EN
CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM
Abstract
The subject of this study concerns the effect of temperature and Cetyltrimethyl ammonium bromide (CTABr) in the presence of tetramethylammonium bromide [(Me)4N+Br-] at different temperature using conductometric method. CTABr showed a remarkable decrease in critical micelle concentration (CMC) in the presence of [(Me)4N+Br-]. The CMC values reduced to a certain minimum in all cases, with increase in the system temperature at different concentration of [(Me)4N+Br-]. The thermodynamic parameters ( , and ) for the micelle system were estimated by applying the phase separation model while the data obtained allowed access to their usability on the micellization process. Enthalpy – entropy compensation was observed, with a constant compensation temperature of 296K.
Keywords
Details
Primary Language
English
Subjects
-
Journal Section
-
Authors
Publication Date
July 16, 2015
Submission Date
July 16, 2015
Acceptance Date
-
Published in Issue
Year 2015 Volume: 18 Number: 4
APA
Esan, O. (2015). CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM. International Journal of Thermodynamics, 18(4), 246-252. https://doi.org/10.5541/ijot.5000130524
AMA
1.Esan O. CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM. International Journal of Thermodynamics. 2015;18(4):246-252. doi:10.5541/ijot.5000130524
Chicago
Esan, Olaseni. 2015. “CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM”. International Journal of Thermodynamics 18 (4): 246-52. https://doi.org/10.5541/ijot.5000130524.
EndNote
Esan O (December 1, 2015) CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM. International Journal of Thermodynamics 18 4 246–252.
IEEE
[1]O. Esan, “CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM”, International Journal of Thermodynamics, vol. 18, no. 4, pp. 246–252, Dec. 2015, doi: 10.5541/ijot.5000130524.
ISNAD
Esan, Olaseni. “CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM”. International Journal of Thermodynamics 18/4 (December 1, 2015): 246-252. https://doi.org/10.5541/ijot.5000130524.
JAMA
1.Esan O. CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM. International Journal of Thermodynamics. 2015;18:246–252.
MLA
Esan, Olaseni. “CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM”. International Journal of Thermodynamics, vol. 18, no. 4, Dec. 2015, pp. 246-52, doi:10.5541/ijot.5000130524.
Vancouver
1.Olaseni Esan. CONDUCTOMETRIC STUDIES ON THE EFFECT OF TEMPERATURE AND TETRAMETHYLAMMONIUM BROMIDE SALT ON THE MICELLIZATION OF CETYLTRIMETHYLAMMONIUM BROMIDE IN AQUEOUS MEDIUM. International Journal of Thermodynamics. 2015 Dec. 1;18(4):246-52. doi:10.5541/ijot.5000130524
Cited By
Ammonia Borane Nanospheres for Hydrogen Storage
ACS Applied Nano Materials
https://doi.org/10.1021/acsanm.9b00176Transition metal based single chained surfactants: synthesis, aggregation behavior and enhanced photoluminescence properties of fluorescein
RSC Advances
https://doi.org/10.1039/C6RA21811CMixed micellization study of dodecyltrimethylammonium chloride and cetyltrimethylammonium bromide mixture in aqueous/urea medium at different temperatures: Theoretical and experimental view
Journal of Physical Organic Chemistry
https://doi.org/10.1002/poc.3872Solvation thermodynamic parameters for sodium dodecyl sulfate (SDS) and sodium lauryl ether sulfate (SLES) surfactants in aqueous and alcoholic-aqueous solvents
SN Applied Sciences
https://doi.org/10.1007/s42452-019-0974-6Influence of polyethylene glycol on the aggregation/clouding phenomena of cationic and non-ionic surfactants in attendance of electrolytes (NaCl & Na2SO4): An experimental and theoretical analysis
Journal of Molecular Liquids
https://doi.org/10.1016/j.molliq.2020.112880Influence of various electrolytes on the interaction of cetyltrimethylammonium bromide with tetradecyltrimethylammonium bromide at different temperatures and compositions: Experimental and theoretical investigation
Journal of Molecular Liquids
https://doi.org/10.1016/j.molliq.2018.12.112Insight of molecular interactions between short‐chain tetraalkylammonium bromides and cetyltrimethylammonium bromide: A spectroscopic and thermodynamic approach
Journal of Surfactants and Detergents
https://doi.org/10.1002/jsde.12682The Assembly of the Mixture of Two Ionic Surfactants in Polyols Media at Variable Temperatures: Combined Conductivity and Theoretical Investigations
Journal of Surfactants and Detergents
https://doi.org/10.1002/jsde.12528An insight into thermodynamic and association behaviours of cocamidopropyl betaine (CAPB) surfactant in water and water–alcohol mixed media
SN Applied Sciences
https://doi.org/10.1007/s42452-020-2504-ySolvation Thermodynamic Parameters for Alkyl Benzyl Dimethyl Ammonium Chloride and Cetyl Trimethyl Ammonium Chloride Surfactants in Water and Alcoholic-Water Solvents
Journal of Chemical & Engineering Data
https://doi.org/10.1021/acs.jced.9b00527Micellization and thermodynamics study of n-alkyl-4-methylpyridinium bromides in water and mixed water–ethanol media
Journal of Molecular Liquids
https://doi.org/10.1016/j.molliq.2022.118765Micellization, molal volume and polarizability of benzyl and allyl-methyl imidazolium ionic liquids in aqueous and alcoholic-aqueous solvents
Journal of the Iranian Chemical Society
https://doi.org/10.1007/s13738-021-02336-3Chromium-based metallosurfactants: synthesis, physicochemical characterization and probing of their interactions with xanthene dyes
New Journal of Chemistry
https://doi.org/10.1039/C7NJ04226DUnveiling the molecular interactions and antimicrobial activity of cetyl pyridinium bromide in ternary systems with short tetraalkylammonium bromide salts
Journal of Biomolecular Structure and Dynamics
https://doi.org/10.1080/07391102.2023.2291540