Research Article
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Year 2022, Volume: 25 Issue: 2, 16 - 22, 01.06.2022

Dhirendra Sharma , Seema Agarwal

https://doi.org/10.5541/ijot.991645
Cited By: 2

Abstract

References

  • S. Agarwal, D. K. Sharma, “Ultrasonic, Volumetric and Isentropic Compressibility of Binary Mixtures of 1,4-Dioxane with Primary Alcohols at 303.15 K, ” Open Journal of Physical Chemistry, 11, 168-181, 2021.
  • GV Rama Rao, AV sarma, D. Ramachandran, C. Rambabu “Evaluation of excess free volume and inernal pressure of binary solution of o-chloro phenol at different temperatures” Indian journal of Pure & Applied Physics, 43, 602-609,2005.
  • A. Ali, A. K. Nain, “Ultrasonic study of molecular interaction in binary liquid mixtures at 30°C,” Parmana J. Phys., 58, 695-701, 2002.
  • P. C. Sharma, “Ultrasonic interferometric study of the solutions of tetra alkyl ammonium iodides in dimethyl sulphoxide at 40, 50 and 60°C,” Ultrasonics, 29, 344-347, 1991.
  • F. Comeli, S. Ottani, R. Francesconi, C. Castellari, “Densities, Viscosities, and Refractive Indices of Binary Mixtures Containing n-Hexane + Components of Pine Resins and Essential Oils at 298.15 K,” J. Chem. Eng. Data, 47, 93-97, 2002.
  • C. Chauhan, S.K. Syal, M.S. Chauhan, “ Viscosity and ultrasonic velocity studies of binary mixtures at different temperature 1:Acetonitrile-propylene carbonate” Ind. J. Pure Appl. Phys., 32, 186, 1994.
  • A. Ali, A. K. Nain, “Study of intermolecular interaction in binary mixtures of Formamide with 2-propanol, 1,2-propanediol and 1,2,3-propanetriol through ultrasonic speed messurements” Ind. J. Pure Appl. Phys., 39, 421, 2001.
  • S. Ottani, D. Vitalini, F. Comeli, C. Castellari, “Densities, Viscosities, Refractive Indices, and Excess Molar Enthalpies of Binary Mixtures Containing Poly (ethylene glycol) 200 and 400 + Dimethoxymethane and + 1,2-Dimethoxyethane at 298.15 K,” J. Chem. Eng. Data, 47, 1226–1231, 2002 .
  • R. Naejus, C. Damas, D. Lemordant, C. Coudert, P. Willmann, “Excess thermodynamic properties of the ethylene carbonate–trifluoroethyl methyl carbonate and propylene carbonate–trifluoroethyl methyl carbonate systems at T = (298.15 or 315.15) K,” J. Chem., Thermodyn., 34, 795-806, 2002.
  • J. H. Hildebrand and R. L.Scott, “Solubility of Non-electrolytes”, (NewYork) 1965.
  • P. Paul Divakar, K. Samatha, Ind. Streams Research Journal, 1, 9, 2011.
  • S. Kaki, D. R. Chandran, “Studying various thermodynamic properties of binary mixture of ethyl acetate with ethanol at 303.15 and 313.15 K,” J. of Eng. and Applied Sciences 13, 2693-2704, 2018.
  • A. Rodriguez, J. Canosa, J. Tojo, “Physical Properties and Liquid-Liquid Equilibrium and Physical Properties of the Ternary Mixture (Dimethyl Carbonate +Methanol + Cyclohexane) at 298.15 K,” Journal of Chemical & Engineering Data, 46, 846-850, 2001.
  • P. S. Nikam, T. R. Mahale, M. Hasan, “Density and Viscosity of Binary Mixtures of Ethyl Acetate with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, 2-Methylpropan-1-ol, and 2-Methylpropan-2-ol at (298.15, 303.15, and 308.15) K,” J. Chem. Eng. Data, 41, 1055-1058, 1996.
  • M. N. Roy, A. Sinka, S. Biswajit, “Excess Molar Volumes, Viscosity Deviations and Isentropic Compressibility of Binary Mixtures Containing 1,3-Dioxolane and Mono alcohols at 303.15 K,” Journal of Solution Chemistry, 34, 1311-1325, 2005 .
  • B. U. Kadam, P. A. Hiray, B. A. Sawant, M. Hasan, “Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Propan-1-oland Butan-1-ol at (303.15 and 313.15) K,” Journal of Chemical & Engineering Data, 51, 60-63, 2006.
  • P. S. Nikam, T. R. Mahale, M. Hasan, “Densities and Viscosities for Ethyl Acetate + Pentan-1-ol, + Hexan-1-ol, + 3,5,5-Trimethylhexan-1-ol, + Heptan-1-ol, + Octan-1-ol, and + Decan-1-ol at (298.15, 303.15, and 308.15) K,” J. Chem. Eng. Data, 43, 436-440, 1998.
  • A. J. Al-Kandary, A. S. Al-Jimaz, A.M. Abdul-Latif, “Densities, Viscosities, Speeds of Sound and Refractive Indices of Binary Mixtures of Tetrahydrofuran with 1-Hexanol, 1-Heptanol, 1-Octanol, 1-Nonanol and 1-Decanol at 298.15, 303.15, 308.15 and 313.15 K,” Physics and Chemistry of Liquid, 47, 210-224, 2009 .
  • G. P. Dubey, M. Sharma, “Excess Volumes, Densities, Speeds of Sound, and Viscosities for the Binary Systems of 1-Octanol with Hexadecane and Squalane at (298.15, 303.15 and 308.15) K,” International Journal of Thermophysics, 29, 1361-1375, 2008.
  • S. Elangovan, S. Mullainathan, “Ultrasonic Studies of Intermolecular Interaction in Binary Mixture of n-Methyl Formate with 1-Propanol at Various Temperatures,”Indian Journal of Physics, 87, 659-664, 2013.
  • M. Yasmin, K. P. Singh, S. Parveen, M. Gupta, J. P. Shukla, “Thermoacoustical Excess Properties of BinaryLiquid Mixtures—A Comparative Experimental and Theoretical Study,” Acta Physica Polonica A, 115, 890-900, 2009.
  • A. Ali, S. Hyder, M. Tariq, “Measurements of the Properties of Binary Mixtures of Dimethylsulphoxide (DMSO) with 1-Alkanols (C4, C6, C7) at 303.15,” Journal of Thermophysics, 26, 1537-1548, 2005.
  • R.R. Yadava, V.N. Singh, S.S. Yadava, “Excess Volume of Mixing for Binary Mixtures of Some Nitroalkanes and Symmetrical Aromatic Hydrocarbons,” J Chem. Eng. Data, 39, 705-707, 1994 & “Shear viscosities of binary mixtures of polar solutes nitromethane, nitroethane, and 2-nitropropane with nonpolar aromatic solvents benzene, p-xylene, and mesitylene at 293.15 K,” J. Chem. Eng. Data, 33, 402-404, 1988.
  • B. Sathyanarayan, B. Ranjith Kumar, T. SavithaJyostna, N. Satyanarayan, “Densities and viscosities of binary liquid mixtures of N-methylacetamide with some chloroethanes and chloroethenes at T = 308.15 K,” J. Chem. Thermodyn., 39, 16-21, 2007.
  • J. R. Suindells, T. B. Godfray, J. Res. Natd. Bur.Stand. 48, 1, 1952.
  • P. S. Nikam, L. N. Shirsat, M. Hasan, “Density and Viscosity Studies of Binary Mixtures of Acetonitrile with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, 2-Methylpropan-1-ol, and 2-Methylpropan-2-ol at (298.15, 303.15, 308.15, and 313.15) K,” J. Chem. Eng. Data, 43, 732-737, 1998.
  • M. N. Roy, A. Jha, R. Dey, “Study of Ion−Solvent Interactions of Some Alkali Metal Chlorides in Tetrahydrofuran + Water Mixture at Different Temperatures,” J. Chem. Eng. Data, 46, 1327–1329, 2001.
  • M. N. Roy, A. Jha, A. Choudhury, “Densities, Viscosities and Adiabatic Compressibilities of Some Mineral Salts in Water at Different Temperatures,” J. Chem. Eng. Data, 49, 291-296, 2004.
  • J.Kuppusami and C.V. Suryanarayana, Indian J Acoust Soc.India,5,102-106,1977.
  • C.V.Suryanarayana and J. Kuppusami, Indian J Acoust Soc.India,4,75,1976.
  • J. A. Dean, Lange’s Handbook of chemistry, 13th Ed. New York: McGraw Hill Int., 186, 1987.
  • L. Palaniappan and K. Ramesh, “Thermoacoustical studies of some iso-alcohols in cyclohexane with toluene,” Indian J. Pure Appl. Phys., 40, 828-830, 2002.
  • R. Thiyagarajan, M. Suhaimi Jaafar and L. Palaniappan, Journal of physical Science, 18, 81-88, 2007.
  • R. P. Singh, C.P. Sinha, J. C. Das and P. Ghosh, Journal of Chem. Eng. Data, 35, 93-97, 1990.
  • T. Sumathi, S. Govindarajan, “Molecular interaction studies on some binary organic liquid mixtures at 303.15 K,” International Journal of Biology, Pharmacy and Allied Sciences (IJBPAS), 1, 1153-1165, 2012.
  • A. Ali, A. K. Nain, V. K. Sharma and S. Ahmed, “Ultrasonic studies in binary liquid mixtures,” Indian Journal of Physics B, 75, 519-525, 2001.
  • K. C Reddy, S. V. Subrahmanyan, J. Bhimsenachar, J Phys Soc Japan, 19, 59, 1964.
  • P. S. Naidu, K. Ravindra Prasad, “Molecular interactions in binary liquid mixtures - An ultrasonic study,” Indian J Pure & Appl. Phys., 40, 264-271, 2002.
  • G. V. Rama Rao, A. Viswanatha Sama , D. Ramachandran & C. Rambabu, “ Evaluation of excess free volumes and excess internal pressures of binary solutions of o-chlorophenol at different temperatures,” Indian Journal of Pure & Applied Physics, 43, 602-608, 2005.
  • C.V.Suryanarayana, “The liquid state-A new out look”, Indian J Acoust Soc.India,5,11,1977.

Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K

Year 2022, Volume: 25 Issue: 2, 16 - 22, 01.06.2022

Dhirendra Sharma , Seema Agarwal

https://doi.org/10.5541/ijot.991645
Cited By: 2

Abstract

Ultrasonic velocity (u), density (ρ), and viscosity (η) measurements have been taken in six binary liquid mixtures ethyl acetate + methanol, ethyl acetate + ethanol, ethyl acetate + propanol, ethyl acetate + butanol, ethyl acetate + hexanol and ethyl acetate + octanol at 303.15 K over the entire mole fraction range. The experimental data has been used to calculate the free volume, internal pressure and their excess values. Excess values of free volume〖(V〗_f^E) and internal pressure (p_i^E) were plotted against the mole fraction of ethyl acetate over the whole composition range at 303.15 K. They have been analyzed to discuss the nature and strength of intermolecular interactions in these mixtures.

Keywords

Ultrasonic velocity binary liquid mixtures internal pressure free volume intermolecular interactions.

References

  • S. Agarwal, D. K. Sharma, “Ultrasonic, Volumetric and Isentropic Compressibility of Binary Mixtures of 1,4-Dioxane with Primary Alcohols at 303.15 K, ” Open Journal of Physical Chemistry, 11, 168-181, 2021.
  • GV Rama Rao, AV sarma, D. Ramachandran, C. Rambabu “Evaluation of excess free volume and inernal pressure of binary solution of o-chloro phenol at different temperatures” Indian journal of Pure & Applied Physics, 43, 602-609,2005.
  • A. Ali, A. K. Nain, “Ultrasonic study of molecular interaction in binary liquid mixtures at 30°C,” Parmana J. Phys., 58, 695-701, 2002.
  • P. C. Sharma, “Ultrasonic interferometric study of the solutions of tetra alkyl ammonium iodides in dimethyl sulphoxide at 40, 50 and 60°C,” Ultrasonics, 29, 344-347, 1991.
  • F. Comeli, S. Ottani, R. Francesconi, C. Castellari, “Densities, Viscosities, and Refractive Indices of Binary Mixtures Containing n-Hexane + Components of Pine Resins and Essential Oils at 298.15 K,” J. Chem. Eng. Data, 47, 93-97, 2002.
  • C. Chauhan, S.K. Syal, M.S. Chauhan, “ Viscosity and ultrasonic velocity studies of binary mixtures at different temperature 1:Acetonitrile-propylene carbonate” Ind. J. Pure Appl. Phys., 32, 186, 1994.
  • A. Ali, A. K. Nain, “Study of intermolecular interaction in binary mixtures of Formamide with 2-propanol, 1,2-propanediol and 1,2,3-propanetriol through ultrasonic speed messurements” Ind. J. Pure Appl. Phys., 39, 421, 2001.
  • S. Ottani, D. Vitalini, F. Comeli, C. Castellari, “Densities, Viscosities, Refractive Indices, and Excess Molar Enthalpies of Binary Mixtures Containing Poly (ethylene glycol) 200 and 400 + Dimethoxymethane and + 1,2-Dimethoxyethane at 298.15 K,” J. Chem. Eng. Data, 47, 1226–1231, 2002 .
  • R. Naejus, C. Damas, D. Lemordant, C. Coudert, P. Willmann, “Excess thermodynamic properties of the ethylene carbonate–trifluoroethyl methyl carbonate and propylene carbonate–trifluoroethyl methyl carbonate systems at T = (298.15 or 315.15) K,” J. Chem., Thermodyn., 34, 795-806, 2002.
  • J. H. Hildebrand and R. L.Scott, “Solubility of Non-electrolytes”, (NewYork) 1965.
  • P. Paul Divakar, K. Samatha, Ind. Streams Research Journal, 1, 9, 2011.
  • S. Kaki, D. R. Chandran, “Studying various thermodynamic properties of binary mixture of ethyl acetate with ethanol at 303.15 and 313.15 K,” J. of Eng. and Applied Sciences 13, 2693-2704, 2018.
  • A. Rodriguez, J. Canosa, J. Tojo, “Physical Properties and Liquid-Liquid Equilibrium and Physical Properties of the Ternary Mixture (Dimethyl Carbonate +Methanol + Cyclohexane) at 298.15 K,” Journal of Chemical & Engineering Data, 46, 846-850, 2001.
  • P. S. Nikam, T. R. Mahale, M. Hasan, “Density and Viscosity of Binary Mixtures of Ethyl Acetate with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, 2-Methylpropan-1-ol, and 2-Methylpropan-2-ol at (298.15, 303.15, and 308.15) K,” J. Chem. Eng. Data, 41, 1055-1058, 1996.
  • M. N. Roy, A. Sinka, S. Biswajit, “Excess Molar Volumes, Viscosity Deviations and Isentropic Compressibility of Binary Mixtures Containing 1,3-Dioxolane and Mono alcohols at 303.15 K,” Journal of Solution Chemistry, 34, 1311-1325, 2005 .
  • B. U. Kadam, P. A. Hiray, B. A. Sawant, M. Hasan, “Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Propan-1-oland Butan-1-ol at (303.15 and 313.15) K,” Journal of Chemical & Engineering Data, 51, 60-63, 2006.
  • P. S. Nikam, T. R. Mahale, M. Hasan, “Densities and Viscosities for Ethyl Acetate + Pentan-1-ol, + Hexan-1-ol, + 3,5,5-Trimethylhexan-1-ol, + Heptan-1-ol, + Octan-1-ol, and + Decan-1-ol at (298.15, 303.15, and 308.15) K,” J. Chem. Eng. Data, 43, 436-440, 1998.
  • A. J. Al-Kandary, A. S. Al-Jimaz, A.M. Abdul-Latif, “Densities, Viscosities, Speeds of Sound and Refractive Indices of Binary Mixtures of Tetrahydrofuran with 1-Hexanol, 1-Heptanol, 1-Octanol, 1-Nonanol and 1-Decanol at 298.15, 303.15, 308.15 and 313.15 K,” Physics and Chemistry of Liquid, 47, 210-224, 2009 .
  • G. P. Dubey, M. Sharma, “Excess Volumes, Densities, Speeds of Sound, and Viscosities for the Binary Systems of 1-Octanol with Hexadecane and Squalane at (298.15, 303.15 and 308.15) K,” International Journal of Thermophysics, 29, 1361-1375, 2008.
  • S. Elangovan, S. Mullainathan, “Ultrasonic Studies of Intermolecular Interaction in Binary Mixture of n-Methyl Formate with 1-Propanol at Various Temperatures,”Indian Journal of Physics, 87, 659-664, 2013.
  • M. Yasmin, K. P. Singh, S. Parveen, M. Gupta, J. P. Shukla, “Thermoacoustical Excess Properties of BinaryLiquid Mixtures—A Comparative Experimental and Theoretical Study,” Acta Physica Polonica A, 115, 890-900, 2009.
  • A. Ali, S. Hyder, M. Tariq, “Measurements of the Properties of Binary Mixtures of Dimethylsulphoxide (DMSO) with 1-Alkanols (C4, C6, C7) at 303.15,” Journal of Thermophysics, 26, 1537-1548, 2005.
  • R.R. Yadava, V.N. Singh, S.S. Yadava, “Excess Volume of Mixing for Binary Mixtures of Some Nitroalkanes and Symmetrical Aromatic Hydrocarbons,” J Chem. Eng. Data, 39, 705-707, 1994 & “Shear viscosities of binary mixtures of polar solutes nitromethane, nitroethane, and 2-nitropropane with nonpolar aromatic solvents benzene, p-xylene, and mesitylene at 293.15 K,” J. Chem. Eng. Data, 33, 402-404, 1988.
  • B. Sathyanarayan, B. Ranjith Kumar, T. SavithaJyostna, N. Satyanarayan, “Densities and viscosities of binary liquid mixtures of N-methylacetamide with some chloroethanes and chloroethenes at T = 308.15 K,” J. Chem. Thermodyn., 39, 16-21, 2007.
  • J. R. Suindells, T. B. Godfray, J. Res. Natd. Bur.Stand. 48, 1, 1952.
  • P. S. Nikam, L. N. Shirsat, M. Hasan, “Density and Viscosity Studies of Binary Mixtures of Acetonitrile with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, 2-Methylpropan-1-ol, and 2-Methylpropan-2-ol at (298.15, 303.15, 308.15, and 313.15) K,” J. Chem. Eng. Data, 43, 732-737, 1998.
  • M. N. Roy, A. Jha, R. Dey, “Study of Ion−Solvent Interactions of Some Alkali Metal Chlorides in Tetrahydrofuran + Water Mixture at Different Temperatures,” J. Chem. Eng. Data, 46, 1327–1329, 2001.
  • M. N. Roy, A. Jha, A. Choudhury, “Densities, Viscosities and Adiabatic Compressibilities of Some Mineral Salts in Water at Different Temperatures,” J. Chem. Eng. Data, 49, 291-296, 2004.
  • J.Kuppusami and C.V. Suryanarayana, Indian J Acoust Soc.India,5,102-106,1977.
  • C.V.Suryanarayana and J. Kuppusami, Indian J Acoust Soc.India,4,75,1976.
  • J. A. Dean, Lange’s Handbook of chemistry, 13th Ed. New York: McGraw Hill Int., 186, 1987.
  • L. Palaniappan and K. Ramesh, “Thermoacoustical studies of some iso-alcohols in cyclohexane with toluene,” Indian J. Pure Appl. Phys., 40, 828-830, 2002.
  • R. Thiyagarajan, M. Suhaimi Jaafar and L. Palaniappan, Journal of physical Science, 18, 81-88, 2007.
  • R. P. Singh, C.P. Sinha, J. C. Das and P. Ghosh, Journal of Chem. Eng. Data, 35, 93-97, 1990.
  • T. Sumathi, S. Govindarajan, “Molecular interaction studies on some binary organic liquid mixtures at 303.15 K,” International Journal of Biology, Pharmacy and Allied Sciences (IJBPAS), 1, 1153-1165, 2012.
  • A. Ali, A. K. Nain, V. K. Sharma and S. Ahmed, “Ultrasonic studies in binary liquid mixtures,” Indian Journal of Physics B, 75, 519-525, 2001.
  • K. C Reddy, S. V. Subrahmanyan, J. Bhimsenachar, J Phys Soc Japan, 19, 59, 1964.
  • P. S. Naidu, K. Ravindra Prasad, “Molecular interactions in binary liquid mixtures - An ultrasonic study,” Indian J Pure & Appl. Phys., 40, 264-271, 2002.
  • G. V. Rama Rao, A. Viswanatha Sama , D. Ramachandran & C. Rambabu, “ Evaluation of excess free volumes and excess internal pressures of binary solutions of o-chlorophenol at different temperatures,” Indian Journal of Pure & Applied Physics, 43, 602-608, 2005.
  • C.V.Suryanarayana, “The liquid state-A new out look”, Indian J Acoust Soc.India,5,11,1977.
There are 40 citations in total.

Details

Primary Language English
Subjects Thermodynamics and Statistical Physics
Journal Section Research Articles
Authors

Dhirendra Sharma 0000-0002-4171-8372

Seema Agarwal This is me

Publication Date June 1, 2022
Published in Issue Year 2022 Volume: 25 Issue: 2

Cite

APA Sharma, D., & Agarwal, S. (2022). Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K. International Journal of Thermodynamics, 25(2), 16-22. https://doi.org/10.5541/ijot.991645
AMA Sharma D, Agarwal S. Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K. International Journal of Thermodynamics. June 2022;25(2):16-22. doi:10.5541/ijot.991645
Chicago Sharma, Dhirendra, and Seema Agarwal. “Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K”. International Journal of Thermodynamics 25, no. 2 (June 2022): 16-22. https://doi.org/10.5541/ijot.991645.
EndNote Sharma D, Agarwal S (June 1, 2022) Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K. International Journal of Thermodynamics 25 2 16–22.
IEEE D. Sharma and S. Agarwal, “Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K”, International Journal of Thermodynamics, vol. 25, no. 2, pp. 16–22, 2022, doi: 10.5541/ijot.991645.
ISNAD Sharma, Dhirendra - Agarwal, Seema. “Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K”. International Journal of Thermodynamics 25/2 (June 2022), 16-22. https://doi.org/10.5541/ijot.991645.
JAMA Sharma D, Agarwal S. Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K. International Journal of Thermodynamics. 2022;25:16–22.
MLA Sharma, Dhirendra and Seema Agarwal. “Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K”. International Journal of Thermodynamics, vol. 25, no. 2, 2022, pp. 16-22, doi:10.5541/ijot.991645.
Vancouver Sharma D, Agarwal S. Free Volume and Internal Pressure of Binary Liquid Mixtures from Ultrasonic Velocity at 303.15 K. International Journal of Thermodynamics. 2022;25(2):16-22.

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