Research Article
BibTex RIS Cite

Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen

Year 2024, , 559 - 579, 25.12.2024
https://doi.org/10.58559/ijes.1582150

Abstract

This study experimentally investigates the purification of synthesis gas using the pressure swing adsorption (PSA) method to isolate H₂. The effects of different pressures and flow rates on adsorption durations has been examined. The lowest adsorption capacity has been observed at 5 bar, while the highest has been recorded at 15 bar. It has been observed that the column adsorption capacity increases with increasing pressure. The results indicate an increase in column retention capacity with pressure. The optimum adsorption duration has been found to be 3 minutes at 5 bar and 9 minutes at 15 bar. Additionally, significant effects of p/f ratio and pressurization direction on H₂ purity has been observed. These findings are consistent with the study’s objective which is to provide insights on optimization of PSA parameters and enhancing hydrogen purity. The results support a broader understanding of PSA technology and potential applications of hydrogen purification in industrial areas and paves the way for further progress. Future research suggests that modeling studies could provide further insights and the use of different adsorbents may enhance H₂ purity.

Thanks

The authors would like to thank to Lentatek Space Aviation and Technology for the experimental setup.

References

  • [1] Lorenz TB, Jiang L, Fox VG. Recent Advances in Simulation and Optimal Design of Pressure Swing Adsorption Systems. Separation & Purification Reviews. 2005;33(1):1-39.
  • [2] Zhang R, Shen Y, Tang Z, Li W, Zhang D. A Review of Numerical Research on the Pressure Swing Adsorption Process. Processes. 2022;10(5):812.
  • [3] Voss C. Applications of Pressure Swing Adsorption Technology. Adsorption. 2005;11:527-9.
  • [4] Riboldi L, Bolland O. Overview on Pressure Swing Adsorption (PSA) as CO2 Capture Technology: State-of-the-Art, Limits and Potentials. Energy Procedia. 2017;114:2390-400.
  • [5] Zhu X, Li S, Shi Y, Cai N. Recent advances in elevated-temperature pressure swing adsorption for carbon capture and hydrogen production. Progress in Energy and Combustion Science. 2019;75:100784.
  • [6] Shabbani HJ, Othman MR, Al-Janabi SK, Barron AR, Helwani Z. H2 purification employing pressure swing adsorption process: Parametric and bibliometric review. Renew Sustain Energy Rev. 2024;50:674-99.
  • [7] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of a PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical Engineering. 2017;5(12):10.
  • [8] Yang SI, Choi DY, Jang SC, et al. Hydrogen separation by multi-bed pressure swing adsorption of synthesis gas. Adsorption. 2008;14(5-6):583-90.
  • [9] Choi WK, Kwon TI, Yeo YK, et al. Optimal operation of the pressure swing adsorption (PSA) process for CO2 recovery. Korean J Chem Eng. 2003;20(4):617-23.
  • [10] De Witte N, Denayer JFM, Van Assche TRC. Effect of adsorption duration and purge flowrate on pressure swing adsorption performance. Ind Eng Chem Res. 2021;60(37):13684-91.
  • [11] Beeyani A, Singh K, Vyas R, Kumar S, Kumar S. Parametric studies and simulation of PSA process for oxygen production from air. Pol J Chem Technol. 2010;12(1):18-28.
  • [12] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and Kinetic Behaviour of CO2 Adsorption onto Zeolites, Carbon Molecular Sieve and Activated Carbons. Energy Procedia. 2017;114:2450 9.
  • [13] Fletcher FB, Leitch HR. Hydrogen Embrittlement of Austenitic Stainless Steels. Metallurgical Transactions A. 1974;5(7):1757-65.
  • [14] Gangloff RP. Hydrogen-Assisted Cracking. In: Sedriks AJ, editor. Stress Corrosion Cracking: Theory and Practice. Houston: NACE International; 1990. p. 55-77.
  • [15] Xiao J, Peng Y, Benard P, Chahine R. Thermal effects on breakthrough curves of pressure swing adsorption for hydrogen purification. International Journal of Hydrogen Energy. 2015;40(9):3706-13.
  • [16] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and kinetic behaviour of CO2 adsorption onto zeolites, carbon molecular sieve and activated carbons. Energy Procedia. 2017;114:2450-9.
  • [17] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of a PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical Engineering. 2017;5:1250-9.
  • [18] Liu Y, Shen X, Ding W, Hou J. Adsorption of CO2 and CH4 on shale under high pressure: An experimental study and thermodynamic modeling. Journal of Chemical & Engineering Data. 2021;66(1):185-94.
  • [19] Khosravi Z, Rajabzadeh A, Bahrami S. Adsorption behavior of carbon dioxide on chemically modified activated carbons: A study on equilibrium, kinetic, and thermodynamic properties. Adsorption Science & Technology. 2019;37(1-2):181-97.
  • [20] Lillo-Ródenas MA, Fletcher AJ, Thomas KM, Cazorla-Amorós D, Linares-Solano A. Competitive adsorption of a binary mixture of gases on activated carbon: Effects of surface chemistry. Microporous and Mesoporous Materials. 2018;263:169-79.
  • [21] Sircar S, Golden TC. Pressure swing adsorption technology for hydrogen production. Adsorption. 2000;6(4):283-300.
  • [22] Yang RT. Gas separation by adsorption processes. Butterworth-Heinemann; 1987.
Year 2024, , 559 - 579, 25.12.2024
https://doi.org/10.58559/ijes.1582150

Abstract

References

  • [1] Lorenz TB, Jiang L, Fox VG. Recent Advances in Simulation and Optimal Design of Pressure Swing Adsorption Systems. Separation & Purification Reviews. 2005;33(1):1-39.
  • [2] Zhang R, Shen Y, Tang Z, Li W, Zhang D. A Review of Numerical Research on the Pressure Swing Adsorption Process. Processes. 2022;10(5):812.
  • [3] Voss C. Applications of Pressure Swing Adsorption Technology. Adsorption. 2005;11:527-9.
  • [4] Riboldi L, Bolland O. Overview on Pressure Swing Adsorption (PSA) as CO2 Capture Technology: State-of-the-Art, Limits and Potentials. Energy Procedia. 2017;114:2390-400.
  • [5] Zhu X, Li S, Shi Y, Cai N. Recent advances in elevated-temperature pressure swing adsorption for carbon capture and hydrogen production. Progress in Energy and Combustion Science. 2019;75:100784.
  • [6] Shabbani HJ, Othman MR, Al-Janabi SK, Barron AR, Helwani Z. H2 purification employing pressure swing adsorption process: Parametric and bibliometric review. Renew Sustain Energy Rev. 2024;50:674-99.
  • [7] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of a PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical Engineering. 2017;5(12):10.
  • [8] Yang SI, Choi DY, Jang SC, et al. Hydrogen separation by multi-bed pressure swing adsorption of synthesis gas. Adsorption. 2008;14(5-6):583-90.
  • [9] Choi WK, Kwon TI, Yeo YK, et al. Optimal operation of the pressure swing adsorption (PSA) process for CO2 recovery. Korean J Chem Eng. 2003;20(4):617-23.
  • [10] De Witte N, Denayer JFM, Van Assche TRC. Effect of adsorption duration and purge flowrate on pressure swing adsorption performance. Ind Eng Chem Res. 2021;60(37):13684-91.
  • [11] Beeyani A, Singh K, Vyas R, Kumar S, Kumar S. Parametric studies and simulation of PSA process for oxygen production from air. Pol J Chem Technol. 2010;12(1):18-28.
  • [12] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and Kinetic Behaviour of CO2 Adsorption onto Zeolites, Carbon Molecular Sieve and Activated Carbons. Energy Procedia. 2017;114:2450 9.
  • [13] Fletcher FB, Leitch HR. Hydrogen Embrittlement of Austenitic Stainless Steels. Metallurgical Transactions A. 1974;5(7):1757-65.
  • [14] Gangloff RP. Hydrogen-Assisted Cracking. In: Sedriks AJ, editor. Stress Corrosion Cracking: Theory and Practice. Houston: NACE International; 1990. p. 55-77.
  • [15] Xiao J, Peng Y, Benard P, Chahine R. Thermal effects on breakthrough curves of pressure swing adsorption for hydrogen purification. International Journal of Hydrogen Energy. 2015;40(9):3706-13.
  • [16] Sarker AI, Aroonwilas A, Veawab A. Equilibrium and kinetic behaviour of CO2 adsorption onto zeolites, carbon molecular sieve and activated carbons. Energy Procedia. 2017;114:2450-9.
  • [17] Abdeljaoued A, Relvas F, Mendes A, Chahbani MH. Simulation and experimental results of a PSA process for production of hydrogen used in fuel cells. Journal of Environmental Chemical Engineering. 2017;5:1250-9.
  • [18] Liu Y, Shen X, Ding W, Hou J. Adsorption of CO2 and CH4 on shale under high pressure: An experimental study and thermodynamic modeling. Journal of Chemical & Engineering Data. 2021;66(1):185-94.
  • [19] Khosravi Z, Rajabzadeh A, Bahrami S. Adsorption behavior of carbon dioxide on chemically modified activated carbons: A study on equilibrium, kinetic, and thermodynamic properties. Adsorption Science & Technology. 2019;37(1-2):181-97.
  • [20] Lillo-Ródenas MA, Fletcher AJ, Thomas KM, Cazorla-Amorós D, Linares-Solano A. Competitive adsorption of a binary mixture of gases on activated carbon: Effects of surface chemistry. Microporous and Mesoporous Materials. 2018;263:169-79.
  • [21] Sircar S, Golden TC. Pressure swing adsorption technology for hydrogen production. Adsorption. 2000;6(4):283-300.
  • [22] Yang RT. Gas separation by adsorption processes. Butterworth-Heinemann; 1987.
There are 22 citations in total.

Details

Primary Language English
Subjects Energy
Journal Section Research Article
Authors

Kemalcan Sevük 0000-0003-0133-1509

Berre Kümük 0000-0001-7953-0167

Mustafa İlbaş 0000-0001-6668-1484

Publication Date December 25, 2024
Submission Date November 10, 2024
Acceptance Date November 28, 2024
Published in Issue Year 2024

Cite

APA Sevük, K., Kümük, B., & İlbaş, M. (2024). Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen. International Journal of Energy Studies, 9(4), 559-579. https://doi.org/10.58559/ijes.1582150
AMA Sevük K, Kümük B, İlbaş M. Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen. Int J Energy Studies. December 2024;9(4):559-579. doi:10.58559/ijes.1582150
Chicago Sevük, Kemalcan, Berre Kümük, and Mustafa İlbaş. “Experimental Investigation of the Synthesis Gas Purification Using the PSA Method to Isolate Hydrogen”. International Journal of Energy Studies 9, no. 4 (December 2024): 559-79. https://doi.org/10.58559/ijes.1582150.
EndNote Sevük K, Kümük B, İlbaş M (December 1, 2024) Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen. International Journal of Energy Studies 9 4 559–579.
IEEE K. Sevük, B. Kümük, and M. İlbaş, “Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen”, Int J Energy Studies, vol. 9, no. 4, pp. 559–579, 2024, doi: 10.58559/ijes.1582150.
ISNAD Sevük, Kemalcan et al. “Experimental Investigation of the Synthesis Gas Purification Using the PSA Method to Isolate Hydrogen”. International Journal of Energy Studies 9/4 (December 2024), 559-579. https://doi.org/10.58559/ijes.1582150.
JAMA Sevük K, Kümük B, İlbaş M. Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen. Int J Energy Studies. 2024;9:559–579.
MLA Sevük, Kemalcan et al. “Experimental Investigation of the Synthesis Gas Purification Using the PSA Method to Isolate Hydrogen”. International Journal of Energy Studies, vol. 9, no. 4, 2024, pp. 559-7, doi:10.58559/ijes.1582150.
Vancouver Sevük K, Kümük B, İlbaş M. Experimental investigation of the synthesis gas purification using the PSA method to isolate hydrogen. Int J Energy Studies. 2024;9(4):559-7.