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Year 2008, Volume: 11 Issue: 4, 181 - 186, 01.12.2008

Man Singh , Vinod Kumar

Abstract

Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter

Year 2008, Volume: 11 Issue: 4, 181 - 186, 01.12.2008

Man Singh , Vinod Kumar

Abstract

Both benzene and water immiscible phases when mixed together develop an energetic interface that remains tense due to individual surface tensions. Physics of a tense interface does equilibrate tensional forces to have an optimized surface force which is denoted as Interfacial Tension (IFT, mN/m). The IFT between water and benzene with addition of surfactants: dodecyltrimethylammonium bromide (DTAB), trimethylsulfoxonium iodide (TMSOI), methyltrioctylammonium chloride (MTOAC) and 3,5-dihydroxytoluene monohydrate (Orcinol) critically decrease to 15.69, 12.86, 10.59, 8.36, 2.97 mN/m for DTAB , TMSOI, water, orcinol, MTOAC respectively. This lowering of IFT infers a higher mutual miscibility (MM) of the phases denoted as wetting. The DTAB and orcinol increased surface tension of water from 71.25 to 79.55 and 72.70 mN/m respectively at 304.65 Kelvin temperature due to stronger cohesive forces.

Keywords

DTAB interfacial tension π-conjugation mutual miscibility buoyancy inductive effects steric effects alkyl chains

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Details

Primary Language English
Journal Section Regular Original Research Article
Authors

Man Singh

Vinod Kumar This is me

Publication Date December 1, 2008
Published in Issue Year 2008 Volume: 11 Issue: 4

Cite

APA Singh, M., & Kumar, V. (2008). Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter. International Journal of Thermodynamics, 11(4), 181-186.
AMA Singh M, Kumar V. Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter. International Journal of Thermodynamics. December 2008;11(4):181-186.
Chicago Singh, Man, and Vinod Kumar. “Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied With Interfacial Tension, Surface Tension and Viscosity Measured With Survismeter”. International Journal of Thermodynamics 11, no. 4 (December 2008): 181-86.
EndNote Singh M, Kumar V (December 1, 2008) Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter. International Journal of Thermodynamics 11 4 181–186.
IEEE M. Singh and V. Kumar, “Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter”, International Journal of Thermodynamics, vol. 11, no. 4, pp. 181–186, 2008.
ISNAD Singh, Man - Kumar, Vinod. “Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied With Interfacial Tension, Surface Tension and Viscosity Measured With Survismeter”. International Journal of Thermodynamics 11/4 (December 2008), 181-186.
JAMA Singh M, Kumar V. Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter. International Journal of Thermodynamics. 2008;11:181–186.
MLA Singh, Man and Vinod Kumar. “Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied With Interfacial Tension, Surface Tension and Viscosity Measured With Survismeter”. International Journal of Thermodynamics, vol. 11, no. 4, 2008, pp. 181-6.
Vancouver Singh M, Kumar V. Solvodynamics of Benzene and Water Phases by DTAB, MTOAC, TMSOI and Orcinol Studied with Interfacial Tension, Surface Tension and Viscosity Measured with Survismeter. International Journal of Thermodynamics. 2008;11(4):181-6.