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Year 2021, Volume: 5 Issue: 1, 1 - 6, 30.06.2021

Abstract

References

  • Reymond, F., Fermin, D., Lee, H. J., Girault, H. H., 2000. Electrochemistry at liquid/liquid interfaces: methodology and potential applications, Electrochimica Acta 45(15-16): 2647–2662.
  • Yoshida, Y., Maeda, K., Shirai, O., 2005. The complex formation of ions with a phospholipid monolayer adsorbed at an aqueous|1,2-dichloroethane interface, J. Electroanal. Chem. 578 (1):17–24.
  • Girault, H. H.; Schiffrin, D. J. 1984. Adsorption of phosphatidylcholine and phosphatidylethanolamine at the polarised water/1,2 dichloroethane interface. Electroanal. Chem.179: 277–284.
  • Uyanik, I., 2018. Transfer of the protonable surfactant dipalmitoyl-phosphatidylcholine across a large liquid/liquid interface: a voltammetric study. Turkish Journal of Chemistry 42:264–273.
  • Girault, H. H.; Schiffrin, D. J. 1986. Charge effects on phospholipid monolayers in relation to cell motility. Biochim. Biophys. Acta, 857:251–258.
  • Marken, F., Webster, R. D., Bull, S. D., Davies, S. G., 1997. Redox processes in microdroplets studied by voltammetry, microscopy and ESR spectroscopy: oxidation ofN,N,N′,N′-tetrahexylphenylene diamine deposited on solid electrode surfaces and immersed in aqueous electrolyte solution. J. Electroanal. Chem. 437 (1-2): 209–218.
  • Ball, J. C., Marken, F., Fulian, Q., Wadhawan, J. D., Blythe, A. N., Schröder, U., Compton, R. G., Bull, S. D., Davies, S. G. 2000. Voltammetry of Electroactive Oil Droplets. Part II: Comparison of Experimental and Simulation Data for Coupled Ion and Electron Insertion Processes and Evidence for Microscale Convection. Electroanalysis, 12:1017–1025.
  • Marken, F.; Blythe, A. N.; Wadhawan, J. D.; Compton, R. G.; Bull, S. D.; Aplin, R. T.; Davies, S. G. J. 2001. Voltammetry of electroactive liquid redox systems: anion insertion and chemical reactions in microdroplets of para-tetrakis(6-methoxyhexyl) phenylenediamine, para- and meta-tetrahexylphenylenediamine. Sol. State Electrochem. 5:17–22.
  • Fulian, Q.; Ball, J. C.; Marken, F.; Compton, R. G.; Fisher, A. C. 2000. Voltammetry of Electroactive Oil Droplets. Part I: Numerical Modelling for Three Mechanistic Models Using the Dual Reciprocity Finite Element Method Electroanalysis 12:1012–1016.
  • Marken, F.; Compton, R. G.; Goeting, C. H.; Foord, J. S.; Bull, S. D.; Davies, S. G. 1998. Anion Detection by Electro‐Insertion into N, N, N′, N′‐Tetrahexyl‐Phenylenediamine (THPD) Microdroplets Studied by Voltammetry, EQCM, and SEM Techniques Electroanalysis, 10:821–826.
  • Ulmeanu, S., Lee, H. J., Fermin, D. J., Girault, H. H., Shao, Y., 2001. Voltammetry at a liquid|liquid interface supported on a metallic electrode. Electrochem. Commun. 3 (5):219–223.
  • Gulaboski, R., Scholz, F. 2003. Lipophilicity of Peptide Anions:  An Experimental Data Set for Lipophilicity Calculations. J. Phys. Chem. B 107:5650–5657.
  • Mendez, M A, Zahra, N., Uyanik, I., Lu, Y., Girault, H. G. 2011. Melittin Adsorption and Lipid Monolayer Disruption at Liquid–Liquid Interfaces. Langmuir, 27(22):13918–13924.
  • Uyanik, I., Cengeloglu, Y., 2012. Voltammetric and visual evidence of adsorption reactions at the liquid–liquid interfaces supported on a metallic electrode. Electrochimica Acta 62:290–295.
  • Samec, Z., Trojanek, A., Girault, H. H., 2003. Thermodynamic analysis of the cation binding to a phosphatidylcholine monolayer at a polarised interface between two immiscible electrolyte solutions. Electrochem. Commun., 5(1):98–103.

The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System

Year 2021, Volume: 5 Issue: 1, 1 - 6, 30.06.2021

Abstract

Ion transfer voltammetry at liquid-liquid interfaces supported on a metallic electrode has been investigated to evaluate ferrocyanide/ferricyanide (K3Fe(CN)6 /K4Fe(CN)6) as a new redox pair in the aqueous droplet immersed into the organic phase 1,2-DCE. To this purpose, the drop system has been extended to the adsorption-desorption processes associated with the complex formation between aqueous cations and the phospholipid dipalmitoylposphatidylcholine (DPPC) at the polarizable water/1,2-DCE interface in the drop electrode system. From the cyclic voltammetry experiments, the redox couple ferrocyanide/ferricyanide has been shown to be a useful candidate for ion transfer voltammetry application in liquid-liquid soft interfaces.

References

  • Reymond, F., Fermin, D., Lee, H. J., Girault, H. H., 2000. Electrochemistry at liquid/liquid interfaces: methodology and potential applications, Electrochimica Acta 45(15-16): 2647–2662.
  • Yoshida, Y., Maeda, K., Shirai, O., 2005. The complex formation of ions with a phospholipid monolayer adsorbed at an aqueous|1,2-dichloroethane interface, J. Electroanal. Chem. 578 (1):17–24.
  • Girault, H. H.; Schiffrin, D. J. 1984. Adsorption of phosphatidylcholine and phosphatidylethanolamine at the polarised water/1,2 dichloroethane interface. Electroanal. Chem.179: 277–284.
  • Uyanik, I., 2018. Transfer of the protonable surfactant dipalmitoyl-phosphatidylcholine across a large liquid/liquid interface: a voltammetric study. Turkish Journal of Chemistry 42:264–273.
  • Girault, H. H.; Schiffrin, D. J. 1986. Charge effects on phospholipid monolayers in relation to cell motility. Biochim. Biophys. Acta, 857:251–258.
  • Marken, F., Webster, R. D., Bull, S. D., Davies, S. G., 1997. Redox processes in microdroplets studied by voltammetry, microscopy and ESR spectroscopy: oxidation ofN,N,N′,N′-tetrahexylphenylene diamine deposited on solid electrode surfaces and immersed in aqueous electrolyte solution. J. Electroanal. Chem. 437 (1-2): 209–218.
  • Ball, J. C., Marken, F., Fulian, Q., Wadhawan, J. D., Blythe, A. N., Schröder, U., Compton, R. G., Bull, S. D., Davies, S. G. 2000. Voltammetry of Electroactive Oil Droplets. Part II: Comparison of Experimental and Simulation Data for Coupled Ion and Electron Insertion Processes and Evidence for Microscale Convection. Electroanalysis, 12:1017–1025.
  • Marken, F.; Blythe, A. N.; Wadhawan, J. D.; Compton, R. G.; Bull, S. D.; Aplin, R. T.; Davies, S. G. J. 2001. Voltammetry of electroactive liquid redox systems: anion insertion and chemical reactions in microdroplets of para-tetrakis(6-methoxyhexyl) phenylenediamine, para- and meta-tetrahexylphenylenediamine. Sol. State Electrochem. 5:17–22.
  • Fulian, Q.; Ball, J. C.; Marken, F.; Compton, R. G.; Fisher, A. C. 2000. Voltammetry of Electroactive Oil Droplets. Part I: Numerical Modelling for Three Mechanistic Models Using the Dual Reciprocity Finite Element Method Electroanalysis 12:1012–1016.
  • Marken, F.; Compton, R. G.; Goeting, C. H.; Foord, J. S.; Bull, S. D.; Davies, S. G. 1998. Anion Detection by Electro‐Insertion into N, N, N′, N′‐Tetrahexyl‐Phenylenediamine (THPD) Microdroplets Studied by Voltammetry, EQCM, and SEM Techniques Electroanalysis, 10:821–826.
  • Ulmeanu, S., Lee, H. J., Fermin, D. J., Girault, H. H., Shao, Y., 2001. Voltammetry at a liquid|liquid interface supported on a metallic electrode. Electrochem. Commun. 3 (5):219–223.
  • Gulaboski, R., Scholz, F. 2003. Lipophilicity of Peptide Anions:  An Experimental Data Set for Lipophilicity Calculations. J. Phys. Chem. B 107:5650–5657.
  • Mendez, M A, Zahra, N., Uyanik, I., Lu, Y., Girault, H. G. 2011. Melittin Adsorption and Lipid Monolayer Disruption at Liquid–Liquid Interfaces. Langmuir, 27(22):13918–13924.
  • Uyanik, I., Cengeloglu, Y., 2012. Voltammetric and visual evidence of adsorption reactions at the liquid–liquid interfaces supported on a metallic electrode. Electrochimica Acta 62:290–295.
  • Samec, Z., Trojanek, A., Girault, H. H., 2003. Thermodynamic analysis of the cation binding to a phosphatidylcholine monolayer at a polarised interface between two immiscible electrolyte solutions. Electrochem. Commun., 5(1):98–103.
There are 15 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Articles
Authors

İbrahim Uyanık

Publication Date June 30, 2021
Published in Issue Year 2021 Volume: 5 Issue: 1

Cite

APA Uyanık, İ. (2021). The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System. International Journal of Environmental Trends (IJENT), 5(1), 1-6.
AMA Uyanık İ. The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System. IJENT. June 2021;5(1):1-6.
Chicago Uyanık, İbrahim. “The Utilization of Ferrocyanide/Ferricyanide As a New Redox-Pair in the Drop Electrode System”. International Journal of Environmental Trends (IJENT) 5, no. 1 (June 2021): 1-6.
EndNote Uyanık İ (June 1, 2021) The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System. International Journal of Environmental Trends (IJENT) 5 1 1–6.
IEEE İ. Uyanık, “The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System”, IJENT, vol. 5, no. 1, pp. 1–6, 2021.
ISNAD Uyanık, İbrahim. “The Utilization of Ferrocyanide/Ferricyanide As a New Redox-Pair in the Drop Electrode System”. International Journal of Environmental Trends (IJENT) 5/1 (June 2021), 1-6.
JAMA Uyanık İ. The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System. IJENT. 2021;5:1–6.
MLA Uyanık, İbrahim. “The Utilization of Ferrocyanide/Ferricyanide As a New Redox-Pair in the Drop Electrode System”. International Journal of Environmental Trends (IJENT), vol. 5, no. 1, 2021, pp. 1-6.
Vancouver Uyanık İ. The Utilization of Ferrocyanide/Ferricyanide as a New Redox-Pair in the Drop Electrode System. IJENT. 2021;5(1):1-6.

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