Excess Molar Volumes, Apparent Molar Volumes, Partial Molar Volumes of Methionine, An Amino Acid, in Water + Ethanol And Water + Methanol Solutions at 298.15 K

Year 2022, , 135 - 140, 01.03.2022

Şaban Uysal , Ufuk Sancar Vural

https://doi.org/10.5541/ijot.1015207

Abstract

Methionine is an amino acid that is extremely important for human health. To better understand the biochemical events occurring in the human body, the excess molar properties of methionine and aqueous ethanol and aqueous methanol mixtures were determined at 298.15 K. Interactions between components in solutions are explained. Negative deviations from the ideal state have been observed in methionine solutions due to hydrogen bonds, dipole interactions, charge-transfer interactions.

Keywords

Methionine, excess molar volume, excess partial molar volume, apparent molar volume

References

• J. T. Brosnan, M. E. Brosnan, R. F.P. Bertolo and J. A. Brunton, “Methionine: A metabolically unique amino acid,” Livestock Science, 112(1-2): 2-7, 2007.
• G. Wu, Y. Z. Fang, S. Yang, J. R. Lupton and N. D. Turner, “Glutathione metabolism and its implications for health,” J Nutr. 134(3): 489-92, 2004.
• M. H. Stipanuk and I. Ueki, “ Dealing with methionine/homocysteine sulfur: cysteine metabolism to taurine and inorganic sulfur,” Journal of inherited metabolic disease, 34(1): 17–32, 2011.
• J. C. Heiby, B. Goretzki, and C. M. Johnson et al. “Methionine in a protein hydrophobic core drives tight interactions required for assembly of spider silk,” Nat Commun 10, 4378, 2019.
• S. Ravanel, B. Gakière, D. Job and R. Douce, “The specific features of methionine biosynthesis and metabolism in plants,” Proc. Natl. Acad. Sci. 95(13): 7805–7812, 1998.
• S. M. Phillips, “A brief review of critical processes in exercise-induced muscular hypertrophy,” Sports Med. 44(1): 71-77, 2014.
• J. T. Brosnan and M. E. Brosnan, “The Sulfur-Containing Amino Acids: An Overview,” The Journal of Nutrition, 136(6): 1636S-640S, 2006.
• T. Zhang, Z. Li, Y. Wang, C. Li, B. Yu, X. Zheng, L. Jiang, J. Gong, “Determination and correlation of solubility and thermodynamic properties of l-methionine in binary solvents of water+(methanol, ethanol, acetone),” The Journal of Chemical Thermodynamics, 96: 82-92, 2016.
• E. Yu. Tyunina, V. I. Smirnov and G. N. Tarasova, “Thermodynamic Properties of L-Methionine and Nicotinic Acid in an Aqueous Buffer Solution”, Russian Journal of Physical Chemistry A, 94(11): 2238–2243, 2020.
• F. I. El-Dossoki, “Phase Diagrams, Molal Volumes and Polarizabilities of (Lysine, Methionine Amino Acids-Alcohol-Water) Tri-Component Systems,” International Research Journal of Pure & Applied Chemistry, 16(2): 1-11, 2018
• F. I. El-Dossoki, “Phase Diagrams, Molal Volumes and Polarizabilities of (Lysine, Methionine Amino Acids-Alcohol-Water)Tri-Component Systems,”International Research Journal of Pure & Applied Chemistry, 16(2): 1-11, 2018.
• M. Mokhtarpour and H. Shekaari, “Measurement and correlation of thermophysical properties in aqueous solutions of some novel bio-based deep eutectic solvents (lactic acid/amino acids) at T = (298.15 to 313.15) K,” J. Chem. Thermodynamics, 144, 106051, 2020.
• A. Shalmashi and F. Amani, “Densıtıes And Excess Molar Volumes For Bınary Solutıon Of Water + Ethanol, + Methanol And + Propanol From (283.15 To 313.15) K,” Latin American Applied Research, 44: 163-166, 2014.
• A. Ali, A. K. Nain, V. K. Sharma and S. Ahmad, “Molecular interactions in binary mixtures of tetrahydrofuran with alkanols (C6, C8, C10): an ultrasonic and volumetric study,” Indian J Pure Appl Phys, 42: 666-673, 2004.
• H. Iloukhani, M. Rezaei-Sameti and J. Basiri-Parsa, “Excess molar volumes and dynamic viscosities for binary mixtures of toluene ? n-alkanes (C5–C10) at T = 298.15 K, comparison with Prigogine-Flory-Patterson theory. J Chem Thermodyn. 38: 975-982, 2006.
• U. S. Vural, “Excess molar volumes and viscosities of binary mixtures of epichlorohydrine and alcohols,” Russian Journal of Physical Chemistry A, 79: 1096-1101, 2005.
• U. S. Vural, V. Muradoglu and S. Vural, “Excess molar volumes, and refractive index of binary mixtures of glycerol + methanol and glycerol + water at 298.15 K and 303.15 K,” Bulletin of the Chemical Society of Ethiopia, 25: 111, 2011
• W. A. A. Ddamba, “Excess and Partial Molar Volumes for [Difurylmethane+Acetonitrile] Binary Mixtures in the Temperature Range: 288.15–323.15 K,” Asian Journal of Chemistry, 21(4): 3057-3067, 2009.
• F. Allal, A. Dahmani, B. Saidat, “Volumetric Properties of Binary Mixtures of 1-Ethyl-3-methylimidazolium ethyl phosphonate + Methanol or 2-Propanol,” International Journal of Thermodynamics (IJoT), 22(3): 128-136, 2019.
• H. Iloukhani and H. Bahrami, “Excess Molar Volumes and Partial Molar Volumes For Binary Mıxtures of Water with 1,2-Ethanediol, 1,2-Propanediol, and 1,2-Butanediol at 293.15, 303.15 and 313.15 K,” Phys. Chem. Liq., 38: 103-111, 2004.
• T. Zhu and T. V. Voorhis, “Understanding the Dipole Moment of Liquid Water from a Self-Attractive Hartree Decomposition,” The Journal of Physical Chemistry Letters, 12 (1): 6-12, 2021.
• F. C Frank, “Dipole Induction and the Solvent Effect in Dipole Moment Measurements,” Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, 152 (875): 171-196, 1935.