European Mechanical Science, 5(4), 168-176, 2021
  • Alruqi, A. B., Tailoring the Mechanical Properties of X–C–Si (X= Al, Mg) Alloys for Aerospace and Automotive Industries: An ab Initio Study, Science of Advanced Materials, 16(2), 224-230, 2024
  • Ateş, S., Coşman, S., Improvement of the mechanical and wear properties of Al6061 alloys with quartz and SiC hybrid reinforcements by powder metallurgy, Materials Testing, 67(7), 1190-1205, 2025
  • Bai, J., Yang, Y., Wen, C., Chen, J., Zhou, G., Jiang, B., Peng, X., Pan, F., Applications of magnesium alloys for aerospace: A review, Journal of Magnesium and Alloys, 2023
  • Bolat, Ç., Akgün, İ. C., Göksenli, A., On the way to real applications: Aluminum matrix syntactic foams, European Mechanical Science, 4(3), 131-141, 2020
  • Canakci, A., Varol, T., Erdemir, F., The effect of flake powder metallurgy on the microstructure and densification behavior of B4C nanoparticle-reinforced Al–Cu–Mg alloy matrix nanocomposites, Arabian Journal for Science and Engineering, 41(5), 1781-1796, 2016
  • Chaudhary, V., Verma, R., Sharma, V., Effect of nanoparticles adhesion and multipass friction stir processing on metallurgical properties of AZ91D magnesium alloy, Journal of Adhesion Science and Technology, 38(11), 1953-1973, 2024
  • Dwivedi, S. P., Sharma, S., The behaviour of AZ91 magnesium-based alloy with Ni–Al2O3 reinforcement, Materials Science and Technology, 02670836241228967, 2024
  • Edoziuno, F. O., Adediran, A. A., Emereje, P. O., Akaluzia, R. O., Jen, T.-C., Development of lightweight, creep resistant Mg–Zn–Al alloys for automotive applications: Influence of micro-additions of quaternary elements, Results in Engineering, 101632, 2024
  • Ferkel, H., Mordike, B. L., Magnesium strengthened by SiC nanoparticles, Materials Science and Engineering: A, 298(1-2), 193-199, 2001
  • Furuya, H., Kogiso, N., Matunaga, S., Senda, K. (2000). Applications of magnesium alloys for aerospace structure systems.
  • Guo, H., Zhou, X., Liu, Z., Advanced Lightweight Structural Materials for Automobiles: Properties, Manipulation, and Perspective, Science of Advanced Materials, 16(5), 563-580, 2024
  • Hu, X. J., Li, T. Y., Lai, Y. X., Xiang, X. M., Chen, J. H., Hardness reversal in severely deformed automotive Al-Mg-Si alloys, Journal of Alloys and Compounds, 978, 173515, 2024
  • Iqbal, A. A., Ismail, N. B. (2022). Mechanical Properties and Corrosion Behavior of Silica Nanoparticle Reinforced Magnesium Nanocomposite for Bio-Implant Application. Materials, 15(22). doi:10.3390/ma15228164
  • Krishnakumar, S., Ali, M., Prakash, R., Venkatesh, R., Fabrication of nano SiC and BF-bonded magnesium alloy (AZ80) hybrid nanocomposite via liquid state stir casting process: characteristics study, International Journal of Cast Metals Research, 1-12, 2024
  • Kumar, V. N., Kishore Nath, N., Ramesh Babu, P., Effect of reinforcement and fabrication of Al6061 nanosilica composite prepared using single-and two-step methods, Advances in Materials and Processing Technologies, 8(1), 478-497, 2022
  • Li, X., Fang, X., Jiang, X., Duan, Y., Li, Y., Zhang, H., Li, X., Huang, K., Additively manufactured high-performance AZ91D magnesium alloys with excellent strength and ductility via nanoparticles reinforcement, Additive Manufacturing, 69, 103550, 2023
  • Liu, F., Mao, Y., Sun, Z., Cao, J., Chen, H., Effect of TiC nanoparticles on microstructure and corrosion resistance of laser cladding Al-CNTs composite coatings on AZ31 alloy, International Journal of Cast Metals Research, 37(2), 136-147, 2024
  • Liu, Z., Jin, L., Zeng, J., Wang, F., Wang, F., Dong, S., Dong, J., A review on particle reinforced mg matrix composites fabricated by powder metallurgy, Acta Metallurgica Sinica (English Letters), 37(3), 391-400, 2024
  • Malaki, M., Tehrani, A. F., Niroumand, B., Abdullah, A., Ultrasonically stir cast SiO2/A356 metal matrix nanocomposites, Metals, 11(12), 2004, 2021
  • Mohammed, S., Chen, D. L., Liu, Z. Y., Ni, D. R., Wang, Q. Z., Xiao, B. L., Ma, Z. Y., Deformation behavior and strengthening mechanisms in a CNT-reinforced bimodal-grained aluminum matrix nanocomposite, Materials Science and Engineering: A, 817, 141370, 2021
  • Padmavathi, K. R., Venkatesh, R., Devi, G. R., Muthukumar, V., Synthesis and characteristics evaluation of SiCnp and SiCnp/CNT-reinforced AZ91D alloy hybrid nanocomposites via semisolid stir casting technique, International Journal of Metalcasting, 18(2), 1633-1643, 2024
  • Regev, M., Rosen, A., Bamberger, M., Qualitative model for creep of AZ91D magnesium alloy, Metallurgical and Materials Transactions A, 32(6), 1335-1345, 2001
  • Ren, J.-Y., Ji, G.-C., Guo, H.-R., Zhou, Y.-M., Tan, X., Zheng, W.-F., Xing, Q., Zhang, J.-Y., Sun, J.-R., Yang, H.-Y., Nano-enhanced phase reinforced magnesium matrix composites: a review of the matrix, reinforcement, interface design, properties and potential applications, Materials, 17(10), 2454, 2024
  • Rubel, R. I., Ali, M. H., Jafor, M. A., Alam, M. M., Carbon nanotubes agglomeration in reinforced composites: A review, AIMS Materials Science, 6(5), 756-780, 2019
  • Sankar, C., Gangatharan, K., Singh, S. C. E., Sivaraj, M., Influence of AZ91 alloy reinforced with nano B4C particles on microstructural characterization, hardness and tribological properties prepared through powder metallurgy, Materials Research Express, 8(10), 105007, 2021
  • Senthilkumar, S., Revathi, K., Venkatesh, R., Sivaprakash, E., Enhancement of magnesium alloy (AZ31B) nanocomposite by the additions of zirconia nanoparticle via stir casting technique: physical, microstructural, and mechanical behaviour, International Journal of Metalcasting, 18(2), 1465-1474, 2024
  • Siva Sankar, L. V., Ebenezer, K., Thoufiq Mohammed, K., Manisekar, K., Investigation into the mechanical properties of heat-treated magnesium metal matrix composites reinforced with TiO2 and Sn particles, Interactions, 245(1), 142, 2024
  • Suryanarayana, C., Mechanical alloying and milling, Progress in materials science, 46(1-2), 1-184, 2001 Şanlı, A., Ateş, S., Hardness and fatigue behavior of SiC, Al2O3, and blast furnace slag reinforced hybrid composites with Al6061 matrix, Materials Testing, 67(9), 1557-1567, 2025
  • Tang, Y., Ye, L., Zhang, Z., Friedrich, K., Interlaminar fracture toughness and CAI strength of fibre-reinforced composites with nanoparticles–A review, Composites Science and Technology, 86, 26-37, 2013
  • Thanabal, N., Silambarasan, R., Seenuvasaperumal, P., Basha, D. A., Elayaperumal, A., Microstructure and mechanical behavior of AXM Mg alloy systems—A review, Journal of Magnesium and Alloys, 2024
  • Toprak, H., Ateş, S., Investigation of fatigue behaviors of Al6061 matrix marble powder reinforced composite, Sādhanā, 50(4), 252, 2025
  • Turan, M. E., Sun, Y., Akgul, Y., Mechanical, tribological and corrosion properties of fullerene reinforced magnesium matrix composites fabricated by semi powder metallurgy, Journal of Alloys and Compounds, 740, 1149-1158, 2018
  • Wang, H., Luo, X. C., Zhang, D. T., Qiu, C., Chen, D. L., High-strength extruded magnesium alloys: A critical review, Journal of Materials Science & Technology, 2024
  • Wei, S., Wang, X., Li, X., Shi, H., Hu, X., Xu, C., Liu, D., Microstructure refinement and mechanical properties enhancement of MgAl alloys via a novel of MgO nanoparticles modified graphene nanoplates refiner by in-situ synthesis, Materials Characterization, 210, 113824, 2024
  • Zhang, Y.-Z., Dong, B.-X., Wang, C.-G., Yan, B.-C., Yang, H.-Y., Qiu, F., Shu, S.-L., Jiang, Q.-C., Review on manufacturability and strengthening mechanisms of particulate reinforced Mg composites, Journal of Materials Research and Technology, 2024
  • Zhang, Y., Li, J., Han, S., Gao, P., Luo, H., Chen, P., Zheng, K., Chen, X., Pan, F., Analysis of Cu-decorated Ti particles as a reinforcement for AZ91 alloys prepared using the powder metallurgy method, Journal of Materials Research and Technology, 30, 5711-5723, 2024
  • Zhu, Z.-h., Nie, K.-b., Munroe, P., Deng, K.-k., Guo, Y.-c., Han, J.-g., Synergistic effects of hybrid (SiC+ TiC) nanoparticles and dynamic precipitates in the design of a high-strength magnesium matrix nanocomposite, Materials Chemistry and Physics, 259, 124048, 2021
There are 38 citations in total.

Details

Primary Language Turkish
Subjects Mechanical Engineering (Other)
Journal Section Research Article
Authors

Mikail Aslan 0000-0003-0578-5049

Project Number MF.YLT.24.15
Submission Date November 30, 2025
Acceptance Date December 22, 2025
Publication Date December 23, 2025
Published in Issue Year 2025 Volume: 7 Issue: 2

Cite

APA Aslan, M. (2025). Nanosilika ile güçlendirilmiş AZ91 alaşimlarinin mikroyapı, sertlik ve yoğunluk araştırması. Uluslararası Mühendislik Tasarım Ve Teknoloji Dergisi, 7(2), 106-112.